Abstract
This chapter is intended to give an overview of electrical conductivity and dielectric properties of chloroprene rubber (CR) composites with reference to their application in the field of electronics. Influence of different types of filler on the dielectric properties of the CR composites, in a wide frequency range and varying temperature condition, is thoroughly discussed. Type, concentration, and state of dispersion of fillers as well as the polar nature of CR are noticed to play a significant role in governing the electrical conductivity of CR composites. Electrical conductivity studies of carbon black (CB) and carbon fiber-based CR composites are discussed in terms of filler concentration, filler dispersion, and processing techniques. The role of ionic liquid-modified multi-walled carbon nanotube (MWCNT) in improving the electrical conductivity of CR composites is emphatically reviewed. The effects of different types of aging on the electrical properties of CR composites are also focused in this chapter. The CR composites discussed herewith could potentially be used in the field of electromagnetic interference (EMI) shielding, microwave absorbance, and conductive adhesive.
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Abbreviations
- AC:
-
Alternating current
- BMI 1:
-
Butyl -3-methyl imidazolium bis(trifluoromethylsulphonyl) imide
- BaHF:
-
Barium hexaferrite (BaFe12O19)
- CB:
-
Carbon black
- CR:
-
Chloroprene rubber
- CNT:
-
Carbon nanotube
- CIP:
-
Carbonyl-iron powder
- DBSA:
-
Dodecylbenzenesulfonic acid
- DE:
-
Dielectric elastomer
- DC:
-
Direct current
- EAP:
-
Electroactive polymers
- EMI:
-
Electromagnetic interference
- FEF:
-
Fast extrusion furnace
- GHz:
-
Gigahertz
- HAF:
-
High abrasion furnace
- MT:
-
Thermal medium
- MWCNT:
-
Multi-walled carbon nanotube
- PANI:
-
Polyaniline
- Phr:
-
Parts by weight per hundred parts of rubber
- PTC:
-
Positive temperature coefficient
- PVC:
-
Polyvinyl chloride
- RAM:
-
Radar-absorbing material
- SAF:
-
Super abrasion furnace
- SE:
-
Shielding effectiveness
- SEM:
-
Scanning electron microscopy
- SRF:
-
Semi-reinforcing furnace
- Co-TiBaHF:
-
Ti–Co-doped barium hexaferrite
References
Bhattacharya SK, Tummala RR (2000) Next generation integral passives: materials, processes, and integration of resistors and capacitors on PWB substrates. J Mater Sci: Mater Electron 11:253–268
Chahal P, Tummala RR, Allen MG, Swaminathan M (1998) A novel integrated decoupling capacitor for MCM-L technology. IEEE Trans Comp Pack Manuf Technol Part B: Adv Packag 21:184–193
Brandrup J, Immergut EH (1974) Polymer handbook, 2nd edn. Wiley-Interscience, New York
Skotheim T, Elsenbaumer R, Reynolds J (1998) Handbook of conductive polymers. Marcel Dekker, New York
Nalwa HS (1997) Handbook of organic conductive molecules and polymers, vol 2. Wiley, New York
Tamai T (1982) Electrical properties of conductive elastomer as electrical contact material. Compon Hybrids Manufact Technol IEEE Trans 5:56–61
Mather PJ, Thomas KM (1997) Carbon black/high density polyethylene conducting composite materials: part I structural modification of a carbon black by gasification in carbon dioxide and the effect on the electrical and mechanical properties of the composite. J Mater Sci 32:401–407
Achour ME, Miane JL, Lahjomri F, El Malhi M, Carmona F (1995) Microwave propagation through carbon black-epoxy resin composites. J Mater Sci Lett 14:1425–1429
Makela T, Sten J, Hujanen A, Isotalo H (1999) High frequency polyaniline shields. Synth Met 101:707–717
Norman RH (1970) Electrically conducting rubber composites. Elsevier, Oxford
Chung D (2000) Materials for electromagnetic interference shielding. J Mater Eng Perform 9:350–354
Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205
Rizvi R, Cochrane B, Biddiss E, Naguib H (2011) Piezoresistance characterization of poly (dimethyl-siloxane) and poly (ethylene) carbon nanotube composites. Smart Mater Struct 20:094003
Bigg DM (1979) Mechanical, thermal, and electrical properties of metal fiber-filled polymer composites. Polym Eng Sci 19:1188–1192
Tanrattanakul V, Bunchuay A (2007) Microwave absorbing rubber composites containing carbon black and aluminum powder. J Appl Polym Sci 105:2036–2045
Medalia AI (1986) Electrical conduction in carbon black composites. Rubber Chem Technol 59:432–454
Sherman RD, Middleman LM, Jacobs SM (1983) Electron transport processes in conductor-filled polymers. Polym Eng Sci 23:36–46
Bueche F (1972) Electrical resistivity of conducting particles in an insulating matrix. J Appl Phy 43:4837–4838
Bueche F (1973) A new class of switching materials. J Appl Phy 44:532–533
De SK, White JR (2001) Rubber technologist’s handbook, vol 1. Smithers Rapra Publishing
Bhowmick AK, Stephens H (2000) Handbook of elastomers, 2nd edn. CRC Press, Technology and Engineering, Boca Raton
Shtarkova R, Dishovsky N (2009) Elastomer-based microwave absorbing materials. J Elastomers Plast 41:163–174
Schneider WC, Carter WC, Magat M, Smyth CP (1945) Dielectric dispersion and absorption in neoprene gum and tread stocks. J Am Chem Soc 67:959–963
Matsuo M, Ishida Y, Yamafuji K, Takayanagi M, Irie F (1965) Dielectric behavior of polychloroprene. Kolloid-Zeitschrift und Zeitschrift für Polymere 201:89–93
Abo-Hashem A (1993) DC conduction in chloroprene rubber (CR). Polym Degrad Stab 40:379–384
Baughman RH (1996) Conducting polymer artificial muscles. Synth Metals 78:339–353
Suo Z (2010) Theory of dielectric elastomers. Acta Mech Solida Sin 23:549–578
Pelrine R, Sommer-Larsen P, Kornbluh RD, Heydt R, Kofod G, Pei Q, Gravesen P (2001) Applications of dielectric elastomer actuators. In: SPIE’s 8th annual international symposium on smart structures and materials. International Society for Optics and Photonics, pp 335–349
Kornbluh R, Pelrine R, Eckerle J, Joseph J (1998) Electrostrictive polymer artificial muscle actuators. In: Robotics and automation. Proceedings of IEEE international conference, vol 3, pp 2147–2154
Heydt R, Kornbluh R, Pelrine R, Mason V (1998) Design and performance of an electrostrictive-polymer-film acoustic actuator. J Sound Vib 215:297–311
Carpi F, De Rossi D, Kornbluh R, Pelrine RE, Sommer-Larsen P (2001) (eds.). Dielectric elastomers as electromechanical transducers: Fundamentals, materials, devices, models and applications of an emerging electroactive polymer technology. Elsevier
Banno H (1983) Recent developments of piezoelectric ceramic products and composites of synthetic rubber and piezoelectric ceramic particles. Ferroelectrics 50:3–12
Lawandy SN, Abd-El-Nour KN (1986) Dielectric properties and stress–strain measurements of chloroprene rubber based on different carbon black fillers. J Appl Polym Sci 31:841–848
Hanna FF, Abdel-Nour KN, Abdel-Messieh SL (1992) Dielectric properties of some synthetic rubber mixtures: Part I Neoprene-carbon black mixtures. Polym Degrad Stab 35:49–52
Omar Al-Hartomy A, Ahmed Al-Ghamdi A, Falleh Alsolamy J, Dishovsky N, Mihaylov M, Iliev V, El-Tantawy F (2012) Effect of furnace carbon black on the dielectric and microwave properties of chloroprene rubber composites. Kautsch Gummi Kunstst 65:43–48
Al-Hartomy OA, Al-Ghamdi A, Dishovsky N, Shtarkova R, Iliev V, El-Tantawy F (2013) Comparison of microwave absorbing properties of chloroprene rubber composites containing carbon black and nickel/cobalt powder. J Elastomers Plast 45:471–485
Abd-El-Messieh SL, Younan AF (1996) Dielectric relaxation and mechanical properties of natural and chloroprene rubber with some nitroaniline additives. J Appl Polym Sci 62:805–812
Bengtsson P, Klason C, Kubat J, McQueen DH (1989) Electrical noise characteristics of carbon-black-filled chloroprene rubber. J Phys D Appl Phys 22:1736–1741
Ali MH, Abo-Hashem A (1997) Percolation concept and the electrical conductivity of carbon black-polymer composites 2: non-crystallisable chloroprene rubber mixed with HAF carbon black. J Mater Process Technol 68:163–167
Ali MH, Abo-Hashem A (1997) Percolation concept and the electrical conductivity of carbon black-polymer composites 3: crystallisable chloroprene rubber mixed with FEF carbon black. J Mater Process Technol 68:168–171
Jana PB, Chaudhuri S, Pal AK, De SK (1992) Electrical conductivity of short carbon fiber-reinforced polychloroprene rubber and mechanism of conduction. Polym Eng Sci 32:448–456
Jana PB, De SK, Chaudhuri S, Pal AK (1992) Electrical conductivity of barium-ferrite-vulcanized polychloroprene filled with short carbon fiber. Rubber Chem Technol 65:7–23
Saritha Chandran A, Narayanankutty SK (2008) An elastomeric conducting composite based on polyaniline coated nylon fiber and chloroprene rubber. Eur Polym J 44:2418–2429
Kim YA, Hayashi T, Endo M, Gotoh Y, Wada N, Seiyama J (2006) Fabrication of aligned carbon nanotube-filled rubber composite. Scripta Mater 54:31–35
Xie XL, Mai YW, Zhou XP (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng R 49:89–112
Das A, Stöckelhuber KW, Jurk R, Saphiannikova M, Fritzsche J, Lorenz H, Klüppel M, Heinrich G (2008) Modified and unmodified multiwalled carbon nanotubes in high performance solution-styrene–butadiene and butadiene rubber blends. Polymer 49:5276–5283
Subramaniam K, Das A, Steinhauser D, Klüppel M, Heinrich G (2011) Effect of ionic liquid on dielectric, mechanical and dynamic mechanical properties of multi-walled carbon nanotubes/polychloroprene rubber composites. Eur Polym J 47:2234–2243
Subramaniam K, Das A, Heinrich G (2011) Development of conducting polychloroprene rubber using imidazolium based ionic liquid modified multi-walled carbon nanotubes. Compos Sci Technol 71:1441–1449
Steinhauser D, Subramaniam K, Das A, Heinrich G, Klüppel M (2012) Influence of ionic liquids on the dielectric relaxation behavior of CNT based elastomer nanocomposites. Express Polym Lett 6:927–936
Semeriyanov FF, Chervanyov AI, Jurk R, Subramaniam K, König S, Roscher M, Das A, Stöckelhuber KW, Heinrich G (2013) Non-monotonic dependence of the conductivity of carbon nanotube-filled elastomers subjected to uniaxial compression/decompression. J Appl Phy 113:103706
Ito M, Okada S, Kuriyama I (1981) The deterioration of mechanical properties of chloroprene rubber in various conditions. J Mater Sci 16:10–16
Pinho MS, Gregori ML, Nunes RCR, Soares BG (2001) Aging effect on the reflectivity measurements of polychloroprene matrices containing carbon black and carbonyl-iron powder. Polym Degrad Stab 73:1–5
Kuwahara H, Sudo S, Iijima M, Ohya S (2010) Dielectric properties of thermally degraded chloroprene rubber. Polym Degrad Stab 95:2461–2466
Subramaniam K, Das A, Heinrich G (2013) Improved oxidation resistance of conducting polychloroprene composites. Compos Sci Technol 74:14–19
Ramasamy SR (1997) A review of EMI shielding and suppression materials. In: Electromagnetic interference and compatibility. Proceedings of the international conference on IEEE pp 459–466
Kimmel WD, Gerke DD (1995) Controlling EMI with cable shields. Med Device Diagn Ind 17:112–115
