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Nanoplasmonics, Nano-Optics, Nanocomposites, and Surface Studies pp 165–192Cite as

Spin-Crossover Nanocrystals and Ising Model

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 167))

Abstract

A compressible model of spin-crossover solid is studied in the framework of the Ising-like model with two order parameters under statistical approach where the effect of elastic strain on interaction integral is taken into account. From these considerations the relation between the order parameters during temperature changes was examined. Starting from the phenomenological Hamiltonian, entropy has been derived in mean field approach and the phase diagram which characterizes the system is analyzed numerically. Also the model for the breathing crystal field of spin-crossover solids is presented. Using Monte Carlo simulation we have systematically studied the thermal transition of spin-crossover solids for local random fields with different statistical characteristics. It is found that the breathing of crystal field provokes the broadening of the hysteresis loop, but for strong colored fluctuations its power spectrum is diminished and the width of the hysteresis loop approaches again to the deterministic one.

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Acknowledgements

The work of AIu is supported in part by the Ministry of Science and Education of Ukraine under grant No. 0113U003249.

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Authors and Affiliations

  1. Chernivtsi National University, Kotsiubynsky Str., Nr. 2, Chernivtsi, 58012, Ukraine

    Iu. Gudyma, A. Maksymov & V. Ivashko

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  1. Iu. Gudyma
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  2. A. Maksymov
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  3. V. Ivashko
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Correspondence to Iu. Gudyma .

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Editors and Affiliations

  1. Institute of Physics of NASU, Kiev, Ukraine

    Olena Fesenko

  2. Institute of Physics of NASU, Kiev, Ukraine

    Leonid Yatsenko

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Gudyma, I., Maksymov, A., Ivashko, V. (2015). Spin-Crossover Nanocrystals and Ising Model. In: Fesenko, O., Yatsenko, L. (eds) Nanoplasmonics, Nano-Optics, Nanocomposites, and Surface Studies. Springer Proceedings in Physics, vol 167. Springer, Cham. https://doi.org/10.1007/978-3-319-18543-9_10

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