Skip to main content

Breath Figures: Fabrication of Honeycomb Porous Films Induced by Marangoni Instabilities

  • Chapter
Book cover Polymer Surfaces in Motion

Abstract

Micro/nanoporous films have found use in many applications ranging from electronics or photonic to biotechnology. The preparation of such porous structures usually requires of the templates that need to be removed upon film preparation. As an alternative, the breath figures approach has been employed for the preparation of porous surfaces and films. This approach, the topic of this chapter, has several advantages over other techniques including the use of water as template (easily removed) and possibility of controlling the chemical composition of the pore and the external surface. Herein, the strategies reported to prepare honeycomb structured porous films by the breath figures approach are summarized. In addition, the methodologies reported to control the chemical composition of the porous films are depicted. The last part of this chapter focuses on the applications in which these films have been employed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Ostuni, E., Chen, C.S., Ingber, D.E., Whitesides, G.M.: Selective deposition of proteins and cells in arrays of microwells. Langmuir 17, 2828–2834 (2001)

    Google Scholar 

  2. Joannopoulos, J.D., Johnson, S.G., Winn, J.N., Meade, R.D.: Photonic Crystals: Molding the Flow of Light, 2nd edn. Princeton University Press, Princeton (2008)

    Google Scholar 

  3. Yoshida, M.: Novel thin film with cylindrical nanopores that open and close depending on temperature: first successful synthesis. Macromolecules 29, 8987–8989 (1996)

    Google Scholar 

  4. Hoa, M.L.K., Lu, M.H., Zhang, Y.: Preparation of porous materials with ordered hole structure. Adv. Colloid Interface Sci. 121, 9–23 (2006)

    Google Scholar 

  5. Wu, D., Xu, F., Sun, B., Fu, R., He, H., Matyjaszewski, K.: Design and preparation of porous polymers. Chem. Rev. 12(7), 3959–4015 (2012)

    Google Scholar 

  6. Cassagneau, T., Caruso, F.: Conjugated polymer inverse opals for potentiometric biosensing. Adv. Mater. 14, 1837–1841 (2002)

    Google Scholar 

  7. Hong, J.C., Park, J.H., Chun, C., Kim, D.Y.: Photoinduced tuning of optical stop bands in azopolymer based inverse opal photonic crystals. Adv. Funct. Mater. 17, 2462–2469 (2007)

    Google Scholar 

  8. You, B., Shi, L., Wen, N., Liu, X., Wu, L., Zi, J.: A facile method for fabrication of ordered porous polymer films. Macromolecules 41, 6624–6626 (2008)

    Google Scholar 

  9. Li, C., Hong, G.S., Yu, H., Qi, L.M.: Facile fabrication of honeycomb-patterned thin films of amorphous calcium carbonate and mosaic calcite. Chem. Mater. 22, 3206–3211 (2010)

    Google Scholar 

  10. Xue, M.J., Xiao, W.T., Zhang, Z.J.: Porous films from transformation of polymeric sphere arrays. Adv. Mater. 20, 439–442 (2008)

    Google Scholar 

  11. Santos, L., Martin, P., Ghilane, J., Lacaze, P.C., Randriamahazaka, H., Abrantes, L.M., et al.: Electrosynthesis of well-organized nanoporous poly(3,4-ethylenedioxythiophene) by nanosphere lithography. Electrochem. Commun. 12, 872–875 (2010)

    Google Scholar 

  12. Pietsch, T., Gindy, N., Fahmi, A.: Nano- and micro-sized honeycomb patterns through hierarchical self-assembly of metal-loaded diblock copolymer vesicles. Soft Matter 5, 2188–2197 (2009)

    Google Scholar 

  13. Shin, Y., Li, X.S., Wang, C., Coleman, J.R., Exarhos, G.J.: Synthesis of hierarchical titanium carbide from titania-coated cellulose paper. Adv. Mater. 16, 1212–1215 (2004)

    Google Scholar 

  14. Shin, Y., Wang, C., Exarhos, G.J.: Synthesis of SiC ceramics by the carbothermal reduction of mineralized wood with silica. Adv. Mater. 17, 73–77 (2005)

    Google Scholar 

  15. Huang, J., Kunitake, T.: Nano-precision replication of natural cellulosic substances by metal oxides. J. Am. Chem. Soc. 125, 11834–11835 (2003)

    Google Scholar 

  16. Meldrum, F., Seshadri, R.: Porous gold structures through templating by echinoid skeletal plates. Chem. Commun. 29–30 (2000)

    Google Scholar 

  17. Luo, R.L., Young, T.H., Sun, Y.M.: Structure formation and characterization of EVAL membranes with cosolvent of isopropanol and water. Polymer 44, 157–166 (2003)

    Google Scholar 

  18. Zhang, Y.L., Ding, H., Wei, S., Liu, S., Wang, Y.P., Xiao, F.S.: Hierarchical macroporous epoxy resin templated from single semi-fluorinated surfactant. J. Por. Mater 17, 693–698 (2010)

    Google Scholar 

  19. Tang, C.B., Bang, J., Stein, G.E., Fredrickson, G.H., Hawker, C.J., Kramer, E.J., et al.: Square packing and structural arrangement of ABC triblock copolymer spheres in thin films. Macromolecules 41, 4328–4339 (2008)

    Google Scholar 

  20. Xiang, H., Lin, Y., Russell, T.P.: Electrically induced patterning in block copolymer films. Macromolecules 37, 5358–5363 (2004)

    Google Scholar 

  21. Morikawa, Y., Nagano, S., Watanabe, K., Kamata, K., Iyoda, T., Seki, T.: Optical alignment and patterning of nanoscale microdomains in a block copolymer thin film. Adv. Mater. 18, 883–886 (2006)

    Google Scholar 

  22. Li, G., Burggraf, L.W.: Controlled patterning of polymer films using an AFM tip as a nano-hammer. Nanotechnology 18, 245302 (2007)

    Google Scholar 

  23. Behl, M., Seekamp, J., Zankovych, S., Sotomayor Torres, C.M., Zentel, R., Ahopelto, J.: Towards plastic electronics: patterning semiconducting polymers by nanoimprint lithography. Adv. Mater. 14, 588–591 (2002)

    Google Scholar 

  24. Campbell, M., Sharp, D.N., Harrison, M.T., Denning, R.G., Turberfield, A.J.: Fabrication of photonic crystals for the visible spectrum by holographic lithography. Nature 404, 53–56 (2000)

    Google Scholar 

  25. Hernandez-Guerrero, M., Stenzel, M.H.: Honeycomb structured polymer films via breath figures. Polym. Chem 3, 563–577 (2012)

    Google Scholar 

  26. Bunz, U.H.F.: Breath figures as a dynamic templating method for polymers and nanomaterials. Adv. Mater. 18, 973–989 (2006)

    Google Scholar 

  27. Muñoz-Bonilla, A., Fernández-García, M., Rodríguez-Hernández, J.: Towards hierarchically ordered functional porous polymeric surfaces prepared by the breath figures approach. Prog. Polym. Sci. 39, 510–554 (2014)

