Skip to main content
SpringerLink
Log in

Copper: σ-SiH Coordination to Cu(I)

  • Chapter
  • First Online:
Synthesis and Original Reactivity of Copper and Gold Complexes

Part of the book series: Springer Theses ((Springer Theses))

  • 488 Accesses

Abstract

This chapter gives firstly an introduction concerning σ-complexes and in particular σ-SiH complexes. Afterwards, the obtained results concerning the coordination of diphosphino-hydrosilanes to Cu(I) will be described.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. G.J. Kubas, R.R. Ryan, B.I. Swanson, P.J. Vergamini, H.J. Wasserman, J. Am. Chem. Soc. 106, 451–452 (1984)

    Article  CAS  Google Scholar 

  2. G.J. Kubas, Metal Dihydrogen and σ-Bond Complexes (Kluwer Academic Publishers, New York, 2001)

    Google Scholar 

  3. G.I. Nikonov, in Advanced Organometallic Chemistry. (Elsevier, Amsterdam, 2005), pp. 217–309

    Google Scholar 

  4. J.F. Hartwig, Organotransition Metal Chemistry: From Bonding to Catalysis (University Science Books, Sausalito, 2009)

    Google Scholar 

  5. J.Y. Corey, Chem. Rev. 111, 863–1071 (2011)

    Article  CAS  Google Scholar 

  6. S. Lachaize, S. Sabo-Etienne, Eur. J. Inorg. Chem. 2006, 2115–2127 (2006)

    Article  Google Scholar 

  7. Z. Lin, Chem. Soc. Rev. 31, 239–245 (2002)

    Article  CAS  Google Scholar 

  8. U. Schubert, in Advanced Organometallic Chemistry. (Elsevier, Amsterdam, 1990), pp. 151–187

    Google Scholar 

  9. K. Pandey, Coord. Chem. Rev. 253, 37–55 (2009)

    Article  CAS  Google Scholar 

  10. M. Brookhart, M.L.H. Green, G. Parkin, Proc. Natl. Acad. Sci. 104, 6908–6914 (2007)

    Article  CAS  Google Scholar 

  11. W.H. Bernskoetter, C.K. Schauer, K.I. Goldberg, M. Brookhart, Science 326, 553–556 (2009)

    Article  CAS  Google Scholar 

  12. S.D. Pike, A.L. Thompson, A.G. Algarra, D.C. Apperley, S.A. Macgregor, A.S. Weller, Science 337, 1648–1651 (2012)

    Article  CAS  Google Scholar 

  13. G.I. Nikonov, Angew. Chem. Int. Ed. 42, 1335–1337 (2003)

    Article  CAS  Google Scholar 

  14. W. Chen, S. Shimada, M. Tanaka, Science 295, 308–310 (2002)

    Article  CAS  Google Scholar 

  15. E.C. Sherer, C.R. Kinsinger, B.L. Kormos, J.D. Thompson, C.J. Cramer, Angew. Chem. Int. Ed. 2002, 41 (1953)

    Google Scholar 

  16. G. Aullón, A. Lledós, S. Alvarez, Angew. Chem. Int. Ed. 41, 1956–1959 (2002)

    Article  Google Scholar 

  17. M. Etienne, A.S. Weller, Chem. Soc. Rev. 43, 242–259 (2013)

    Article  Google Scholar 

  18. S.K. Brayshaw, E.L. Sceats, J.C. Green, A.S. Weller, Proc. Natl. Acad. Sci. 104, 6921–6926 (2007)

    Article  CAS  Google Scholar 

  19. A.B. Chaplin, J.C. Green, A.S. Weller, J. Am. Chem. Soc. 133, 13162–13168 (2011)

