Experimental Techniques and Methods of Data Analysis
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Abstract
This chapter details the experimental methods and apparatus used in the work presented in this thesis. The experiments were performed in two separate laboratories: that of Prof. Mark Brouard at the University of Oxford, and that of Prof. Henrik Staplefeldt at the University of Aarhus. Both apparatus are variants of a conventional velocity-map ion imaging (VMI) spectrometer. The fundamental principals of velocity-map ion imaging were introduced in Sect. 1.5 and are reviewed briefly here, whereafter each spectrometer is described in detail. The Pixel Imaging Mass Spectrometry (PImMS) camera, which is central to the work undertaken in this thesis, is introduced and the design and function of the device are described in detail. Experimental results are presented characterising the performance and characteristics of the device. In addition to experimental methods, this chapter also describes the various data analysis routines used to extract scientifically pertinent information from the experimental data.
Keywords
Reaction Chamber Probe Pulse Time Code Phosphor Screen Coulomb ExplosionReferences
- 1.A. Johnsen, Ion imaging, applications and extensions. Ph.D. thesis, University of Oxford (2010)Google Scholar
- 2.P. Richharia, Sol. Energ. Mater. 20, 199 (1990)CrossRefGoogle Scholar
- 3.M. Krems, J. Zirbel, M. Thomason, R.D. DuBois, Rev. Sci. Instrum. 76, 093305 (2005)CrossRefGoogle Scholar
- 4.U. Even, J. Jortner, D. Noy, N. Lavie, C. Cossart-Magos, J. Chem. Phys. 112, 8068 (2000)CrossRefGoogle Scholar
- 5.M. Hillenkamp, S. Keinan, U. Even, J. Chem. Phys. 118, 8699 (2003)CrossRefGoogle Scholar
- 6.F. Filsinger, J. Kpper, G. Meijer, L. Holmegaard, J.H. Nielsen, I. Nevo, J.L. Hansen, H. Stapelfeldt, J. Chem. Phys. 131, 064309 (2009)CrossRefGoogle Scholar
- 7.G.E. Chamberlain, J.C. Zorn, Phys. Rev. 129, 677 (1963)CrossRefGoogle Scholar
- 8.J.L. Hansen, Imaging molecular frame dynamics using spatially oriented molecules. Ph.D. thesis, Aarhus University (2012)Google Scholar
- 9.H. Stapelfeldt, T. Seideman, Rev. Mod. Phys. 75, 543 (2003)CrossRefGoogle Scholar
- 10.C. Rulliere, Femtosecond Laser Pulses: Principles and Experiments, 2nd edn. (Springer, New York, 2004)Google Scholar
- 11.J.L. Hansen, J.H. Nielsen, C.B. Madsen, A.T. Lindhardt, M.P. Johansson, T. Skrydstrup, L.B. Madsen, H. Stapelfeldt, J. Chem. Phys. 136, 204310 (2012)CrossRefGoogle Scholar
- 12.B.J. Whitaker, Imaging in Chemical Dynamics (Oxford University Press, Oxford, 2000)Google Scholar
- 13.F.B. Hildebrand, Methods of Applied Mathematics (Prentice-Hall, Englewood Cliffs, 1952)Google Scholar
- 14.R.N. Bracewell, The Fourier Transform and its Applications (McGraw-Hill, New York, 1978)Google Scholar
- 15.L.M. Smith, D.R. Keefer, S.I. Sudharsanan, J. Quant. Spectrosc. Radiat. Transf. 39, 367 (1988)CrossRefGoogle Scholar
- 16.S. Manzhos, H.-P. Loock, Comput. Phys. Commun. 154, 76 (2003)CrossRefGoogle Scholar
- 17.M.J.J. Vrakking, Rev. Sci. Instrum. 72, 4084 (2001)CrossRefGoogle Scholar
- 18.G.A. Garcia, L. Nahon, I. Powis, Rev. Sci. Instrum. 75, 4989 (2004)CrossRefGoogle Scholar
- 19.V. Dribinski, A. Ossadtchi, V.A. Mandelshtam, H. Reisler, Rev. Sci. Instrum. 73, 2634 (2002)CrossRefGoogle Scholar
- 20.J.J. John, M. Brouard, A. Clark, J. Crooks, E. Halford, L. Hill, J.W.L. Lee, A. Nomerotski, R. Pisarczyk, I. Sedgwick, C.S. Slater, R. Turchetta, C. Vallance, E. Wilman, B. Winter, W.H. Yuen, JINST 7, C08001 (2012)CrossRefGoogle Scholar
- 21.J.A. Ballin, J.P. Crooks, P.D. Dauncey, A.-M. Magnan, Y. Mikami, O.D. Miller, M.N., V. Rajovic, M. Stanitzki, K. Stefanov, R. Turchetta, M. Tyndel, E.G. Villani, N.K. Watson, J.A. Wilson, Sensors 8, 5336 (2008)Google Scholar
- 22.K. Arndt, G. Bolla, D. Bortoletto, K. Giolo, R. Horisberger, A. Roy, T. Rohe, Nucl. Instrum. Methods Phys. Res. A 511, 106 (2003)Google Scholar
- 23.C. Gemme, Nucl. Instrum. Methods Phys. Res. A 501, 87 (2003)Google Scholar
- 24.S.E. Bohndiek, E.J. Cook, C.D. Arvantis, A. Olivo, G.J. Royle, A.T. Clark, M.L. Prydderch, R. Turchetta, R.D. Speller, Phys. Med. Biol. 53, 655 (2008)CrossRefGoogle Scholar
- 25.A.R. Faruqi, R. Henderson, Curr. Opin. Struct. Biol. 17, 549 (2007)CrossRefGoogle Scholar
- 26.C. Vallance, M. Brouard, A. Lauer, C.S. Slater, E. Halford, B. Winter, S.J. King, J.W.L. Lee, D. Pooley, I. Sedgwick, R. Turchetta, A. Nomerotski, J.J. John, L. Hill, Phys. Chem. Chem. Phys. 16, 383 (2014)CrossRefGoogle Scholar
- 27.A.T. Clark, J.P. Crooks, I. Sedgwick, R. Turchetta, J.W.L. Lee, J.J. John, E.S. Wilman, L. Hill, E. Halford, C.S. Slater, B. Winter, W.-H. Yuen, S.H. Gardiner, M.L. Lipciuc, M. Brouard, A. Nomerotski, C. Vallance, J. Phys. Chem. A 116, 10897 (2012)CrossRefGoogle Scholar
- 28.G.F. Knoll, Radiation Detection and Measurement, 4th edn. (Wiley, Hoboken, 2010)Google Scholar
- 29.Y. Tang, W.-B. Lee, Z. Hu, B. Zhang, K.-C. Lin, J. Chem. Phys. 126, 064302 (2007)CrossRefGoogle Scholar