    Google Scholar 

  28. Stenzel, M.H., Barner-Kowollik, C., Davis, T.P.: Formation of honeycomb-structured, porous films via breath figures with different polymer architectures. J. Polym. Sci. A Polym. Chem 44, 2363–2375 (2006)

    Google Scholar 

  29. Escale, P., Rubatat, L., Billon, L., Save, M.: Recent advances in honeycomb-structured porous polymer films prepared via breath figures. Eur. Polym. J. 48, 1001–1025 (2012)

    Google Scholar 

  30. Srinivasarao, M., Collings, D., Philips, A., Patel, S.: Three-dimensionally ordered array of air bubbles in a polymer film. Science 292, 79–83 (2001)

    Google Scholar 

  31. Widawski, G., Rawiso, M., François, B.: Self-organized honeycomb morphology of star-polymer polystyrene films. Nature 369, 387–389 (1994)

    Google Scholar 

  32. Aitkek, J.: Breath figures. Nature 86, 516–517 (1911)

    Google Scholar 

  33. Aitkek, J.: Breath figures. Nature 90, 619–621 (1912)

    Google Scholar 

  34. Giltay, J.W.: Breath figures. Nature 86, 585–586 (1911)

    Google Scholar 

  35. Rayleigh, L.: Breath figures. Nature 86, 416–417 (1911)

    Google Scholar 

  36. Rayleigh, L.: Breath figures. Nature 90, 436–438 (1912)

    Google Scholar 

  37. Jenekhe, S.A., Chen, X.L.: Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 283, 372–375 (1999)

    Google Scholar 

  38. Sun, H., Wu, L.X.: Ordered honeycomb-patterned films via breath figures. Prog. Chem 22, 1784–1798 (2010)

    Google Scholar 

  39. Beysens, D., Steyer, A., Guenoun, P., Fritter, D., Knobler, C.M.: How does dew form? Phase Trans 31, 219–246 (1991)

    Google Scholar 

  40. Beysens, D.: The formation of dew. Atmos. Res 39, 215–237 (1995)

    Google Scholar 

  41. Beysens, D.: Dew nucleation and growth. Compt. Rend. Phys 7, 1082–1100 (2006)

    Google Scholar 

  42. Fritter, D., Knobler, C.M., Beysens, D.A.: Experiments and simulation of the growth of droplets on a surface (breath figures). Phys. Rev. A 43, 2858–2869 (1991)

    Google Scholar 

  43. Family, F., Meakin, P.: Scaling of the droplet-size distribution in vapor-deposited thin films. Phys. Rev. Lett. 61, 428–431 (1988)

    Google Scholar 

  44. Fritter, D., Knobler, C.M., Roux, D., Beysens, D.: Computer simulations of the growth of breath figures. J. Stat. Phys 52, 1447–1459 (1988)

    Google Scholar 

  45. Briscoe, B.J., Galvin, K.P.: Breath figures. J. Phys. D Appl. Phys. 23, 1265 (1990)

    Google Scholar 

  46. Narhe, R.D., Khandkar, M.D., Shelke, P.B., Limaye, A.V., Beysens, D.A.: Condensation-induced jumping water drops. Phys. Rev. E Stat. Nonlin. Soft Matter Phys. 80(3 Pt 1), 031604 (2009)

    Google Scholar 

  47. Rogers, T.M., Elder, K.R., Desai, R.C.: Droplet growth and coarsening during heterogeneous vapor condensation. Phys. Rev. A 38, 5303–5309 (1988)

    Google Scholar 

  48. Beysens, D., Knobler, C.M.: Growth of breath figures. Phys. Rev. Lett. 57, 1433–1436 (1986)

    Google Scholar 

  49. Blaschke, J., Lapp, T., Hof, B., Vollmer, J.: Breath figures: nucleation, growth, coalescence, and the size distribution of droplets. Phys. Rev. Lett. 109, 068701 (2012)

    Google Scholar 

  50. Gau, H., Mönch, W., Herminghaus, S.: Coalescence dynamics of ordered breath figures. Prog. Coll. Polym. Sci 110, 34–36 (1998)

    Google Scholar 

  51. Gau, H., Herminghaus, S.: Ripening of ordered breath figures. Phys. Rev. Lett. 84, 4156 (2000)

    Google Scholar 

  52. Lopez, G., Biebuyck, H., Frisbie, C., Whitesides, G.: Imaging of features on surfaces by condensation figures. Science 260, 647–649 (1993)

    Google Scholar 

  53. Knobler, C.M., Beysens, D.: Growth of breath figures on fluid surfaces. Europhys. Lett 6, 707–712 (1988)

    Google Scholar 

  54. Bormashenko, E., Pogreb, R., Stanevsky, O., Bormashenko, Y., Stein, T., Gengelman, O.: Mesoscopic patterning in evaporated polymer solutions: new experimental data and physical mechanisms. Langmuir 21, 9604–9609 (2005)

    Google Scholar 

  55. Bormashenko, E., Pogreb, R., Musin, A., Stanevsky, O., Bormashenko, Y., Whyman, G., et al.: Patterning in rapidly evaporated polymer solutions: formation of annular structures under evaporation of the poor solvent. J. Colloid Interface Sci. 300, 293–297 (2006)

    Google Scholar 

  56. Bormashenko, E., Musin, A., Pogreb, R., Bormashenko, Y., Gendelman, O.: Self-assembled patterns obtained with evaporated polymer solutions and pre-stretched polymer substrates. Colloids Surf. A Physicochem. Eng. Asp. 303, 253–256 (2007)

    Google Scholar 

  57. Bormashenko, E., Balter, S., Pogreb, R., Bormashenko, Y., Gendelman, O., Aurbach, D.: On the mechanism of patterning in rapidly evaporated polymer solutions: is temperature-gradient-driven Marangoni instability responsible for the large-scale patterning? J. Colloid Interface Sci. 343, 602–607 (2010)

    Google Scholar 

  58. Barrow, M.S., Jones, R.L., Park, J.O., Srinivasarao, M., Williams, P.R., Wright, C.J.: Physical characterisation of microporous and nanoporous polymer films by atomic force microscopy, scanning electron microscopy and high speed video microphotography. Spectroscopy 18, 577–585 (2004)

    Google Scholar 

  59. Kuo, C.T., Lin, Y.S., Liu, T.K., Liu, H.C., Hung, W.C., Jiang, I.M., et al.: Dynamics of single-layer polymer breath figures. Opt. Express 18, 18464–18470 (2010)

    Google Scholar 

  60. Maruyama, N., Koito, T., Nishida, J., Sawadaishi, T., Cieren, X., Ijiro, K., et al.: Mesoscopic patterns of molecular aggregates on solid substrates. Thin Solid Films 327, 854–856 (1998)

    Google Scholar 

  61. Wong, K., Hernández-Guerrero, M., Granville, A., Davis, T., Barner-Kowollik, C., Stenzel, M.: Water-assisted formation of honeycomb structured porous films. J. Por. Mater 13, 213–223 (2006)

    Google Scholar 

  62. Kasai, W., Kondo, T.: Fabrication of honeycomb-patterned cellulose films. Macromol. Biosci. 4, 17–21 (2004)

    Google Scholar 

  63. Wang, Y., Liu, Z., Huang, Y., Han, B., Yang, G.: Micropatterned polymer surfaces induced by nonsolvent. Langmuir 22, 1928–1931 (2006)

