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\(*\)Random Phase Approximation

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Quantum Kinetic Theory
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Abstract

This chapter presents the fourth of the key many-body approximations (after the mean-field approximation of Chap. 4, the second Born approximation of Chap. 6 and the T-matrix approximation of Chap. 9): the random phase approximation (RPA). Related terms that are often used include “GW approximation” (condensed matter physics) or polarization approximation leading to the Balescu-Lenard kinetic equation (plasma physics). This approximation is complementary to the ladder approximation. It takes into account long-range interaction effects, such as in the case of Coulomb interaction \(V_C\), that give rise to screening of charged particles. In the presence of screening scattering of two particles is radically altered because energy and momentum may be transfered via excitation of collective excitations. Using the RPA as closure for the pair correlation operator the same collective modes that were discussed in Chap. 4 are properly “built-in” into the renormalized interaction potential. We present the non-Markovian generalization of the RPA that directly yields an equation of motion of the screened potential \(V_s(t,t')=V_C\epsilon ^{-1}(t,t')\) with the inverse dielectric function \(\varepsilon ^{-1}\). The solution for \(\epsilon ^{-1}\) describes the build-up of Coulomb correlations and of the screening cloud—effects that are crucial during the short-time dynamics.

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Notes

  1. 1.

    This chapter (as all sections marked with “*") may be skipped on first reading.

  2. 2.

    The results of this chapter have been obtained together with D. Kremp and, in part, J.W. Dufty, see [108].

  3. 3.

    Further references will be given below. Also, the Green functions approach to screening is discussed in Chap. 13.

  4. 4.

    As we will see below, this approximation is equivalent to the selfconsistent random phase approximation of Green functions theory, where all propagators are renormalized by selfenergies in RPA.

  5. 5.

    Alternatively, one can use retarded and advanced propagators, which are defined as \(U^{\pm }(tt')=\Theta [\pm (t-t')]U(tt')\). Having this in mind, we will be able to go over to \(U^{\pm }\) at any time later. Notice also, that \(U_{13}\) is different from the two-particle propagator in Chap. 9.

  6. 6.

    The last term in brackets is a higher order correction, for its discussion, see Sect. 7.4.

  7. 7.

    All momenta are understood as vectors.

  8. 8.

    For completeness, we give the equation of the matrix elements of the free propagator

    figure a

    The solution of this commutator equation is

    figure b

    which, obviously, is related to the quasiparticle propagators (cf. Appendix D) simply by \(U^0(1,1+q,tt')=U_1(tt')\,U^{*}_{1+q}(tt')\).

  9. 9.

    See Problem 10.1, Sect. 10.4.

  10. 10.

    Or, equivalently the longitudinal component of the electromagnetic field, see also Chap. 13.

  11. 11.

    The ansatz (10.26) was only used for identical transformations.

  12. 12.

    There it is obtained using the selfenergy in RPA and by applying the generalized Kadanoff–Baym ansatz (GKBA), cf. Chap. 13. With (10.27) we have, in fact, derived the GKBA in RPA from the hierarchy.

  13. 13.

    Equivalently, (10.32) can be used to define \(V_s\), replacing the ansatz (10.26). This relation is analogous to the relation (9.34) between propagators and the T-operators in case of the binary collision approximation, cf. Chap. 9.

  14. 14.

    Modifications appear only in case of multiple time integrations. For example, the integral \(A(t_1t_2)\) splits in a sum of two according to

    $$\begin{aligned} A(t_1t_2)= \int _{t_0}^{t_1}dt_3\int _{t_0}^{t_2}dt_4 B(t_1t_3)C(t_3t_4)D(t_4t_2) =\int _{t_0}^{t_1}dt_3\int _{t_0}^{t_2}dt_4 B^{+}(t_1t_3)C(t_3t_4)D^{-}(t_4t_2) \nonumber \\ =\int _{t_0}^{t_1}dt_3\int _{t_0}^{t_3}dt_4 B^{+}(t_1t_3)C^{+}(t_3t_4)D^{-}(t_4t_2) +\int _{t_0}^{t_1}dt_3\int _{t_3}^{t_2}dt_4 B^{+}(t_1t_3)C^{-}(t_3t_4)D^{-}(t_4t_2), \nonumber \end{aligned}$$

    where the resulting two integrals have a clear time ordering in all quantities.

  15. 15.

    The transformations are analogous to the ones used to derive the non-Markovian Boltzmann collision integral, Chap. 9. The decomposition in the two integral terms in brackets arises from different time orderings in the \(t_3\) and \(t_4\) integrations as explained in footnote 13, see also [261]. The initial correlation term in (10.11) is treated analogously.

  16. 16.

    The introduction of the retarded and advanced quantities was discussed at the end of Sect. 10.2. In particular, the explicit form of the propagators \(U^{0\pm }(tt')\) follows immediately from (10.22) by multiplication with \(\Theta [\pm (t-t')]\).

  17. 17.

    In principle, the derivation yields the renormalized energies \(\epsilon \) in the denominator. However, this leads to inconsistencies, and the proper inclusion of renormalization effects is still being debated.

  18. 18.

    Recall that all momenta have to be understood as vectors.

  19. 19.

    To this end, we again have to use the limiting result (10.39) for the dielectric function, where the static long wavelength limit (\(\omega \rightarrow 0\) and, subsequently, \(q\rightarrow 0\)) has to be taken. As a result, in (10.44), the integrations over \(t_1\) and \(t_2\) are removed and the square of the statically screened Coulomb potential (Debye potential) appears.

  20. 20.

    This assumes that the one-particle distributions are equilibrium (Fermi/Bose) distributions.

  21. 21.

    More generally, one may wish to be able to consider also situations where already carriers, and thus, also correlations exist in the system prior to the onset of the excitation.

  22. 22.

    Already in 1928 Debye and Falkenhagen calculated the relaxation time of the screening cloud around an ion if the ion is perturbed (removed), see also [138].

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Correspondence to Michael Bonitz .

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Bonitz, M. (2016). \(*\)Random Phase Approximation. In: Quantum Kinetic Theory. Springer, Cham. https://doi.org/10.1007/978-3-319-24121-0_10

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