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Activated Zeolites and Heteropolyacids Have Efficient Catalysts for Synthesis Without Use of Organic Solvent at Room Temperature

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Abstract

The Thiele–Winter reaction is of interest for synthesis of triacetoxyaromatic precursors of hydroquinones.

Solid acids such as heteropolyacids and activated zeolites have an efficient catalyst in acetoxylation reaction of quinones without the use of organic solvent at room temperature. Hydroquinones and substituted hydroquinones was easily oxidized at room temperature in quinones by using (Pc[Co]/K10) and air (1 atm). We have also tested this type of reaction in naphthoquinone series. Many naphthoquinones are natural products with interesting biological properties. The catalytic system (Pc[Co]/K10) in the presence of pure oxygen easily oxidizes the 1,5-dihydroxynaphthalene in Juglone (yield 87 %).

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Abbreviations

(Pc[Co]/K10):

Phthalocyanine (Co) supported on clay K10

Ho:

Index hammett

H3PMo12O40 :

Molybdophosphoric acid

ClSO3H:

Chlorosulfonic acid

H3PW12O40 :

12 Tunsto phosphoric acid

H2SO4 :

Sulfuric acid

(CH3)2(CO)2O:

Acetic anhydride

Rt:

Room temperature

Mp:

Melting points

NMR:

Nuclear magnetic resonance

IR:

Infrared spectroscopy

UV:

Ultraviolet–visible spectrophotometry

MO:

Microwave irradiation

COCl2 :

Cobalt chloride

H :

Hour

p :

Power

T :

Temperature

t :

Time

Λ :

Wavelengths

ε λ :

Molar extinction coefficient

H3SiW12O40 :

Tungstosilicic acid

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Authors and Affiliations

  1. Faculty of Sciences, University of Boumerdes, Boumerdes, 35000, Algeria

    Mohamed Hammadi, Hadjila Dokari & Nassima Benferrah

  2. Ensicaen, LCMT—UMR 6507 CNRS, University of Caen, Caen, 14050, France

    Didier Villemin

Authors
  1. Mohamed Hammadi
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  2. Hadjila Dokari
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  3. Didier Villemin
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  4. Nassima Benferrah
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Corresponding author

Correspondence to Mohamed Hammadi .

Editor information

Editors and Affiliations

  1. Department of Mechanical Engineering, University of Ontario, Oshawa, Ontario, Canada

    Ibrahim Dincer

  2. Department of Mechanical Engineering, Dokuz Eylul University, Izmir, Turkey

    C. Ozgur Colpan

  3. Department of Energy Systems Engineering, Suleyman Demirel University, Isparta, Turkey

    Onder Kizilkan

  4. Department of Mechanical Engineering, Dokuz Eylul University, Izmir, Turkey

    M. Akif Ezan

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Hammadi, M., Dokari, H., Villemin, D., Benferrah, N. (2015). Activated Zeolites and Heteropolyacids Have Efficient Catalysts for Synthesis Without Use of Organic Solvent at Room Temperature. In: Dincer, I., Colpan, C., Kizilkan, O., Ezan, M. (eds) Progress in Clean Energy, Volume 1. Springer, Cham. https://doi.org/10.1007/978-3-319-16709-1_38

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  • DOI: https://doi.org/10.1007/978-3-319-16709-1_38

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-16708-4

  • Online ISBN: 978-3-319-16709-1

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