    Google Scholar 

  64. Govor, L.V., Bashmakov, I.A., Kiebooms, R., Dyakonov, V., Parisi, J.: Self-organized networks based on conjugated polymers. Adv. Mater. 13, 588–591 (2001)

    Google Scholar 

  65. Angus, S.D., Davis, T.P.: Polymer surface design and informatics: facile microscopy/image analysis techniques for self-organizing microporous polymer film characterization. Langmuir 18, 9547–9553 (2002)

    Google Scholar 

  66. Madej, W., Budkowski, A., Raczkowska, J., Rysz, J.: Breath figures in polymer and polymer blend films spin-coated in dry and humid ambience. Langmuir 24, 3517–3524 (2008)

    Google Scholar 

  67. Park, M.S., Kim, J.K.: Broad-band antireflection coating at near-infrared wavelengths by a breath figure. Langmuir 21, 11404–11408 (2005)

    Google Scholar 

  68. Park, M.S., Joo, W., Kim, J.K.: Porous structures of polymer films prepared by spin coating with mixed solvents under humid condition. Langmuir 22, 4594–4598 (2006)

    Google Scholar 

  69. Orlov, M., Tokarev, I., Scholl, A., Doran, A., Minko, S.: pH-Responsive thin film membranes from poly(2-vinylpyridine): water vapor-induced formation of a microporous structure. Macromolecules 40, 2086–2091 (2007)

    Google Scholar 

  70. Muñoz-Bonilla, A., Ibarboure, E., Papon, E., Rodriguez-Hernandez, J.: Engineering polymer surfaces with variable chemistry and topography. J. Polym. Sci. A Polym. Chem 47, 2262–2271 (2009)

    Google Scholar 

  71. Pilati, F., Montecchi, M., Fabbri, P., Synytska, A., Messori, M., Toselli, M., et al.: Design of surface properties of PET films: effect of fluorinated block copolymers. J. Colloid Interface Sci. 315, 210–222 (2007)

    Google Scholar 

  72. Yabu, H., Tanaka, M., Ijiro, K., Shimomura, M.: Preparation of honeycomb-patterned polyimide films by self-organization. Langmuir 19, 6297–6300 (2003)

    Google Scholar 

  73. Nishikawa, T., Nonomura, M., Arai, K., Hayashi, J., Sawadaishi, T., Nishiura, Y., et al.: Micropatterns based on deformation of a viscoelastic honeycomb mesh. Langmuir 19, 6193–6201 (2003)

    Google Scholar 

  74. Song, L., Bly, R.K., Wilson, J.N., Bakbak, S., Park, J.O., Srinivasarao, M., et al.: Facile microstructuring of organic semiconducting polymers by the breath figure method: hexagonally ordered bubble arrays in rigid rod-polymers. Adv. Mater. 16, 115–118 (2004)

    Google Scholar 

  75. Boker, A., Lin, Y., Chiapperini, K., Horowitz, R., Thompson, M., Carreon, V., et al.: Hierarchical nanoparticle assemblies formed by decorating breath figures. Nat. Mater. 3, 302–306 (2004)

    Google Scholar 

  76. Roszol, L., Lawson, T., Koncz, V., Noszticzius, Z., Wittmann, M., Sarkadi, T., et al.: Micropatterned polyvinyl butyral membrane for acid-base diodes. J. Phys. Chem. B 114, 13718–13725 (2010)

    Google Scholar 

  77. Hiwatari, K., Serizawa, T., Seto, F., Kishida, A., Muraoka, Y., Akashi, M.: Graft copolymers having hydrophobic backbone and hydrophilic branches XXXIV. Fabrication and control of honeycomb structure prepared from amphiphilic graft copolymers. Polym J 33, 669–675 (2001)

    Google Scholar 

  78. Nishikawa, T., Ookura, R., Nishida, J., Arai, K., Hayashi, J., Kurono, N., et al.: Fabrication of honeycomb film of an amphiphilic copolymer at the air–water interface. Langmuir 18, 5734–5740 (2002)

    Google Scholar 

  79. Connal, L.A., Gurr, P.A., Qiao, G.G., Solomon, D.H.: From well defined star-microgels to highly ordered honeycomb films. J. Mater. Chem. 15, 1286–1292 (2005)

    Google Scholar 

  80. Cheng, C.X., Tian, Y., Shi, Y.Q., Tang, R.P., Xi, F.: Porous polymer films and honeycomb structures based on amphiphilic dendronized block copolymers. Langmuir 21, 6576–6581 (2005)

    Google Scholar 

  81. Escalé, P., Rubatat, L., Derail, C., Save, M., Billon, L.: pH sensitive hierarchically self-organized bioinspired films. Macromol. Rapid Commun 32, 1072–1076 (2011)

    Google Scholar 

  82. Karthaus, O., Maruyama, N., Cieren, X., Shimomura, M., Hasegawa, H., Hashimoto, T.: Water-assisted formation of micrometer-size honeycomb patterns of polymers. Langmuir 16, 6071–6076 (2000)

    Google Scholar 

  83. Bai, H., Du, C., Zhang, A., Li, L.: Breath figure arrays: unconventional fabrications, functionalizations, and applications. Angew. Chem. Int. Ed. Engl. 52, 12240–12255 (2013)

    Google Scholar 

  84. Lide, D.R.: Handbook of Chemistry and Physics, 80th edn. CRC, Boca Raton (1999)

    Google Scholar 

  85. Barner-Kowollik, C., Dalton, H., Davis, T.P., Stenzel, M.H.: Nano- and micro-engineering of ordered porous blue-light-emitting films by templating well-defined organic polymers around condensing water droplets. Angew. Chem. Int. Ed. 42, 3664–3668 (2003)

    Google Scholar 

  86. Yabu, H., Shimomura, M.: Single-step fabrication of transparent superhydrophobic porous polymer films. Chem. Mater. 17, 5231–5234 (2005)

    Google Scholar 

  87. Yunus, S., Delcorte, A., Poleunis, C., Bertrand, P., Bolognesi, A., Botta, C.: A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging. Adv. Funct. Mater. 17, 1079–1084 (2007)

    Google Scholar 

  88. Zhu, L.W., Wan, L.S., Jin, J., Xu, Z.K.: Honeycomb porous films prepared from porphyrin-cored star polymers: submicrometer pores induced by transition of monolayer into multilayer structures. J. Phys. Chem. C 117, 6185–6194 (2013)

    Google Scholar 

  89. Ding, J., Zhang, A., Bai, H., Li, L., Li, J., Ma, Z.: Breath figure in non-aqueous vapor. Soft Matter 9, 506–514 (2013)

    Google Scholar 

  90. Harkins, W.D., Feldman, A.: Films the spreading of liquids and the spreading coefficient. J. Am. Chem. Soc. 44, 2665–2685 (1922)

    Google Scholar 

  91. Jiang, X., Gu, J., Shen, Y., Wang, S., Tian, X.: Formation of honeycomb-patterned microporous films based on a fluorinated poly(siloxane imide) segmented copolymer. J. Appl. Polym. Sci. 119, 3329–3337 (2011)

