Abstract
Seawater is an aggressive environment for materials particularly in warmer and polluted waters. In this environment, steel infrastructure, such as offshore platforms, pipelines, and tanks may corrode quickly, and for engineering and management purposes, the rate at which this occurs is of interest. Here, recently developed understanding of the corrosion processes over extended exposure periods is reviewed and recently developed science-based mathematical models for the prediction of corrosion and pitting of structural steels are described. The effect of various influencing factors is reviewed, including that of seawater quality and the effect of microorganisms on corrosion. Also, short discussions of the corrosion of stainless steels, aluminum, and copper-nickels, all materials that are used under marine exposure conditions, are given. This is followed by a description of recent observations of the corrosion of steel reinforcing bars in reinforced concrete, another widely used construction material in marine environments. It shows that reinforced concrete can be a highly successful construction material, even in long term and under marine conditions, but that severe loss of reinforcement may occur without obvious external signs detectable by visual inspection.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Abbreviations
- HSLA:
-
high strength low alloy
- MIC:
-
microbially induced corrosion
References
C.R. Southwell, J.D. Bultman, C.W. Hummer: Estimating service life of steel in seawater. In: Seawater Corrosion Handbook, ed. by M. Schumacher (Noyes Data Corp., Park Ridge 1979) pp. 374–387
J.M. Wright, A. Colling, G. Bearman: Open University: Seawater: Its Composition, Properties and Behaviour (Butterworths-Heinemann, Oxford 1995)
H.U. Svedrup, M.W. Johnson, R.H. Fleming: The Oceans: Their Physics, Chemistry and General Biology (McGraw-Hill, New York 1942)
B.J. Little, J.S. Lee: Microbiologically Induced Corrosion (Wiley, New York 2007)
OSPAR: Regional Quality Status Report II for the Greater North Sea (OSPAR Comm., London 2000)
H.A. Cole: Pollution of the sea and its effects, Proc. R. Soc. B 205(1158), 17–30 (1979)
A.M. Szmant, A. Forrester: Water column and sediment nitrogen and phosphorous distribution patterns in the Florida Keys, Coral Reefs 15, 21–41 (1996)
M.J. Furnas, J. Brodie: Current status of nutrient levels and other water quality parameters in the great barrier reef. In: Downstream Effects of Land Use, ed. by H.M. Hunter, A.G. Eyles, B. Rayment (Department of Natural Resources, Queensland 1996) pp. 9–21
J.M. Odom: Industrial and environmental activities of sulfate-reducing bacteria. In: The Sulfate-Reducing Bacteria: Contemporary Perspectives, ed. by J.M. Odom, R. Singleton Jr. (Springer, New York 1993) pp. 189–210
G. Radach, J. Genkeler: Gridding of the NOWESP Data Sets, Ber. Zent. Meere. Klimatforsch. B: Ozeanogr., Vol. 27 (Inst. Meeresk., Hamburg 1997)
A.F. Carlucci: Nutrient and microbial response to nutrients in seawater. In: Effect of Ocean Environments on Microbial Activities, ed. by R.R. Colwell, R.Y. Morita (Univ. Park Press, Baltimore 1974)
K.H. Coale, K.S. Johnson, S.E. Fitzwater, R.M. Gordon, S. Tanner, F.P. Chavez, L. Ferioli, C. Sakamoto, P. Rogers, F. Millero, P. Steinberg, P. Nightingale, D. Cooper, W.P. Cochlan, M.R. Landry, J. Constantinou, G. Rollwagen, A. Trasvina, R. Kudela: A massive phytoplankton bloom induced by an ecosystem-scale iron fertilization experiment in the equatorial pacific ocean, Nature 383, 495–501 (1996)