    Article  CAS  Google Scholar 

  20. M. Brookhart, M.L.H. Green, J. Organomet. Chem. 250, 395–408 (1983)

    Article  CAS  Google Scholar 

  21. J. Hoyano, M. Elder, W.A.G. Graham, J. Am. Chem. Soc. 91, 4568–4569 (1969)

    Article  CAS  Google Scholar 

  22. U. Schubert, H. Gilges, Organometallics 15, 2373–2375 (1996)

    Article  CAS  Google Scholar 

  23. J. Takaya, N. Iwasawa, Organometallics 28, 6636–6638 (2009)

    Article  CAS  Google Scholar 

  24. W. Hieringer, J. Eppinger, R. Anwander, W.A. Herrmann, J. Am. Chem. Soc. 122, 11983–11994 (2000)

    Article  CAS  Google Scholar 

  25. M. Lein, J.A. Harrison, A.J. Nielson, Dalton Trans. 40, 10731 (2011)

    Article  CAS  Google Scholar 

  26. I. Corral, O. Mó, M. Yáñez, J. Phys. Chem. A 107, 1370–1376 (2003)

    Article  CAS  Google Scholar 

  27. I. Corral, O. Mó, M. Yáñez, Int. J. Mass Spectrom. 227, 401–412 (2003)

    Article  CAS  Google Scholar 

  28. A. Amgoune, D. Bourissou, Chem. Commun. 47, 859 (2011)

    Article  CAS  Google Scholar 

  29. G. Bouhadir, A. Amgoune, D. Bourissou, in Advance Organometallic Chemistry, ed. by A.F. Hill and M.J. Fink), (Academic Press, New-York, 2010), pp. 1–107

    Google Scholar 

  30. P. Gualco, A. Amgoune, K. Miqueu, S. Ladeira, D. Bourissou, J. Am. Chem. Soc. 133, 4257–4259 (2011)

    Article  CAS  Google Scholar 

  31. P. Gualco, S. Ladeira, K. Miqueu, A. Amgoune, D. Bourissou, Angew. Chem. Int. Ed. 50, 8320–8324 (2011)

    Article  CAS  Google Scholar 

  32. M.C. MacInnis, D.F. MacLean, R.J. Lundgren, R. McDonald, L. Turculet, Organometallics 26, 6522–6525 (2007)

    Article  CAS  Google Scholar 

  33. D.F. MacLean, R. McDonald, M.J. Ferguson, A.J. Caddell, L. Turculet, Chem. Commun. 2008, 5146

    Google Scholar 

  34. S.J. Mitton, R. McDonald, L. Turculet, Angew. Chem. Int. Ed. 48, 8568–8571 (2009)

    Article  CAS  Google Scholar 

  35. S.J. Mitton, R. McDonald, L. Turculet, Organometallics 28, 5122–5136 (2009)

    Article  CAS  Google Scholar 

  36. E. Morgan, D.F. MacLean, R. McDonald, L. Turculet, J. Am. Chem. Soc. 131, 14234–14236 (2009)

    Article  CAS  Google Scholar 

  37. S.J. Mitton, L. Turculet, Chem.Eur. J. 18, 15258–15262 (2012)

    Google Scholar 

  38. J. Takaya, N. Iwasawa, J. Am. Chem. Soc. 130, 15254–15255 (2008)

    Article  CAS  Google Scholar 

  39. J. Takaya, N. Iwasawa, Dalton Trans. 40, 8814 (2011)

    Article  CAS  Google Scholar 

  40. P. Gualco, M. Mercy, S. Ladeira, Y. Coppel, L. Maron, A. Amgoune, D. Bourissou, Chem.Eur. J. 16, 10808–10817 (2010)

    Google Scholar 

  41. B. Cordero, V. Gómez, A.E. Platero-Prats, M. Revés, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez, Dalton Trans. 2832–2838 (2008)