    Google Scholar 

  92. Li, J., Zhao, Q.L., Chen, J.Z., Li, L., Huang, J., Ma, Z., et al.: Highly ordered microporous films containing a polyolefin segment fabricated by the breath-figure method using well-defined polymethylene-b-polystyrene copolymers. Polym. Chem 1, 164–167 (2010)

    Google Scholar 

  93. Wang, C.Y., Mao, Y.D., Wang, D.Y., Qu, Q.S., Yang, G.J., Hu, X.Y.: Fabrication of highly ordered microporous thin films by PS-b-PAA self-assembly and investigation of their tunable surface properties. J. Mater. Chem. 18, 683–690 (2008)

    Google Scholar 

  94. Wu, X.J., Jones, M.D., Davidson, M.G., Chaudhuri, J.B., Ellis, M.J.: Surfactant-free poly(lactide-co-glycolide) honeycomb films for tissue engineering: relating solvent, monomer ratio and humidity to scaffold structure. Biotechnol. Lett. 33, 423–430 (2011)

    Google Scholar 

  95. Zhang, Z., Hughes, T.C., Gurr, P.A., Blencowe, A., Uddin, H., Hao, X., et al.: The behaviour of honeycomb film formation from star polymers with various fluorine content. Polymer 54, 4446–4454 (2013)

    Google Scholar 

  96. de León, A.S., del Campo, A., Fernández-García, M., Rodríguez-Hernández, J., Muñoz-Bonilla, A.: Hierarchically structured multifunctional porous interfaces through water templated self-assembly of ternary systems. Langmuir 28, 9778–9787 (2012)

    Google Scholar 

  97. Chen, S., Alvès, M., Save, M., Billon, L.: Synthesis of amphiphilic diblock copolymers derived from renewable dextran by nitroxide mediated polymerization: towards hierarchically structured honeycomb porous films. Polym. Chem. 5(18), 53105 (2014). doi:10.1039/C4PY00390J

    Google Scholar 

  98. Dong, W.Y., Zhou, Y.F., Yan, D.Y., Mai, Y.Y., He, L., Jin, C.Y.: Honeycomb-structured microporous films made from hyperbranched polymers by the breath figure method. Langmuir 25, 173–178 (2009)

    Google Scholar 

  99. Qin, S., Li, H., Yuan, W.Z., Zhang, Y.M.: Fabrication of polymeric honeycomb microporous films: breath figures strategy and stabilization of water droplets by fluorinated diblock copolymer micelles. J. Mater. Sci. 47, 6862–6871 (2012)

    Google Scholar 

  100. de Leon, A.S., Del Campo, A., Cortajarena, A.L., Fernandez-Garcia, M., Munoz-Bonilla, A., Rodriguez-Hernandez, J.: Formation of multigradient porous surfaces for selective bacterial entrapment. Biomacromolecules 15, 3338–3348 (2014)

    Google Scholar 

  101. Hayakawa, T., Horiuchi, S.: From angstroms to micrometers: self-organized hierarchical structure within a polymer film. Angew. Chem. Int. Ed. Engl. 42, 2285–2289 (2003)

    Google Scholar 

  102. Ejima, H., Iwata, T., Yoshie, N.: Morphology-retaining carbonization of honeycomb-patterned hyperbranched poly(phenylene vinylene) film. Macromolecules 41, 9846–9848 (2008)

    Google Scholar 

  103. Tian, Y., Liu, S., Ding, H.Y., Wang, L.H., Liu, B.Q., Shi, Y.Q.: Formation of honeycomb-patterned polyetherketone cardo (PEK-C) films in a highly humid atmosphere. Macromol. Chem. Phys 207, 1998–2005 (2006)

    Google Scholar 

  104. Servoli, E., Ruffo, G.A., Migliaresi, C.: Interplay of kinetics and interfacial interactions in breath figure templating - A phenomenological interpretation. Polymer 51, 2337–2344 (2010)

    Google Scholar 

  105. Xiong, X.P., Lin, M.F., Zou, W.W., Liu, X.Y.: Kinetic control of preparing honeycomb patterned porous film by the method of breath figure. React. Funct. Polym. 71, 964–971 (2011)

    Google Scholar 

  106. Billon, L., Manguian, M., Pellerin, V., Joubert, M., Eterradossi, O., Garay, H.: Tailoring highly ordered honeycomb films based on ionomer macromolecules by the bottom-up approach. Macromolecules 42, 345–356 (2009)

    Google Scholar 

  107. Cong, H.L., Wang, J.L., Yu, B., Tang, J.G.: Preparation of a highly permeable ordered porous microfiltration membrane of brominated poly(phenylene oxide) on an ice substrate by the breath figure method. Soft Matter 8, 8835–8839 (2012)

    Google Scholar 

  108. Honglawan, A., Yang, S.: Evaporative assembly of ordered microporous films and their hierarchical structures from amphiphilic random copolymers. Soft Matter 8, 11897–11904 (2012)

    Google Scholar 

  109. Yabu, H., Jia, R., Matsuo, Y., Ijiro, K., Yamamoto, S., Nishino, F., et al.: Preparation of highly oriented nano-pit arrays by thermal shrinking of honeycomb-patterned polymer films. Adv. Mater. 20, 4200–4204 (2008)

    Google Scholar 

  110. Li, J., Peng, J., Huang, W.H., Wu, Y., Fu, J., Cong, Y., et al.: Ordered honeycomb-structured gold nanoparticle films with changeable pore morphology: from circle to ellipse. Langmuir 21, 2017–2021 (2005)

    Google Scholar 

  111. Escale, P., Van Camp, W., Du Prez, F., Rubatat, L., Billon, L., Save, M.: Highly structured pH-responsive honeycomb films by a combination of a breath figure process and in situ thermolysis of a polystyrene-block-poly(ethoxy ethyl acrylate) precursor. Polym. Chem 4, 4710–4717 (2013)

    Google Scholar 

  112. Yabu, H., Shimomura, M.: Mesoscale pincushions, microrings, and microdots prepared by heating and peeling of self-organized honeycomb-patterned films deposited on a solid substrate. Langmuir 22, 4992–4997 (2006)

    Google Scholar 

  113. Saito, Y., Kawano, T., Shimomura, M., Yabu, H.: Fabrication of mussel-inspired highly adhesive honeycomb films containing catechol groups and their applications for substrate-independent porous templates. Macromol. Rapid Comm 34, 630–634 (2013)

    Google Scholar 

  114. Pessoni, L., Lacombe, S., Billon, L., Brown, R., Save, M.: Photoactive, porous honeycomb films prepared from rose bengal-grafted polystyrene. Langmuir 29, 10264–10271 (2013)

    Google Scholar 

  115. Dong, R.H., Yan, J.L., Ma, H.M., Fang, Y., Hao, J.C.: Dimensional architecture of ferrocenyl-based oligomer honeycomb-patterned films: from monolayer to multilayer. Langmuir 27, 9052–9056 (2011)

    Google Scholar 

  116. Limaye, A.V., Narhe, R.D., Dhote, A.M., Ogale, S.B.: Evidence for convective effects in breath figure formation on volatile fluid surfaces. Phys. Rev. Lett. 76, 3762–3765 (1996)

