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Template Guided Structuration of Polymer Films

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Polymer Surfaces in Motion
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Abstract

The ability to control polymer film structure has wide-ranging applications in the fields of optical coatings, electronics, organic photovoltaics, and biofilms. Structured polymer films can be fabricated using three broad strategies: direct deposition (such as with ink-jet printing), selective etching (such as with photolithography), and template directed structuring. Each strategy currently possesses advantages, disadvantages, and opportunities for improvement. As the methods to fabricate structured polymer films have improved, so has the associated scientific understanding of the rules governing these methods. The focus of this chapter, template guided structuring, has arisen in the past two decades to encompass several exciting techniques. In this chapter the methods and principles behind these discoveries are introduced.

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References

  1. Jeong, J.W., Park, W.I., Do, L.-M., Park, J.-H., Kim, T.-H., Chae, G., Jung, Y.S.: Nanotransfer printing with sub-10 nm resolution realized using directed self-assembly. Adv. Mater. 24, 3526–3531 (2012)

    Article  Google Scholar 

  2. Germack, D.S., Checco, A., Ocko, B.M.: Directed assembly of P3HT:PCBM blend films using a chemical template with sub-300 nm features. ACS Nano 7, 1990–1999 (2013)

    Article  Google Scholar 

  3. Ginger, D.S., Zhang, H., Mirkin, C.A.: The evolution of dip-pen nanolithography. Angew. Chem. Int. Ed. 43, 30–45 (2004)

    Article  Google Scholar 

  4. Gates, B.D., Xu, Q.B., Stewart, M., Ryan, D., Willson, C.G., Whitesides, G.M.: New approaches to nanofabrication: molding, printing, and other techniques. Chem. Rev. 105, 1171–1196 (2005)

    Article  Google Scholar 

  5. del Campo, A., Arzt, E.: Fabrication approaches for generating complex micro- and nanopatterns on polymeric surfaces. Chem. Rev. 108, 911–945 (2008)

    Article  Google Scholar 

  6. Coffey, D.C.: Characterizing the local optoelectronic performance of organic solar cells with scanning-probe microscopy. Ph.D. dissertation, University of Washington, Seattle, WA (2007)

    Google Scholar 

  7. Boltau, M., Walheim, S., Mlynek, J., Krausch, G., Steiner, U.: Surface-induced structure formation of polymer blends on patterned substrates. Nature 391, 877–879 (1998)

    Article  Google Scholar 

  8. Kargupta, K., Sharma, A.: Mesopatterning of thin liquid films by templating on chemically patterned complex substrates. Langmuir 19, 5153–5163 (2003)

    Article  Google Scholar 

  9. Kargupta, K., Sharma, A.: Morphological self-organization by dewetting in thin films on chemically patterned substrates. J. Chem. Phys. 116, 3042–3051 (2002)

    Article  Google Scholar 

  10. Kargupta, K., Sharma, A.: Creation of ordered patterns by dewetting of thin films on homogeneous and heterogeneous substrates. J. Colloid Interface Sci. 245, 99–115 (2002)

    Article  Google Scholar 

  11. Kargupta, K., Sharma, A.: Dewetting of thin films on periodic physically and chemically patterned surfaces. Langmuir 18, 1893–1903 (2002)

    Article  Google Scholar 

  12. Gennes, P.G.: Scaling Concepts in Polymer Physics. Cornell University Press, New York (1979)

    Google Scholar 

  13. McNeill, C.R., Watts, B., Thomsen, L., Belcher, W.J., Greenham, N.C., Dastoor, P.C.: Nanoscale quantitative chemical mapping of conjugated polymer blends. Nano Lett. 6, 1202–1206 (2006)

    Article  Google Scholar 

  14. Wei, J.H., Coffey, D.C., Ginger, D.S.: Nucleating pattern formation in spin-coated polymer blend films with nanoscale surface templates. J. Phys. Chem. B 110, 24324–24330 (2006)

    Article  Google Scholar 

  15. Park, L.Y., Munro, A.M., Ginger, D.S.: Controlling film morphology in conjugated polymer: fullerene blends with surface patterning. J. Am. Chem. Soc. 130, 15916–15926 (2008)

    Article  Google Scholar 

  16. Kim, S.O., Solak, H.H., Stoykovich, M.P., Ferrier, N.J., de Pablo, J.J., Nealey, P.F.: Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates. Nature 424, 411–414 (2003)

    Article  Google Scholar 

  17. Stoykovich, M.P., Nealey, P.F.: Block copolymers and conventional lithography. Mater. Today 9, 20–29 (2006)

    Article  Google Scholar 

  18. Edwards, E.W., Montague, M.F., Solak, H.H., Hawker, C.J., Nealey, P.F.: Precise control over molecular dimensions of block-copolymer domains using the interfacial energy of chemically nanopatterned substrates. Adv. Mater. 16, 1315–1319 (2004)

    Article  Google Scholar 

  19. Cheng, J.Y., Ross, C.A., Smith, H.I., Thomas, E.L.: Templated self-assembly of block copolymers: top-down helps bottom-up. Adv. Mater. 18, 2505–2521 (2006)

    Article  Google Scholar 

  20. Coffey, D.C., Ginger, D.S.: Patterning phase separation in polymer films with dip-pen nanolithography. J. Am. Chem. Soc. 127, 4564–4565 (2005)

    Article  Google Scholar 

  21. Higgins, A.M., Jones, R.: Anisotropic spinodal dewetting as a route to self-assembly of patterned surfaces. Nature 404, 476–478 (2000)

    Article  Google Scholar 

  22. Xing, R., Luo, C., Wang, Z., Han, Y.: Dewetting of polymethyl methacrylate on the patterned elastomer substrate by solvent vapor treatment. Polymer 48, 3574–3583 (2007)

    Article  Google Scholar 

  23. Roy, S., Mukherjee, R.: Ordered to isotropic morphology transition in pattern-directed dewetting of polymer thin films on substrates with different feature heights. ACS Appl. Mater. Interfaces 4, 5375–5385 (2012)

    Article  Google Scholar 

  24. Sundrani, D., Darling, S.B., Sibener, S.J.: Guiding polymers to perfection: macroscopic alignment of nanoscale domains. Nano Lett. 4, 273–276 (2004)

    Article  Google Scholar 

  25. Fasolka, M.J., Harris, D.J., Mayes, A.M., Yoon, M., Mochrie, S.: Phys. Rev. Lett. 79, 3018–3021 (1997)

    Article  Google Scholar 

  26. Wei, M., Fang, L., Lee, J., Somu, S., Xiong, X., Barry, C., Busnaina, A., Mead, J.: Directed assembly of polymer blends using nanopatterned templates. Adv. Mater. 21, 794–798 (2009)

    Article  Google Scholar 

  27. Verma, R., Sharma, A., Kargupta, K., Bhaumik, J.: Electric field induced instability and pattern formation in thin liquid films. Langmuir 21, 3710–3721 (2005)

    Article  Google Scholar 

  28. Misner, M.J., Skaff, H., Emrick, T., Russell, T.P.: Directed deposition of nanoparticles using diblock copolymer templates. Adv. Mater. 15, 221–224 (2003)

    Article  Google Scholar 

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Correspondence to David Coffey .

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Coffey, D., Wei, J. (2015). Template Guided Structuration of Polymer Films. In: Rodríguez-Hernández, J., Drummond, C. (eds) Polymer Surfaces in Motion. Springer, Cham. https://doi.org/10.1007/978-3-319-17431-0_6

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