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Nanomechanical Characterization of the Carbonated Wollastonite System

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Nanotechnology in Construction

Abstract

This paper focuses on the nano-mechanical characterization of carbonated calcium silicate mineral (wollastonite (CaSiO3)) using nanoindentation technique. While exposed to carbon dioxide (CO2), the calcium component of wollastonite undergoes carbonation reaction which results in formation of two main products: calcium carbonate (CaCO3) and silica (SiO2). The mechanical properties of these partially reacted wollastonite systems were evaluated using the nanoindentation technique from which the reduced elastic modulus (Er) of silicate phase found to be around 38 GPa. For calcium carbonate phase this value was around 60 GPa.

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References

  1. Huijgen, W. J. J., & Comans, R. N. J. (2005). Carbon dioxide sequestration by mineral carbonation: literature review update 2003–2004 (Report). Energy Research Centre of the Netherlands.

    Google Scholar 

  2. Goff, F., & Lackner, K. (1998). Carbon dioxide sequestering using ultramafic rocks. Environmental Geosciences, 5(3), 89–101.

    Article  Google Scholar 

  3. Lackner, K. (2003, June). A guide to CO2 sequestration. Science, 300, 1677–1678.

    Google Scholar 

  4. Daval, D., Martinez, I., Corvisier, J., Findling, N., Goffé, B., & Guyot, F. (2009, July). Carbonation of Ca-bearing silicates, the case of wollastonite: Experimental investigations and kinetic modeling. Chemical Geology, 265(1–2), 63–78.

    Google Scholar 

  5. Daval, D., Martinez, I., Guigner, J. M., Hellmann, R., Corvisier, J., Findling, N., et al. (2009, November). Mechanism of wollastonite carbonation deduced from micro- to nanometer length scale observations. American Mineralogist, 94(11–12), 1707–1726.

    Google Scholar 

  6. Tai, C. Y., Chen, W. R., & Shih, S. M. (2006, January). Factors affecting wollastonite carbonation under CO2 supercritical conditions. AIChE Journal, 52(1), 292–299.

    Google Scholar 

  7. Chun, Y., Naik, T., & Kraus, R. (2007). Carbon dioxide sequestration in concrete in different curing environments. In Conference: Sustainable Construction Materials and Technologies, Coventry, Special Papers Proceedings pp. 18–24.

    Google Scholar 

  8. Papadakis, V., Vayenas, C., & Fardis, M. (1991). Fundamental modeling and experimental investigation of concrete carbonation. ACI Materials Journal, 88, 363–373.

    Google Scholar 

  9. Riman, R. E., Gupta, S., Atakan, V., & Li, Q. (2013). U.S. 20130122267 A1: Bonding element, bonding matrix and composite material having the bonding element, and method of manufacturing thereof.

    Google Scholar 

  10. Constantinides, G., Ravi Chandran, K. S., Ulm, F. J., & Van Vliet, K. J. (2006, August). Grid indentation analysis of composite microstructure and mechanics: Principles and validation. Materials Science and Engineering: A, 430(1–2), 189–202.

    Google Scholar 

  11. Ulm, F. J., Vandamme, M., Bobko, C., Alberto Ortega, J., Tai, K., & Ortiz, C. (2007, September). Statistical indentation techniques for hydrated nanocomposites: Concrete, bone, and shale. Journal of the American Ceramic Society, 90(9), 2677–2692.

    Google Scholar 

  12. Němeček, J. (2009, September). Creep effects in nanoindentation of hydrated phases of cement pastes. Materials Characterization, 60(9), 1028–1034.

    Google Scholar 

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Acknowledgement

Solidia technologies are gratefully acknowledged for providing testing materials required for this study. Authors would also like to acknowledge the Rutger University, NJ, USA for the development of the technology.

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Correspondence to Warda Ashraf .

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© 2015 Springer International Publishing Switzerland

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Ashraf, W., Olek, J., Tian, N. (2015). Nanomechanical Characterization of the Carbonated Wollastonite System. In: Sobolev, K., Shah, S. (eds) Nanotechnology in Construction. Springer, Cham. https://doi.org/10.1007/978-3-319-17088-6_8

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