    Google Scholar 

  117. Xu, S., Li, M., Mitov, Z., Kumacheva, E.: Surface textures induced by convection in thin films of polymeric and polymerizable fluids. Prog. Org. Coat. 48, 227–235 (2003)

    Google Scholar 

  118. Sun, H., Li, H.L., Bu, W.F., Xu, M., Wu, L.X.: Self-organized microporous structures based on surfactant-encapsulated polyoxometalate complexes. J. Phys. Chem. B 110, 24847–24854 (2006)

    Google Scholar 

  119. Bolognesi, A., Mercogliano, C., Yunus, S., Civardi, M., Comoretto, D., Turturro, A.: Self-organization of polystyrenes into ordered microstructured films and their replication by soft lithography. Langmuir 21, 3480–3485 (2005)

    Google Scholar 

  120. Pitois, O., Francois, B.: Formation of ordered micro-porous membranes. Eur. Phys. J. B 8, 225–231 (1999)

    Google Scholar 

  121. Ghannam, L., Manguian, M., Francois, J., Billon, L.: A versatile route to functional biomimetic coatings: ionomers for honeycomb-like structures. Soft Matter 3, 1492–1499 (2007)

    Google Scholar 

  122. Escalé, P., Save, M., Lapp, A., Rubatat, L., Billon, L.: Hierarchical structures based on self-assembled diblock copolymers within honeycomb micro-structured porous films. Soft Matter 6, 3202–3210 (2010)

    Google Scholar 

  123. Li, L., Chen, C.K., Zhang, A.J., Liu, X.Y., Cui, K., Huang, J., et al.: Fabrication of robust honeycomb polymer films: a facile photochemical cross-linking process. J. Colloid Interface Sci. 331, 446–452 (2009)

    Google Scholar 

  124. Du, C., Zhang, A., Bai, H., Li, L.: Robust microsieves with excellent solvent resistance: cross-linkage of perforated polymer films with honeycomb structure. ACS Macro Lett 2, 27–30 (2013)

    Google Scholar 

  125. de Boer, B., Stalmach, U., van Hutten, P.F., Melzer, C., Krasnikov, V.V., Hadziioannou, G.: Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers. Polymer 42, 9097–9109 (2001)

    Google Scholar 

  126. Heng, L.P., Zhai, J., Zhao, Y., Xu, J.J., Sheng, X.L., Jiang, L.: Enhancement of photocurrent generation by honeycomb structures in organic thin films. Chemphyschem 7, 2520–2525 (2006)

    Google Scholar 

  127. Lin, C.L., Tung, P.H., Chang, F.C.: Synthesis of rod-coil diblock copolymers by ATRP and their honeycomb morphologies formed by the ‘breath figures’ method. Polymer 46, 9304–9313 (2005)

    Google Scholar 

  128. Chiu, Y.C., Kuo, C.C., Lin, C.J., Chen, W.C.: Highly ordered luminescent microporous films prepared from crystalline conjugated rod-coil diblock copolymers of PF-b-PSA and their superhydrophobic characteristics. Soft Matter 7, 9350–9358 (2011)

    Google Scholar 

  129. Francois, B., Pitois, O., Francois, J.: Polymer films with a self-organized honeycomb morphology. Adv. Mater. 7, 1041–1044 (1995)

    Google Scholar 

  130. Hsu, J.C., Sugiyama, K., Chiu, Y.C., Hirao, A., Chen, W.C.: Synthesis of new star-shaped polymers with styrene-fluorene conjugated moieties and their multicolor luminescent ordered microporous films. Macromolecules 43, 7151–7158 (2010)

    Google Scholar 

  131. Zhang, C., Wang, X., Min, K., Lee, D., Wei, C., Schulhauser, H., et al.: Developing porous honeycomb films using miktoarm star copolymers and exploring their application in particle separation. Macromol. Rapid Comm 35, 221–227 (2014)

    Google Scholar 

  132. Connal, L.A., Qiao, G.G.: Preparation of porous poly(dimethylsiloxane)-based honeycomb materials with hierarchal surface features and their use as soft-lithography templates. Adv. Mater. 18, 3024–3028 (2006)

    Google Scholar 

  133. Connal, L.A., Vestberg, R., Gurr, P.A., Hawker, C.J., Qiao, G.G.: Patterning on nonplanar substrates: flexible honeycomb films from a range of self-assembling star copolymers. Langmuir 24, 556–562 (2008)

    Google Scholar 

  134. Hernandez-Guerrero, M., Davis, T.P., Barner-Kowollik, C., Stenzel, M.H.: Polystyrene comb polymers built on cellulose or poly(styrene-co-2-hydroxyethylmethacrylate) backbones as substrates for the preparation of structured honeycomb films. Eur. Polym. J. 41, 2264–2277 (2005)

    Google Scholar 

  135. Walter, M.V., Lundberg, P., Hult, D., Hult, A., Malkoch, M.: A one component methodology for the fabrication of honeycomb films from biocompatible amphiphilic block copolymer hybrids: a linear-dendritic-linear twist. Polym. Chem 4, 2680–2690 (2013)

    Google Scholar 

  136. Blencowe, A., Tan, J.F., Goh, T.K., Qiao, G.G.: Core cross-linked star polymers via controlled radical polymerisation. Polymer 50, 5–32 (2009)

    Google Scholar 

  137. Gao, H.F., Ohno, S., Matyjaszewski, K.: Low polydispersity star polymers via cross-linking macromonomers by ATRP. J. Am. Chem. Soc. 128, 15111–15113 (2006)

    Google Scholar 

  138. Helms, B., Guillaudeu, S.J., Xie, Y., McMurdo, M., Hawker, C.J., Frechet, J.M.J.: One-pot reaction cascades using star polymers with core-confined catalysts. Angew. Chem. Int. Ed. 44, 6384–6387 (2005)

    Google Scholar 

  139. Beattie, D., Wong, K.H., Williams, C., Poole-Warren, L.A., Davis, T.P., Barner-Kowollik, C., et al.: Honeycomb-structured porous films from polypyrrole-containing block copolymers prepared via RAFT polymerization as a scaffold for cell growth. Biomacromolecules 7, 1072–1082 (2006)

    Google Scholar 

  140. Wong, K.H., Davis, T.P., Bamer-Kowollik, C., Stenzel, M.H.: Honeycomb structured porous films from amphiphilic block copolymers prepared via RAFT polymerization. Polymer 48, 4950–4965 (2007)

    Google Scholar 

  141. Escalé, P., Ting, S.R.S., Khoukh, A., Rubatat, L., Save, M., Stenzel, M.H., et al.: Synthetic route effect on macromolecular architecture: from block to gradient copolymers based on acryloyl galactose monomer using RAFT polymerization. Macromolecules 44, 5911–5919 (2011)

    Google Scholar 

  142. Xue, Y., Lu, H.-C., Zhao, Q.-L., Huang, J., Xu, S.-G., Cao, S.-K., et al.: Polymethylene-b-poly(styrene-co-2,3,4,5,6-pentafluoro styrene) copolymers: synthesis and fabrication of their porous films. Polym. Chem 4, 307–312 (2013)