Chung DDL (2001) Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39:279–285
Jana PB, Mallick AK, De SK (1991) Electromagnetic interference shielding by carbon fiber-filled polychloroprene rubber composites. Composites 22:451–455
Joo J, Epstein AJ, MacDiarmid AG (1995) Control of dielectric response of polyanilines: applications to EMI shielding. In: Technical papers of the annual technical conference-society of plastics engineers, pp 1672–1672
Jana PB, Mallick K, De SK (1992) Effects of sample thickness and fiber aspect ratio on EMI shielding effectiveness of carbon fiber filled polychloroprene composites in the X-band frequency range. IEEE Trans Electromagn Compat 34:478–481
Jana PB, Mallick AK, De SK (1993) Electromagnetic interference shielding effectiveness of short carbon fiber-filled polychloroprene vulcanized by barium ferrite. J Mater Sci 28:2097–2104
Jana PB, Mallick AK (1994) Studies on effectiveness of electromagnetic interference shielding in carbon fiber filled polychloroprene composites. J Elastomers Plast 26:58–73
Saritha Chandran A, Narayanankutty SK, Mohanan P (2011) Microwave characteristics of polyaniline based short fiber reinforced chloroprene rubber composites. Polym Plast Technol Eng 50:453–458
Pinho MS, Gregori ML, Nunes RR, Soares BG (2002) Performance of radar absorbing materials by waveguide measurements for X-and Ku-band frequencies. Eur Polym J 38:2321–2327
Lima RC, Pinho MS, Gregori ML, Nunes RR, Ogasawara T (2004) Effect of double substituted m-barium hexaferrites on microwave absorption properties. Mater Sci-Poland 22:245–252
Capitaneo JL, Caffarena VDR, Ogasawara T, Pinho MS (2008) Performance of radar absorbing nanocomposites by waveguide measurements. Mater Res 11:319–324
Caffarena VDR, Capitaneo JL, Ogasawara T, Pinho MS (2008) Microwave absorption properties of Co, Cu, Zn: substituted hexaferrite polychloroprene nanocomposites. Mater Res 11:335–339
Das S, Nayak GC, Sahu SK, Routray PC, Roy AK, Baskey H (2014) Microwave absorption properties of double-layer RADAR absorbing materials based on doped barium Hexaferrite/TiO2/conducting carbon black. J Eng 2014: 1–5. (Article ID 468313, http://dx.doi.org/10.1155/2014/468313)
Kunanuruksapong R, Sirivat A (2013) Highly electro responsive polymer blends of polyaniline nanoparticles and chloroprene rubbers. Adv Polym Technol 32:556–571
Petrie E M (2000) Handbook of adhesives and sealants. McGraw-Hill Professional
Steinfink M (1990) Adhesive materials, Neoprene (polychloroprene)-based solvent and latex adhesives. In Skeist I (ed) Handbook of adhesives. Van Nostrand Reinhold, New York, pp 284–306
Pocius AV (2002)Â Adhesion and adhesives technology: an introduction, 2nd edn. Hanser Gardner Publications
Galiatsatos V (1999) Polychloroprene. In: Polymer data handbook. Oxford University Press, pp 375–379
Li Y, Wong CP (2006) Recent advances of conductive adhesives as a lead-free alternative in electronic packaging: materials, processing, reliability and applications. Mat Sci Eng R 51:1–35
Massoumi B, Farjadbeh F, Mohammadi R, Entezami AA (2013) Synthesis of conductive adhesives based on epoxy resin/nanopolyaniline and chloroprene rubber/nanopolyaniline: characterization of thermal, mechanical and electrical properties. J Compos Mater 47:1185–1195
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Kapgate, B.P., Das, C. (2016). Electronic Applications of Chloroprene Rubber and Its Composites. In: Ponnamma, D., Sadasivuni, K., Wan, C., Thomas, S., Al-Ali AlMa'adeed, M. (eds) Flexible and Stretchable Electronic Composites. Springer Series on Polymer and Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-23663-6_10
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