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Single Pulse Voltammetry: Non-reversible and Complex Electrochemical Reactions

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Pulse Voltammetry in Physical Electrochemistry and Electroanalysis

Part of the book series: Monographs in Electrochemistry ((MOEC))

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Abstract

This chapter treats more complex electrode processes than one-electron reversible electrochemical reactions in single potential pulse techniques. The concepts given here set the basis to tackle the current–potential response in multipotential pulse electrochemical techniques (see Chaps. 4–7), which are more powerful though they also present greater theoretical complexity.

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Notes

  1. 1.

    Note that surface concentrations under stationary conditions are not uniform on the disc surface, varying from the center to the edge of the disc. Under these conditions, only the average surface concentrations are constant. For nonstationary conditions even the average surface concentrations are time dependent.

  2. 2.

    For sake of simplicity, only homogeneous, independent chemical reactions are considered in scheme (3.VI).

  3. 3.

    Note that, according with Eq. (3.180)–(3.181), surface condition (3.192a) is independent on time, since it can be written as \( {c}_{\mathrm{B}}^{\mathrm{s}}-K{c}_{\mathrm{C}}^{\mathrm{s}}=\frac{1-K{\mathrm{e}}^{\eta }}{1+{\mathrm{e}}^{\eta }}{\zeta}^{*}. \)

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  1. Department of Physical Chemistry, University of Murcia, Murcia, Spain

    Ángela Molina & Joaquín González

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  1. Ángela Molina
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Molina, Á., González, J. (2016). Single Pulse Voltammetry: Non-reversible and Complex Electrochemical Reactions. In: Pulse Voltammetry in Physical Electrochemistry and Electroanalysis. Monographs in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-21251-7_3

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