B. Austin: Marine Microbiology (Cambridge Univ. Press, Cambridge 1988), Chap. 5
G. Kreysa, R. Eckermann: Dechema Corrosion Handbook, Vol. 11 (VCH, New York 1992)
M. Schumacher (Ed.): Seawater Corrosion Handbook (Noyes Data Corp., Park Ridge 1979)
O.E. Gjorv: Durability Design of Concrete Structures in Severe Environments (Taylor Francis, London 2009)
M.G. Richardson: Fundamentals of Durable Reinforced Concrete (Spon Press, London 2002)
J.E. Bringas: Handbook of Comparative World Steel Standards (ASTM, Mayfield 2004)
R.E. Melchers: Structural Reliability Analysis and Prediction (Wiley, Chichester 1999)
R. Jeffrey, R.E. Melchers: The changing topography of corroding mild steel surfaces in seawater, Corros. Sci. 49, 2270–2288 (2007)
J. Heyman: Elements of the Theory of Structures (Cambridge Univ. Press, Cambridge 1996)
US Office of Naval Research: Second World Congress on Corrosion in the Military, Naples (Trans-Tech, Pfäffikon 2007)
D. Jones: Principles and Prevention of Corrosion, 2nd edn. (Prentice-Hall, Upper Saddle River 1996)
H.H. Uhlig, R.W. Revie: Corrosion and Corrosion Control, 3rd edn. (Wiley, New York 1985)
B.W. Forgeson, C.R. Southwell, A.L. Alexander: Corrosion of metals in tropical environments. Part 3. Underwater corrosion of ten structural steels, Corrosion 16(3), 87–96 (1960)
C.R. Southwell, B.W. Forgeson, A.L. Alexander: Corrosion of metals in tropical environments. Part 2. Atmospheric corrosion of ten structural steels, Corrosion 14(9), 53–59 (1958)
R.E. Melchers, R. Jeffrey: The critical involvement of anaerobic bacterial activity in modelling the corrosion behaviour of mild steel in marine environments, Electrochim. Acta 54, 80–85 (2008)
R. Jeffrey, R.E. Melchers: Bacteriological influence in the development of iron sulphide species in marine immersion environments, Corros. Sci. 45(4), 693–714 (2003)
R.E. Melchers: Mathematical modelling of the diffusion controlled phase in marine immersion corrosion of mild steel, Corros. Sci. 45(5), 923–940 (2003)
R.E. Melchers, P.A. Wells: Models for the anaerobic phases of marine immersion corrosion, Corros. Sci. 48(7), 1791–1811 (2006)
R.E. Melchers: Modeling of marine immersion corrosion for mild and low alloy steels – Part 1: Phenomenological model, Corrosion 59(4), 319–334 (2003)
R.E. Melchers: Pitting corrosion of mild steel in marine immersion environment – 1: Maximum pit depth, Corrosion 60(9), 824–836 (2004)
J.E. Breakell, K. Foster, M. Siegwart: Management of Accelerated Low Water Corrosion in Steel Maritime Structures, Rep. C634 (CIRIA, London 2005)
I.B. Beech, S.A. Campbell: Accelerated low water corrosion of carbon steel in the presence of a biofilm harbouring sulphate-reducing and sulphur-oxidising bacteria recovered from a marine sediment, Electrochim. Acta 54, 14–21 (2008)
J.M.R. Genin, A.A. Olowe, B. Resiak, N.D. Benbouzid-Rollet, S. L’Haridon, M. Confente, D. Prieur: Microbially induced corrosion of steel sheet piles in a harbour and the presence of green rust two compound. In: Progress in the Understanding and Prevention of Corrosion, ed. by J.M. Costa, A.D. Mercer (Inst. Met., London 1993) pp. 1177–1184
R.E. Melchers, R.J. Jeffrey: Corrosion of long vertical steels strips in the marine tidal zone and implications for ALWC, Corros. Sci. 65, 26–36 (2012)
M.H. Peterson, L.J. Waldron: Investigation of mild steel corrosion rate in San Diego harbor, Corrosion 17(4), 188t–190t (1961)
I.B. Beech, J. Sunner: Biocorrosion: Towards understanding interactions between biofilms and metals, Curr. Opin. Biotechnol. 15, 181–186 (2004)