    Google Scholar 

  143. Yabu, H., Takebayashi, M., Tanaka, M., Shimomura, M.: Superhydrophobic and lipophobic properties of self-organized honeycomb and pincushion structures. Langmuir 21, 3235–3237 (2005)

    Google Scholar 

  144. Muñoz-Bonilla, A., Ibarboure, E., Papon, E., Rodriguez-Hernandez, J.: Self-organized hierarchical structures in polymer surfaces: self-assembled nanostructures within breath figures. Langmuir 25, 6493–6499 (2009)

    Google Scholar 

  145. Zhu, L.-W., Ou, Y., Wan, L.-S., Xu, Z.-K.: Polystyrenes with hydrophilic end groups: synthesis, characterization, and effects on the self-assembly of breath figure arrays. J. Phys. Chem. B 118, 845–854 (2014)

    Google Scholar 

  146. Stenzel, M.H., Davis, T.P.: Biomimetic honeycomb-structured surfaces formed from block copolymers incorporating acryloyl phosphorylcholine. Aust. J. Chem 56, 1035–1038 (2003)

    Google Scholar 

  147. Samanta, S., Chatterjee, D.P., Layek, R.K., Nandi, A.K.: Multifunctional porous poly(vinylidene fluoride)-graft-poly(butyl methacrylate) with good Li + ion conductivity. Macromol. Chem. Phys 212, 134–149 (2011)

    Google Scholar 

  148. De León, A.S., Del Campo, A., Fernández-García, M., Rodríguez-Hernández, J., Muñoz-Bonilla, A.: Fabrication of structured porous films by breath figures and phase separation processes: tuning the chemistry and morphology inside the pores using click chemistry. ACS Appl. Mater. Interfaces 5, 3943–3951 (2013)

    Google Scholar 

  149. Peng, J., Han, Y., Fu, J., Yang, Y., Li, B.: Formation of regular hole pattern in polymer films. Macromol. Chem. Phys 204, 125–130 (2003)

    Google Scholar 

  150. Connal, L.A., Qiao, G.G.: Honeycomb coated particles: porous doughnuts, golf balls and hollow porous pockets. Soft Matter 3, 837–839 (2007)

    Google Scholar 

  151. Bormashenko, E., Schechter, A., Stanevsky, O., Stein, T., Balter, S., Musin, A., et al.: Free-standing, thermostable, micrometer-scale honeycomb polymer films and their properties. Macromol. Mater. Eng 293, 872–877 (2008)

    Google Scholar 

  152. Tsai, H., Xu, Z., Pai, R.K., Wang, L., Dattelbaum, A.M., Shreve, A.P., et al.: Structural dynamics and charge transfer via complexation with fullerene in large area conjugated polymer honeycomb thin films†. Chem. Mater. 23, 759–761 (2010)

    Google Scholar 

  153. Stenzel, M.H., Davis, T.P., Fane, A.G.: Honeycomb structured porous films prepared from carbohydrate based polymers synthesized via the RAFT process. J. Mater. Chem. 13, 2090–2097 (2003)

    Google Scholar 

  154. Ke, B.B., Wan, L.S., Zhang, W.X., Xu, Z.K.: Controlled synthesis of linear and comb-like glycopolymers for preparation of honeycomb-patterned films. Polymer 51, 2168–2176 (2010)

    Google Scholar 

  155. Ting, S.R.S., Min, E.H., Escale, P., Save, M., Billon, L., Stenzel, M.H.: Lectin recognizable biomaterials synthesized via nitroxide-mediated polymerization of a methacryloyl galactose monomer. Macromolecules 42, 9422–9434 (2009)

    Google Scholar 

  156. Nurmawati, M.H., Ajikumar, P.K., Renu, R., Valiyaveettil, S.: Hierarchical self-organization of nanomaterials into two-dimensional arrays using functional polymer scaffold. Adv. Funct. Mater. 18, 3213–3218 (2008)

    Google Scholar 

  157. Jiang, X., Zhou, X., Zhang, Y., Zhang, T., Guo, Z., Gu, N.: Interfacial effects of in situ-synthesized Ag nanoparticles on breath figures. Langmuir 26, 2477–2483 (2010)

    Google Scholar 

  158. Muñoz-Bonilla, A., Ibarboure, E., Bordegé, V., Fernández-García, M., Rodríguez-Hernández, J.: Fabrication of honeycomb-structured porous surfaces decorated with glycopolymers. Langmuir 26, 8552–8558 (2010)

    Google Scholar 

  159. De León, A.S., Del Campo, A., Fernández-García, M., Rodríguez-Hernández, J., Muñoz-Bonilla, A.: Tuning the pore composition by two simultaneous interfacial self-assembly processes: breath figures and coffee stain. Langmuir 30, 6134–6141 (2014)

    Google Scholar 

  160. Cui, L., Peng, J., Ding, Y., Li, X., Han, Y.C.: Ordered porous polymer films via phase separation in humidity environment. Polymer 46, 5334–5340 (2005)

    Google Scholar 

  161. Galeotti, F., Calabrese, V., Cavazzini, M., Quici, S., Poleunis, C., Yunus, S., et al.: Self-functionalizing polymer film surfaces assisted by specific polystyrene end-tagging. Chem. Mater. 22, 2764–2769 (2010)

    Google Scholar 

  162. Hernandez-Guerrero, M., Min, E., Barner-Kowollik, C., Muller, A.H.E., Stenzel, M.H.: Grafting thermoresponsive polymers onto honeycomb structured porous films using the RAFT process. J. Mater. Chem. 18, 4718–4730 (2008)

    Google Scholar 

  163. Wenzel, R.N.: Resistance of solid surfaces to wetting by water. Ind. Eng. Chem. 28, 988–994 (1936)

    Google Scholar 

  164. Cassie, A.B.D., Baxter, S.: Wettability of porous surfaces. Trans. Faraday Soc. 40, 546–551 (1944)

    Google Scholar 

  165. Wan, L.-S., Lv, J., Ke, B.-B., Xu, Z.-K.: Facilitated and site-specific assembly of functional polystyrene microspheres on patterned porous films. ACS Appl. Mater. Interfaces 2, 3759–3765 (2010)

    Google Scholar 

  166. Ke, B.-B., Wan, L.-S., Li, Y., Xu, M.-Y., Xu, Z.-K.: Selective layer-by-layer self-assembly on patterned porous films modulated by Cassie-Wenzel transition. Phys. Chem. Chem. Phys. 13, 4881–4887 (2011)

    Google Scholar 

  167. De León, A.S., Campo, A.D., Labrugère, C., Fernández-García, M., Muñoz-Bonilla, A., Rodríguez-Hernández, J.: Control of the chemistry outside the pores in honeycomb patterned films. Polym. Chem 4, 4024–4032 (2013)

    Google Scholar 

  168. Sun, H., Li, H.L., Wu, L.X.: Micro-patterned polystyrene surfaces directed by surfactant-encapsulated polyoxometalate complex via breath figures. Polymer 50, 2113–2122 (2009)

