Skip to main content

Shock and High Strain Rate Characterization of HTPB with Varying Plasticizer

  • Conference paper
Dynamic Behavior of Materials, Volume 1

Abstract

Hydroxyl-terminated polybutadiene (HTPB) has long been used as a binder in propellants and explosives. However, cured HTPB rubbery polyurethanes have not been characterized in a systematic fashion as function of plasticizer content. In this study, three isocyanate-cured HTPB variants with different amounts of plasticizer have been formulated. The materials were characterized using quasi-static and dynamic compression experiments. Additionally, the shock Hugoniot was measured on the two extremes of the material—no plasticizer and maximum plasticizer.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Chen, T.K., Hwung, C.J., Hou, C.C.: Effects of number‐average molecular weight of network chain on physical properties of cis‐polybutadiene‐containing polyurethane. Polym. Eng. Sci. 32(2), 115–121 (1992)

    Article  Google Scholar 

  2. Vilar, W., Akcelrud, L.: Effect of HTPB structure on prepolymer characteristics and on mechanical properties of polybutadiene-based polyurethanes. Polym. Bull. 35(5), 635–639 (1995)

    Article  Google Scholar 

  3. Panicker, S.S., Ninan, K.: Effect of reactivity of different types of hydroxyl groups of HTPB on mechanical properties of the cured product. J. Appl. Polym. Sci. 63(10), 1313–1320 (1997)

    Article  Google Scholar 

  4. Haska, S.B., et al.: Mechanical properties of HTPB‐IPDI‐based elastomers. J. Appl. Polym. Sci. 64(12), 2347–2354 (1997)

    Article  Google Scholar 

  5. Sekkar, V., et al.: Polyurethanes based on hydroxyl terminated polybutadiene: modelling of network parameters and correlation with mechanical properties. Polymer 41(18), 6773–6786 (2000)

    Article  Google Scholar 

  6. Wingborg, N.: Increasing the tensile strength of HTPB with different isocyanates and chain extenders. Polym. Test. 21(3), 283–287 (2002)

    Article  Google Scholar 

  7. De La Fuente, J.L., Fernández‐García, M., Cerrada, M.L.: Viscoelastic behavior in a hydroxyl‐terminated polybutadiene gum and its highly filled composites: effect of the type of filler on the relaxation processes. J. Appl. Polym. Sci. 78(7), 1705–1712 (2003)

    Google Scholar 

  8. Cady, C., et al.: Mechanical properties of plastic‐bonded explosive binder materials as a function of strain‐rate and temperature. Polym. Eng. Sci. 46(6), 812–819 (2006)

    Article  Google Scholar 

  9. Siviour, C.R., et al.: High strain rate properties of a polymer-bonded sugar: their dependence on applied and internal constraints. Proc. R. Soc. A Math. Phys. Eng. Sci. 464(2093), 1229–1255 (2008)

    Article  Google Scholar 

  10. Meziere, Y., et al.: The Shock Hugoniot of hydroxy-terminated polybutadiene. In: AIP Conference Proceedings (2004)

    Google Scholar 

  11. Millett, J., Bourne, N., Akhavan, J.: The response of hydroxy-terminated polybutadiene to one-dimensional shock loading. J. Appl. Phys. 95(9), 4722–4727 (2004)

    Article  Google Scholar 

  12. Jordan, J.L., Foley, J.R., Siviour, C.R.: Mechanical properties of Epon 826/DEA epoxy. Mech. Time-Depend. Mater. 12(3), 249–272 (2008)

    Article  Google Scholar 

  13. Gorham, D.: A numerical method for the correction of dispersion in pressure bar signals. J. Phys. E Sci. Instrum. 16(6), 477 (1983)

    Article  Google Scholar 

  14. Bacon, C.: An experimental method for considering dispersion and attenuation in a viscoelastic Hopkinson bar. Exp. Mech. 38(4), 242–249 (1998)

    Article  Google Scholar 

Download references

Acknowledgments

This work was funded by the Munitions Directorate, Air Force Research Laboratory. The authors would like to thank Mr. Tomislav Kosta for his assistance with testing. Opinions, interpretations, conclusions, and recommendations are those of the authors and are not necessarily endorsed by the United States Air Force.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jennifer Jordan .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 The Society for Experimental Mechanics, Inc.

About this paper

Cite this paper

Jordan, J., Montaigne, D., Neel, C., Sunny, G., Molek, C. (2016). Shock and High Strain Rate Characterization of HTPB with Varying Plasticizer. In: Song, B., Lamberson, L., Casem, D., Kimberley, J. (eds) Dynamic Behavior of Materials, Volume 1. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-22452-7_7

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-22452-7_7

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-22451-0

  • Online ISBN: 978-3-319-22452-7

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics