Skip to main content

Base-Displacement Reactions and Electron Conduction in Alkali Metals

  • Chapter
  • First Online:
Bonding in Electron-Rich Molecules

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 90))

  • 786 Accesses

Abstract

The donor-acceptor complexes of Chapter 20 were usually formed by reacting a neutral electron donor with a neutral electron acceptor RY.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R. Firestone, J. Org. Chem., 36, 702 (1971).

    Google Scholar 

  2. R.D. Harcourt, J. Chem. Educ., 45, 779 (1968); 46, 856 (1969).

    Google Scholar 

  3. R.D. Harcourt, J. Mol. Struct., 5, 199 (1970).

    Google Scholar 

  4. S.S. Shaik, J. Amer. Chem. Soc. 103, 3692 (1981).

    Google Scholar 

  5. J. March, Advanced Organic Chemistry (McGraw-Hill 1977), p. 266. See also I. Fleming, “Frontier Orbitals and Organic Chemical Reactions (Wiley, 1978) p. 75.

    Google Scholar 

  6. R.J. Gillespie, J. Chem. Soc., 1002 (1952).

    Google Scholar 

  7. C.A. Coulson, Nature, 221, 1106 (1969).

    Google Scholar 

  8. A. Dedieu and A. Veillard, Quantum Theory of Chemical-Reactions, Vol. 1, (R. Daudel, A. Pullman, L. Salem and A. Veillard, eds.) Reidel (1980), p. 69.

    Google Scholar 

  9. L. Pauling, College Chemistry, W.H. Freeman, 3rd. Ed., 1964, p. 558.

    Google Scholar 

  10. L. Pauling, Nature of the Chemical Bond, 3rd. Ed., 1960, p. 400.

    Google Scholar 

  11. R.D. Harcourt, J. Phys. B., 7, L41 (1974).

    Google Scholar 

  12. J. March, ref. 5, p. 896.

    Google Scholar 

  13. R.D. Harcourt and M.L. Styles, J. Phys. Chem. A, 107, 3877 (2003) and Ref. 6 therein.

    Google Scholar 

  14. R.D. Harcourt (a) in Valence-bond Theory and Chemical Structure (Elsevier 1990) p. 251. (b). J. Mol. Struct. (Theochem) 165, 329 (1988); 184, 403 (1989); (c) J. Mol. Struct. (Theochem) 229, 39 (1991). (d) J. Mol. Struct. (Theochem) 253, 363 (1992). (e) New J. Chem. 16, 667 (1992). (f) Int. J. Quantum Chem. 60, 553 (1996). (g) J. Mol. Struct. (Theochem) 398-399, 93 (1997). (h) in Quantum Chemical Methods in Main-Group Chemistry, (Wiley 1998) p. 233 (i) in Pauling’s Legacy Modern Modelling of the Chemical Bond, (Elsevier 1999) p.449. (j) J. Phys. Chem. A, 103, 4293 (1999); 155, 11260 (2003). (k) Eur. J. Inorg. Chem. 1901-1916 (2000). (l) J. Phys. Chem. A, 114, 8573, 8932 (2010).

    Google Scholar 

  15. R.D. Harcourt and T.M. Klapötke, Trends Inorg. Chem. 9, 11 (2006).

    Google Scholar 

  16. X. Sun, (a) Chem. Educator, 8, 303 (2003) (b) Symmetry 2, 201 (2010).

    Google Scholar 

  17. D. Usharani, W. Lai, C. Li, H. Chen, D. Danovich and S. Shaik, Chem. Soc. Revs. 43, 4968 (2014).

    Google Scholar 

  18. R.D. Harcourt (a) J. Chem. Educ. 62, 99 (1985). (b) J. Phys. Chem. A 115, 6610, 8180 (2011).

    Google Scholar 

  19. W.O. Kermack and R. Robinson, J. Chem. Soc. Trans. 121, 433 (1922).

    Google Scholar 

  20. A. Lakshminarayanan, Resonance, 15, 51 (2010).

    Google Scholar 

  21. R.D. Harcourt, Chem. Britain, p. 19 (July 1998).

    Google Scholar 

  22. D.L. Cooper and P.B. Karadakov, Int. Rev. Phys. Chem. 28, 169 (2009

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Richard D. Harcourt .

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Harcourt, R.D. (2016). Base-Displacement Reactions and Electron Conduction in Alkali Metals. In: Bonding in Electron-Rich Molecules. Lecture Notes in Chemistry, vol 90. Springer, Cham. https://doi.org/10.1007/978-3-319-16676-6_21

Download citation

Publish with us

Policies and ethics