    Google Scholar 

  169. Ma, H., Cui, J., Chen, J., Hao, J.: Self-organized polymer nanocomposite inverse opal films with combined optical properties. Chemistry 17, 655–660 (2011)

    Google Scholar 

  170. Deleuze, C., Derail, C., Delville, M.H., Billon, L.: Hierarchically structured hybrid honeycomb films via micro to nanosized building blocks. Soft Matter 8, 8559–8562 (2012)

    Google Scholar 

  171. Ma, H., Cui, J., Song, A., Hao, J.: Fabrication of freestanding honeycomb films with through-pore structures via air/water interfacial self-assembly. Chem. Commun. 47, 1154–1156 (2011)

    Google Scholar 

  172. Wong, K.H., Davis, T.P., Barner-Kowollik, C., Stenzel, M.H.: Gold-loaded organic/inorganic nanocomposite honeycomb membranes. Aust. J. Chem 59, 539–543 (2006)

    Google Scholar 

  173. Kong, L., Dong, R., Ma, H., Hao, J.: Au NP honeycomb-patterned films with controllable pore size and their surface-enhanced Raman scattering. Langmuir 29, 4235–4241 (2013)

    Google Scholar 

  174. Vohra, V., Bolognesi, A., Calzaferri, G., Botta, C.: Multilevel organization in hybrid thin films for optoelectronic applications. Langmuir 25, 12019–12023 (2009)

    Google Scholar 

  175. Zou, J., Chen, H., Chunder, A., Yu, Y., Huo, Q., Zhai, L.: Preparation of a superhydrophobic and conductive nanocomposite coating from a carbon-nanotube-conjugated block copolymer dispersion. Adv. Mater. 20, 3337 (2008)

    Google Scholar 

  176. Tsai, H., Xu, Z., Pai, R.K., Wang, L., Dattelbaum, A.M., Shreve, A.P., et al.: Structural dynamics and charge transfer via complexation with fullerene in large area conjugated polymer honeycomb thin films. Chem. Mater. 23, 759–761 (2011)

    Google Scholar 

  177. Ma, H., Gao, P., Fan, D., Du, B., Hao, J., Wei, Q.: Assembly of graphene nanocomposites into honeycomb-structured macroporous films with enhanced hydrophobicity. N. J. Chem 37, 1307–1311 (2013)

    Google Scholar 

  178. Sun, W., Shao, Z., Ji, J.A.: Particle-assisted fabrication of honeycomb-structured hybrid films via breath figures method. Polymer 51, 4169–4175 (2010)

    Google Scholar 

  179. Wang, J., Wang, C.F., Shen, H.X., Chen, S.: Quantum-dot-embedded ionomer-derived films with ordered honeycomb structures via breath figures. Chem. Commun. 46, 7376–7378 (2010)

    Google Scholar 

  180. Li, X.F., Zhang, L.A., Wang, Y.X., Yang, X.L., Zhao, N., Zhang, X.L., et al.: A bottom-up approach to fabricate patterned surfaces with asymmetrical TiO2 microparticles trapped in the holes of honeycomblike polymer film. J. Am. Chem. Soc. 133, 3736–3739 (2011)

    Google Scholar 

  181. Li, L., Zhong, Y.W., Ma, C.Y., Li, J., Chen, C.K., Zhang, A.J., et al.: Honeycomb-patterned hybrid films and their template applications via a tunable amphiphilic block polymer/inorganic precursor system. Chem. Mater. 21, 4977–4983 (2009)

    Google Scholar 

  182. Ke, B.B., Wan, L.S., Chen, P.C., Zhang, L.Y., Xu, Z.K.: Tunable assembly of nanoparticles on patterned porous film. Langmuir 26, 15982–15988 (2010)

    Google Scholar 

  183. Galeotti, F., Mroz, W., Bolognesi, A.: CdTe nanocrystal assemblies guided by breath figure templates. Soft Matter 7, 3832–3836 (2011)

    Google Scholar 

  184. Ou, Y., Wang, L.-Y., Zhu, L.-W., Wan, L.-S., Xu, Z.-K.: In-situ immobilization of silver nanoparticles on self-assembled honeycomb-patterned films enables surface-enhanced Raman scattering (SERS) substrates. J. Phys. Chem. C 118, 11478–11484 (2014)

    Google Scholar 

  185. Mendes, P.M.: Stimuli-responsive surfaces for bio-applications. Chem. Soc. Rev. 37, 2512–2529 (2008)

    Google Scholar 

  186. Chen, T., Ferris, R., Zhang, J., Ducker, R., Zauscher, S.: Stimulus-responsive polymer brushes on surfaces: transduction mechanisms and applications. Prog. Polym. Sci. 35, 94–112 (2010)

    Google Scholar 

  187. Yabu, H., Hirai, Y., Kojima, M., Shimomura, M.: Simple fabrication of honeycomb- and pincushion-structured films containing thermoresponsive polymers and their surface wettability. Chem. Mater. 21, 1787–1789 (2009)

    Google Scholar 

  188. Nygard, A., Davis, T.P., Barner-Kowollik, C., Stenzel, M.H.: A simple approach to micro-patterned surfaces by breath figures with internal structure using thermoresponsive amphiphilic block copolymers. Aust. J. Chem 58, 595–599 (2005)

    Google Scholar 

  189. Min, E.H., Ting, S.R.S., Billon, L., Stenzel, M.H.: Thermo-responsive glycopolymer chains grafted onto honeycomb structured porous films via RAFT polymerization as a thermo-dependent switcher for lectin concanavalin a conjugation. J. Polym. Sci. A Polym. Chem 48, 3440–3455 (2010)

    Google Scholar 

  190. Wang, J., Shen, H.-X., Wang, C.-F., Chen, S.: Multifunctional ionomer-derived honeycomb-patterned architectures and their performance in light enhancement of light-emitting diodes. J. Mater. Chem. 22, 4089–4096 (2012)

    Google Scholar 

  191. Yabu, H., Akagi, K., Shimomura, M.: Micropatterning of liquid crystalline polyacetylene derivative by using self-organization processes. Synth. Met. 159, 762–764 (2009)

    Google Scholar 

  192. Bolognesi, A., Galeotti, F., Giovanella, U., Bertini, F., Yunus, S.: Nanophase separation in polystyrene-polyfluorene block copolymers thin films prepared through the breath figure procedure. Langmuir 25, 5333–5338 (2009)

    Google Scholar 

  193. Wan, L.-S., Li, Q.-L., Chen, P.-C., Xu, Z.-K.: Patterned biocatalytic films via one-step self-assembly. Chem. Commun. 48, 4417–4419 (2012)

    Google Scholar 

  194. Kim, J.H., Seo, M., Kim, S.Y.: Lithographically patterned breath figure of photoresponsive small molecules: dual-patterned honeycomb lines from a combination of bottom-up and top-down lithography. Adv. Mater. 21, 4130 (2009)

    Google Scholar 

  195. Zhang, M., Sun, S., Yu, X., Cao, X., Zou, Y., Yi, T.: Formation of a large-scale ordered honeycomb pattern by an organogelator via a self-assembly process. Chem. Commun. 46, 3553–3555 (2010)