    Google Scholar 

  42. S.S. Batsanov, Inorg. Mater. 37, 871–885 (2001)

    Article  CAS  Google Scholar 

  43. M.A. Carvajal, J.J. Novoa, S. Alvarez, J. Am. Chem. Soc. 126, 1465–1477 (2004)

    Article  CAS  Google Scholar 

  44. D.V. Gutsulyak, S.F. Vyboishchikov, G.I. Nikonov, J. Am. Chem. Soc. 132, 5950–5951 (2010)

    Article  CAS  Google Scholar 

  45. J.E. Bercaw, J.A. Labinger, Proc. Natl. Acad. Sci. 104, 6899–6900 (2007)

    Article  CAS  Google Scholar 

  46. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G.A. Petersson, et al., Gaussian 09, Revision A.1, Gaussian, Inc. (Wallingford, Connecticut, USA, 2009)

    Google Scholar 

  47. A.D. Becke, J. Chem. Phys. 98, 5648–5652 (1993)

    Article  CAS  Google Scholar 

  48. K. Burke, J.P. Perdew, and Y. Wang, in Electron Density Function Theory Recent Program New Directory (eds.), by J.F. Dobson, G. Vignale, M.P. Das. (Plenum Press, New York, 1998), pp. 81–111

    Google Scholar 

  49. B. Metz, H. Stoll, M. Dolg, J. Chem. Phys. 113, 2563–2569 (2000)

    Article  CAS  Google Scholar 

  50. M. Dolg, in Model Methods Algorithms Quantum Chemistry. (ed.), by J. Grotendorst. (John-von-Neumann-Inst. For Computing, Jülich, 2000), pp. 479–508

    Google Scholar 

  51. D. Andrae, U. Häußermann, M. Dolg, H. Stoll, H. Preuß, Theor. Chim. Acta 77, 123–141 (1990)

    Article  CAS  Google Scholar 

  52. M. Dolg, U. Wedig, H. Stoll, H. Preuss, J. Chem. Phys. 86, 866–872 (1987)

    Article  CAS  Google Scholar 

  53. A.W. Ehlers, M. Böhme, S. Dapprich, A. Gobbi, A. Höllwarth, V. Jonas, K.F. Köhler, R. Stegmann, A. Veldkamp, G. Frenking, Chem. Phys. Lett. 208, 111–114 (1993)

    Article  CAS  Google Scholar 

  54. P.C. Hariharan, J.A. Pople, Theor. Chim. Acta 28, 213–222 (1973)

    Article  CAS  Google Scholar 

  55. J.K. Glendening, A.E. Badenhoop, J.E. Carpenter, J.A. Bohmann, C.M. Morales, F. Weinhold, NBO 5.0. (Theoretical Chemistry Institute, University of Wisconsin, Madison, Wisconsin, USA, 2001)

    Google Scholar 

  56. A.E. Reed, L.A. Curtiss, F. Weinhold, Chem. Rev. 88, 899–926 (1988)

    Article  CAS  Google Scholar 

  57. J.P. Foster, F. Weinhold, J. Am. Chem. Soc. 102, 7211–7218 (1980)

    Article  CAS  Google Scholar 

  58. A.E. Reed, F. Weinhold, J. Chem. Phys. 83, 1736–1740 (1985)

    Article  CAS  Google Scholar 

  59. F. London, J. Phys. Radium 8, 397–409 (1937)

    Article  CAS  Google Scholar 

  60. R. Ditchfield, Mol. Phys. 27, 789–807 (1974)

    Article  CAS  Google Scholar 

  61. K. Wolinski, J.F. Hinton, P. Pulay, J. Am. Chem. Soc. 112, 8251–8260 (1990)

    Article  CAS  Google Scholar 

  62. W. Kutzelnigg, U. Fleischer, M. Schindler, in Deuterium Shift Calculation. (Springer, Heidelberg, 1991), pp. 165–262

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS, Toulouse, France

    Maximilian Joost

Authors
  1. Maximilian Joost
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maximilian Joost .

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Joost, M. (2015). Copper: σ-SiH Coordination to Cu(I). In: Synthesis and Original Reactivity of Copper and Gold Complexes. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-18690-0_2

Download citation

Publish with us

Policies and ethics

Search

Navigation