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Magneto-Transport Results in Alq3 BasedĀ OSVs

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Molecular Spintronics

Part of the book series: Springer Theses ((Springer Theses))

Abstract

The achievement of good magnetoresistance signal at room temperature is an important requirement for the possible future development of organic devices for applications. However, until now only few works reported room temperature MR effect in organic spin valves (OSVs). In this regard, this chapter is dedicated to the investigation of Alq3-based OSVs where Alq3 molecule was chosen since it is a standard material in the field. A systematic study on Co/Alq3/Co OSVs will be presented showing room temperature MR results. Moreover, inelastic electron tunneling spectroscopy (IETS) technique will be used to prove spin injection into the organic layer. Finally, an insulating oxide barrier (Al2O3 or MgO) will be also inserted at the bottom or top interface. This will allow to separately investigate the specific role of ferromagnetic metal/molecule hybridization at each interface and understand their influence on the spin polarization properties.

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Notes

  1. 1.

    The results of this model are similar to the resonant tunneling inversion that was introduced for inorganic semiconductor MTJs [19, 20].

  2. 2.

    For a more complete picture, one would have to consider that coupling strength of different orbitals will also be magnetization orientation dependent.

References

  1. V.A. Dediu, L.E. Hueso, I. Bergenti, A. Riminucci, F. Borgatti, P. Graziosi, C. Newby, F. Casoli, M.P. De Jong, C. Taliani, Y. Zhan, Room-temperature spintronic effects in Alq\(_3\)-based hybrid devices. Phys. Rev. B 78, 115203 (2008)

    ArticleĀ  Google ScholarĀ 

  2. S. Wang, Y.J. Shi, L. Lin, B.B. Chen, F.J. Yue, J. Du, H.F. Ding, F.M. Zhang, D. Wu, Room-temperature spin valve effects in La\(_{0.67}\)Sr\(_{0.33}\)MnO\(_3\)/Alq\(_3\)/Co devices. Synth. Met. 161, 1738ā€“1741 (2011)

    ArticleĀ  CASĀ  Google ScholarĀ 

  3. Y. Liu, T. Lee, H.E. Katz, D.H. Reich, Effects of carrier mobility and morphology in organic semiconductor spin valves. J. Appl. Phys. 105, 07C708 (2009)

    Google ScholarĀ 

  4. T.S. Santos, J.S. Lee, P. Migdal, I.C. Lekshmi, B. Satpati, J.S. Moodera, Room-temperature tunnel magnetoresistance and spin-polarized tunneling through an organic semiconductor barrier. Phys. Rev. Lett. 98, 016601 (2007)

    ArticleĀ  CASĀ  Google ScholarĀ 

  5. G. Szulczewski, H. Tokuc, K. Oguz, J.M.D. Coey, Magnetoresistance in magnetic tunnel junctions with an organic barrier and an MgO spin filter. Appl. Phys. Lett. 95, 202506 (2009)

    ArticleĀ  Google ScholarĀ 

  6. Y. Sakurai, Y. Hosoi, H. Ishii, Y. Ouchi, G. Salvan, A. Kobitski, T.U. Kampen, D.R.T. Zahn, K. Seki, Study of the interaction of tris-(8-hydroxyquinoline) aluminum (Alq\(_3\)) with potassium using vibrational spectroscopy: examination of possible isomerization upon K doping. J. Appl. Phys. 96, 5534 (2004)

    ArticleĀ  CASĀ  Google ScholarĀ 

  7. R.J. Davis, J.E. Pemberton, Surface Raman spectroscopy of the interface of tris-(8-hydroxyquinoline) aluminum with Mg. J. Am. Chem. Soc. 131(29), 10009ā€“10014 (2009)

    ArticleĀ  CASĀ  Google ScholarĀ 

  8. Z.H. Xiong, D. Wu, Z.V. Vardeny, J. Shi, Giant magnetoresistance in organic spin-valves. Nature 427, 821ā€“824 (2004)

    ArticleĀ  CASĀ  Google ScholarĀ 

  9. M. GrĆ¼newald, R. Gƶckeritz, N. Homonnay, F. WĆ¼rthner, L.W. Molenkamp, G. Schmidt, Vertical organic spin valves in perpendicular magnetic fields. Phys. Rev. B 88, 085319 (2013)

