Abstract
In this study, the electroless plating has been successfully applied for nickel catalyst layer and the multiwall carbon nanotubes (MWNTs) grown by chemical vapor deposition (CVD). Sulfuric acid solution was used as buffer to adjust and maintain pH value of electroless plating solution on 4.5. The structural, element, and quality of MWNTs were investigated with field emission scanning electron microscope (FE-SEM), X-ray diffraction patterns (XRD), energy dispersive spectrometer (EDS) and Raman spectrometer. From the FE-SEM image, it showed that the density of MWNTs increased as the deposition time of nickel catalyst layer increased. This result caused by the formation of nickel nucleation become rich as the immersion of the substrate in electroless plating solution was longer, and this benefited the growth of carbon nanotubes. The Raman analysis demonstrated that the ID/IG ratio of MWNTs decreases as the deposition times of nickel catalyst layer increases, indicating that more graphene MWNTs structures were formed.
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References
Saito, Y., Hamaguchi, K., Hata, K., Uchida, K., Tasaka, Y., Ikazaki, F., Yumura, M., Kasuya, A., Nishina, Y.: Conical beams from open nanotubes. Nature 389, 554–555 (1997)
Schmid, H., Fink, H.W.: Carbon nanotubes are coherent electron sources. Appl. Phys. Lett. 70, 2679–2680 (1997)
Rafique, M.M.A., Iqbal, J.: Production of carbon nanotubes by different routes-a review. J. Encap. Adsorpt. Sci. 1, 29–34 (2011)
Iijima, S.: Helical microtubules of graphitic carbon. Nature 354, 56–58 (1991)
Iijima, S., Ichihashi, T.: Single-shell carbon nanotubes of 1-Nm diameter. Nature 363, 603–605 (1993)
Bethune, D.S., Kiang, C.H., De Vries, M.S., Gorman, G., Savoy, R., Vazquez, J., Beyers, R.: Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls. Nature 363, 605–607 (1993)
Mcbride, W. S.: Synthesis of carbon nanotube by chemical vapor deposition. Undergraduate Degree Thesis, College of William and Marry in Virginia, Williamsburg (2001)
Mohammad, M.I., Moosa Ahmed, A., Potgieter, J.H., Ismael Mustafa, K.: Carbon nanotubes synthesis via arc discharge with a yttria catalyst. Nanomaterials 2013, 1–7 (2013). Article ID 785160
Thess, A., Lee, R., Nikolaev, P., Dai, H., Petit, P., Robert, J., Xu, C., Lee, Y.H., Kim, S.G., Rinzler, A.G., Colbert, D.T., Scuseria, G.E., Tománek, D., Fischer, J.E., Smalle, R.E.: Crystalline ropes of metallic carbon nanotubes. Science 273, 483–487 (1996)
Qin, L.C., Zhou, D., Krauss, A.R., Gruen, D.M.: Growing carbon nanotubes by microwave plasma-enhanced chemical vapor deposition. Appl. Phys. Lett. 72, 3437–3439 (1998)
Li, W.Z., Xie, S.S., Qain, L.X., Chang, B.H., Zou, B.S., Zhou, W.Y., Zhao, R.A.: Large-scale synthesis of aligned carbon nanotubes. Science 274, 1701–1703 (1996)
Kumar, M., Ando, Y.: Chemical vapor deposition of carbon nanotubes: a review on growth mechanism and mass production. J. Nanosci. Nanotechnol. 10, 3739–3758 (2010)
Liu, C., Chen, Y.C., Tzeng, Y.: Effects of carbon content in iron catalyst coatings on the growth of vertically aligned carbon nanotubes on smooth silicon surfaces by thermal chemical vapor deposition. Diamond Relat. Mater. 13, 1274–1280 (2004)
Jeong, H.J., Jeong, S.Y., Shin, Y.M., Han, J.H., Lim, S.C., Eum, S.J., Yang, C.W., Kim, N.G., Park, C.Y., Lee, Y.H.: Dual-catalyst growth of vertically aligned carbon nanotubes at low temperature in thermal chemical vapor deposition. Chem. Phys. Lett. 361, 189–195 (2002)
Juang, Z.Y., Chien, I.P., Lai, J.F., Lai, T.S., Tsai, C.H.: The effects of ammonia on the growth of large-scale patterned aligned carbon nanotubes using thermal chemical vapor deposition method. Diamond Relat. Mater. 13, 1203–1209 (2004)
Shyu, Y.M., Hong, F.C.N.: The effects of pre-treatment and catalyst composition on growth of carbon nanofibers at low temperature. Diamond Relat. Mater. 10, 1241–1245 (2001)
Chaisitsak, S., Yamada, A., Konagai, M.: Hot filament enhanced CVD synthesis of carbon nanotubes by using a carbon filament. Diamond Relat. Mater. 13, 438–444 (2004)
Kong, F.Z., Zhang, X.B., Xiong, W.Q., Liu, F., Huang, W.Z., Sun, Y.L., Tu, J.P., Chen, X.W.: Ni-layer on multiwall carbon nanotubes by an electroless plating method. Surf. Coat. Technol. 155, 33–36 (2002)
Saito, R., Dresselhaus, G., Dresselhaus, M.S.: Physical Properties of CNTs. Imperial College Press, London (1999)
Lee, C.J., Park, Y.S., Kim, W.S., Lee, N.S., Kim, J.M., Choi, Y.G.: Synthesis of uniformly distributed carbon nanotubes on a large area of Si substrates by thermal chemical vapor deposition. Appl. Phys. Lett. 75, 1721–1723 (1999)
Acknowledgement
The authors acknowledge the financial support of the Ministry of Science and Technology and National Science Council of MOST 103-2221-E-244-018 and 103-2514-S-218-001, NSC 102-2511-S-244-001 and NSC 102-2221-E-244-019.
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Lin, CY., Pan, JL., Wu, CC., Chang, WC. (2016). Study of Nickel Catalysts Deposited by Using the Electroless Plating Method and Growth of the Multiwall Carbon Nanotubes. In: Juang, J. (eds) Proceedings of the 3rd International Conference on Intelligent Technologies and Engineering Systems (ICITES2014). Lecture Notes in Electrical Engineering, vol 345. Springer, Cham. https://doi.org/10.1007/978-3-319-17314-6_47
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DOI: https://doi.org/10.1007/978-3-319-17314-6_47
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