    Google Scholar 

  196. Babu, S.S., Mahesh, S., Kartha, K.K., Ajayaghosh, A.: Solvent-directed self-assembly of pi gelators to hierarchical macroporous structures and aligned fiber bundles. Chem. Asian J. 4, 824 (2009)

    Google Scholar 

  197. Xu, W.Z., Zhang, X., Kadla, J.F.: Design of functionalized cellulosic honeycomb films: site-specific biomolecule modification via “click chemistry”. Biomacromolecules 13, 350–357 (2011)

    Google Scholar 

  198. Chen, S., Alves, M.-H., Save, M., Billon, L.: Synthesis of amphiphilic diblock copolymers derived from renewable dextran by nitroxide mediated polymerization: towards hierarchically structured honeycomb porous films. Polym. Chem. 5, 5310–5319 (2014)

    Google Scholar 

  199. Sanz de Leon, A., Rodriguez-Hernandez, J., Cortajarena, A.L.: Honeycomb patterned surfaces functionalized with polypeptide sequences for recognition and selective bacterial adhesion. Biomaterials 34, 1453–60 (2013)

    Google Scholar 

  200. Leibler, L., Benoit, H.: Theory of correlations in partly labeled homopolymer melts. Polymer 22, 195–201 (1981)

    Google Scholar 

  201. Matsen, M.W., Bates, F.S.: Origins of complex self-assembly in block copolymers. Macromolecules 29, 7641–7644 (1996)

    Google Scholar 

  202. Geldhauser, T., Walheim, S., Schimmel, T., Leiderer, P., Boneberg, J.: Influence of the relative humidity on the demixing of polymer blends on prepatterned substrates. Macromolecules 43, 1124–1128 (2009)

    Google Scholar 

  203. Cui, L., Xuan, Y., Li, X., Ding, Y., Li, B.Y., Han, Y.C.: Polymer surfaces with reversibly switchable ordered morphology. Langmuir 21, 11696–11703 (2005)

    Google Scholar 

  204. Hecht, U., Schilz, C.M., Stratmann, M.: Influence of relative humidity during film formation processes on the structure of ultrathin polymeric films. Langmuir 14, 6743–6748 (1998)

    Google Scholar 

  205. Ge, W., Lu, C.: Hierarchical honeycomb patterns with tunable microstructures: controllable fabrication and application as replication templates. Soft Matter 7, 2790–2796 (2011)

    Google Scholar 

  206. Connal, L.A., Vestberg, R., Hawker, C.J., Qiao, G.G.: Fabrication of reversibly crosslinkable, 3-dimensionally conformal polymeric microstructures. Adv. Funct. Mater. 18, 3315–3322 (2008)

    Google Scholar 

  207. Ding, J., Gong, J., Bai, H., Li, L., Zhong, Y., Ma, Z., et al.: Constructing honeycomb micropatterns on nonplanar substrates with high glass transition temperature polymers. J. Colloid Interface Sci. 380, 99–104 (2012)

    Google Scholar 

  208. Greiser, C., Ebert, S., Goedel, W.A.: Using breath figure patterns on structured substrates for the preparation of hierarchically structured microsieves. Langmuir 24, 617–620 (2008)

    Google Scholar 

  209. Kwak, G., Fukao, S., Fujiki, M., Sakaguchi, T., Masuda, T.: Nanoporous, honeycomb-structured network fibers spun from semiflexible, ultrahigh molecular weight, disubstituted aromatic polyacetylenes: superhierarchical structure and unique optical anisotropy. Chem. Mater. 18, 5537–5542 (2006)

    Google Scholar 

  210. Zheng, J., Zhang, H., Zhao, Z., Han, C.C.: Construction of hierarchical structures by electrospinning or electrospraying. Polymer 53, 546–554 (2012)

    Google Scholar 

  211. Fashandi, H., Karimi, M.: Pore formation in polystyrene fiber by superimposing temperature and relative humidity of electrospinning atmosphere. Polymer 53, 5832–5849 (2012)

    Google Scholar 

  212. Ting, W.-H., Chen, C.-C., Dai, S.A., Suen, S.-Y., Yang, I.K., Liu, Y.-L., et al.: Superhydrophobic waxy-dendron-grafted polymer films via nanostructure manipulation. J. Mater. Chem. 19, 4819–4828 (2009)

    Google Scholar 

  213. Brown, P.S., Talbot, E.L., Wood, T.J., Bain, C.D., Badyal, J.P.S.: Superhydrophobic hierarchical honeycomb surfaces. Langmuir 28, 13712–13719 (2012)

    Google Scholar 

  214. Yabu, H., Hirai, Y., Shimomura, M.: Electroless plating of honeycomb and pincushion polymer films prepared by self-organization. Langmuir 22, 9760–9764 (2006)

    Google Scholar 

  215. Ishii, D., Yabu, H., Shimomura, M.: Selective metal deposition in hydrophobic porous cavities of self-organized honeycomb-patterned polymer films by all-wet electroless plating. Colloids Surf. A Physicochem. Eng. Asp. 313–314, 590–594 (2008)

    Google Scholar 

  216. Ma, C.Y., Zhong, Y.W., Li, J., Chen, C.K., Gong, J.L., Xie, S.Y., et al.: Patterned carbon nanotubes with adjustable array: a functional breath figure approach. Chem. Mater. 22, 2367–2374 (2010)

    Google Scholar 

  217. Sakatanì, Y., Boissière, C., Grosso, D., Nicole, L., Soler-Illia, G.J.A.A., Sanchez, C.: Coupling nanobuilding block and breath figures approaches for the designed construction of hierarchically templated porous materials and membranes. Chem. Mater. 20, 1049–1056 (2008)

    Google Scholar 

  218. Sato, T., Tanaka, M., Yamamoto, S., Ito, E., Shimizu, K., Igarashi, Y., et al.: Effect of honeycomb-patterned surface topography on the function of mesenteric adipocytes. J. Biomater. Sci. Polym. Ed. 21, 1947–1956 (2010)

    Google Scholar 

  219. Wan, L.S., Li, J.W., Ke, B.B., Xu, Z.K.: Ordered microporous membranes templated by breath figures for size-selective separation. J. Am. Chem. Soc. 134, 95–98 (2012)

    Google Scholar 

  220. Hirai, Y., Yabu, H., Matsuo, Y., Ijiro, K., Shimomura, M.: Arrays of triangular shaped pincushions for SERS substrates prepared by using self-organization and vapor deposition. Chem. Commun. 46, 2298–2300 (2010)

    Google Scholar 

  221. Tang, P., Hao, J.: Directionally electrodeposited gold nanoparticles into honeycomb macropores and their surface-enhanced Raman scattering. N. J. Chem 34, 1059–1062 (2010)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Laurent Billon or Juan Rodríguez-Hernández .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Muñoz-Bonilla, A., Save, M., Billon, L., Rodríguez-Hernández, J. (2015). Breath Figures: Fabrication of Honeycomb Porous Films Induced by Marangoni Instabilities. In: Rodríguez-Hernández, J., Drummond, C. (eds) Polymer Surfaces in Motion. Springer, Cham. https://doi.org/10.1007/978-3-319-17431-0_10

Download citation

Publish with us

Policies and ethics