    ArticleĀ  Google ScholarĀ 

  10. A. Riminucci, M. Prezioso, C. Pernechele, P. Graziosi, I. Bergenti, R. Cecchini, M. Calbucci, M. Solzi, V.A. Dediu, Hanle effect missing in a prototypical organic spintronic device. Appl. Phys. Lett. 102, 92407 (2013)

    ArticleĀ  Google ScholarĀ 

  11. Z.G. Yu, Suppression of the Hanle effect in organic spintronic devices. Phys. Rev. Lett. 111, 016601 (2013)

    ArticleĀ  CASĀ  Google ScholarĀ 

  12. J.G. Kushmerick, J. Lazorcik, C.H. Patterson, R. Shashidhar, D.S. Seferos, G.C. Bazan, Vibronic contributions to charge transport across molecular junctions. Nano Lett. 4, 639ā€“642 (2004)

    ArticleĀ  CASĀ  Google ScholarĀ 

  13. W. Wang, Electrical characterization of self-assembled monolayers. Ph.D. thesis, Yale University (2004)

    Google ScholarĀ 

  14. K.-S. Li, Y.-M. Chang, S. Agilan, J.-Y. Hong, J.-C. Tai, W.-C. Chiang, K. Fukutani, P.A. Dowben, M.-T. Lin, Organic spin valves with inelastic tunneling characteristics. Phys. Rev. B 83, 172404 (2011)

    ArticleĀ  Google ScholarĀ 

  15. K.V. Raman, Spin injection and manipulation in organic semiconductors. Ph.D. thesis, MIT (2011)

    Google ScholarĀ 

  16. H. Vinzelberg, J. Schumann, D. Elefant, R.B. Gangineni, J. Thomas, B. BĆ¼chner, Low temperature tunneling magnetoresistance on (La, Sr)MnO\(_3\)/Co junctions with organic spacer layers. J. Appl. Phys. 103, 93720 (2008)

    ArticleĀ  Google ScholarĀ 

  17. M. Palosse, Ɖlaboration et Ć©tude de vannes de spin organiques: vers le transport de spin Ć  tempĆ©rature ambiante. Ph.D. thesis, UniversitĆ© de Toulouse (2013)

    Google ScholarĀ 

  18. J.J.H.M. Schoonus, P.G.E. Lumens, W. Wagemans, J.T. Kohlhepp, P.A. Bobbert, H.J.M. Swagten, B. Koopmans, Magnetoresistance in hybrid organic spin valves at the onset of multiple-step tunneling. Phys. Rev. Lett. 103, 146601 (2009)

    ArticleĀ  CASĀ  Google ScholarĀ 

  19. E.Y. Tsymbal, A. Sokolov, I.F. Sabirianov, B. Doudin, Resonant inversion of tunneling magnetoresistance. Phys. Rev. Lett. 90(18), 186602 (2003)

    ArticleĀ  CASĀ  Google ScholarĀ 

  20. V. Garcia, H. JaffrĆØs, J.-M. George, M. Marangolo, M. Eddrief, V. Etgens, Spectroscopic measurement of spin-dependent resonant tunneling through a 3d disorder: the case of MnAs/GaAs/MnAs junctions. Phys. Rev. Lett. 97, 246802 (2006)

    ArticleĀ  CASĀ  Google ScholarĀ 

  21. C. Gould, C. RĆ¼ster, T. Jungwirth, E. Girgis, G.M. Schott, R. Giraud, K. Brunner, G. Schmidt, L.W. Molenkamp, Tunneling anisotropic magnetoresistance: a spin-valve-like tunnel magnetoresistance using a single magnetic layer. Phys. Rev. Lett. 93, 117203 (2004)

    ArticleĀ  CASĀ  Google ScholarĀ 

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Correspondence to Marta Galbiati .

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Galbiati, M. (2016). Magneto-Transport Results in Alq3 BasedĀ OSVs. In: Molecular Spintronics. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-22611-8_8

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