G. Cragnolino, O.H. Tuovinen: The role of sulphate-reducing and sulphur-oxidizing bacteria on the localized corrosion of iron-base alloys – A review, Int. Biodeterior. 20(1), 9–26 (1984)
G. Butler, P. Stretton, J.G. Beynon: Initiation and growth of pits on high-purity iron and its alloys with chromium and copper in neutral chloride solutions, Br. Corros. J. 7(7), 168–173 (1972)
Z. Szklarska-Smialowska: Pitting Corrosion of Metals (NACE, Houston 1986)
R.E. Melchers, M. Ahammed, J. Jeffrey, G. Simundic: Statistical characterization of corroded steel surfaces, Mar. Struct. 23, 274–287 (2010)
J. Galambos: The Asymptotic Theory of Extreme Order Statistics, 2nd edn. (Krieger, Malabar 1987)
R.E. Melchers: Extreme value statistics and long-term marine pitting corrosion of steel, Probab. Eng. Mech. 23, 482–488 (2008)
S.C. Dexter, G.Y. Gao: Effect of seawater biofilms on corrosion potential and oxygen reduction of stainless steel, Corrosion 44(10), 717–723 (1988)
R.E. Melchers, R. Jeffrey: Modeling of long-term corrosion loss and pitting for chromium-bearing and stainless steels in seawater, Corrosion 64(2), 143–154 (2008)
C. Vargel: Corrosion of Aluminium (Elsevier, London 2004)
Z. Szklarska-Smialowska: Pitting corrosion of aluminum, Corros. Sci. 41, 1743–1767 (1999)
J.E. Amonette, C.K. Russell, K.A. Carosino, N.L. Robinson, J.T. Ho: Toxidity of Al to Desulfovibrio desulfuricans, Appl. Environ. Microbiol. 69(7), 4057–4066 (2003)
R. E. Melchers: Temperature effect on seawater immersion corrosion of copper-nickel alloy, Corrosion 57(4), 440–451 (2001)
J. Tinnea, L. Li, W.H. Hartt, A.A. Sagüés, F. Pianca, B. Chandler, G. Pedersen: Corrosion in bridges and highways. In: ASM Handbook. Volume 13C, Corrosion: Environments and Industries, ed. by S.D. Cramer, B.S. Covino Jr. (ASM Int., Materials Park 2006) pp. 559–597
R.E. Melchers, C.Q. Li: Reinforcement corrosion in concrete exposed to the North Sea for over 60 years, Corrosion 65(8), 554–566 (2009)
R.E. Melchers, C.Q. Li: Reinforcement corrosion initiation and activation times in concrete structures exposed to severe marine environments, Cem. Concr. Res. 39, 1068–1076 (2009)
R.E. Melchers: Carbonates, carbonation and the durability of reinforced concrete marine structures, Aust. J. Struct. Eng. 10(3), 215–226 (2010)
R.E. Melchers, T.M. Papé: Aspects of long-term durability of reinforced concrete structures in marine environments, Eur. J. Environ. Civ. Eng. 15(7), 969–980 (2011)
R.E. Melchers, T.M. Pape: The durability of reinforced concrete structures in marine environments, Proc. Aust. Struct. Eng. Conf., Sydney (2012)
D.A. Hausmann: Steel corrosion in concrete, how does it occur, Mater. Perform. 6(11), 19–23 (1967)
A.A. Sagues, E.I. Moreno, C. Andrade: Evolution of pH during in-situ leaching in small concrete cavities, Cem. Concr. Res. 27(11), 1747–1759 (1997)
G.J. Verbeek: Mechanisms of Corrosion of Steel in Concrete, Corrosion of Metals in Concrete, SP-49 (Am. Concr. Inst., Farmington Hills 1975) pp. 21–38
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Melchers, R.E. (2016). Principles of Marine Corrosion. In: Dhanak, M.R., Xiros, N.I. (eds) Springer Handbook of Ocean Engineering. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-319-16649-0_6
Download citation
DOI: https://doi.org/10.1007/978-3-319-16649-0_6
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-16648-3
Online ISBN: 978-3-319-16649-0
eBook Packages: EngineeringEngineering (R0)