Abstract
Processing is the mix of operations which are applied to materials when objects are made. A whole branch of engineering deals with the design of viable solutions to all the problems which can arise in the transformation of polymers. With a maybe rough approximation, it can be said that processing consists in the transfer of mechanical or thermal energy to the polymer, with the aim of mixing it with other substances and of shaping it in the desired final form. Processing is rarely mild, because the quest for maximisation of industrial production imposes the conditions which minimise the manufacturing time and which often correspond to high temperatures and shear forces. The polymer thus suffers a relevant mechanical and thermal stress, which is the main driving force determining the structure of the material in the solid state. The reason why this should be of interest to the forensic scientist is that processing-dependent parameters contain information extremely indicative of the manufacturer.
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References
Sugita R, Sasagawa K, Suzuki S (2009) Illegal route estimation of the seized illicit drug, methamphetamine, by the comparison of striation marks on plastic packaging films. J Forensic Sci 54:1341
Berx V, De Kinder J (2002) 3D measurements on extrusion marks in plastic bags. J Forensic Sci 47:976
Denton S (1981) Extrusion marks in polythene film. J Forensic Sci Soc 21:259
Stokes DJ (2003) Recent advances in electron imaging, image interpretation and applications: environmental scanning electron microscopy. Philos Trans R Soc London Ser A 361:2771
Klug HP, Alexander LE (1974) X-ray diffraction procedures. Wiley, New York
Alexander LE (1969) X-ray diffraction procedures in polymer science. Wiley, New York
Ladd M, Palmer R (eds) (2013) Structure determination by X-ray crystallography: analysis by X-rays and neutrons. Springer, New York
De Rosa C, Auriemma F (eds) (2014) Crystals and crystallinity in polymers: diffraction analysis of ordered and disordered crystals. Wiley, Hoboken
Turner Jones A, Aizlewood JM, Beckett DR (1964) Crystalline forms of isotactic polypropylene. Die Makromol Chem 75:134
Hindeleh AM, Johnson DJ (1971) The resolution of multipeak data in fiber science. J Phys D Appl Phys 4:259
Causin V, Marega C, Carresi P et al (2007) A quantitative differentiation method for plastic bags by wide angle X-ray diffraction for tracing the source of illegal drugs. Forensic Sci Int 168:37
Causin V, Marega C, Marigo A et al (2010) Forensic differentiation of paper by X-ray diffraction and infrared spectroscopy. Forensic Sci Int 197:70
Foner HA, Adan N (1983) The characterization of papers by X-ray diffraction (XRD): measurement of cellulose crystallinity and determination of mineral composition. J Forensic Sci Soc 23:313
Chen R, Jakes KA, Foreman DW (2004) Peak-fitting analysis of cotton fiber powder X-ray diffraction spectra. J Appl Polym Sci 93:2019
Liu Y, Hu H (2008) X-ray diffraction study of bamboo fibers treated with NaOH. Fibers Polym 9:735
Moharram MA, Mahmoud OM (2007) X-ray diffraction methods in the study of the effect of microwave heating on the transformation of cellulose I into cellulose II during mercerization. J Appl Polym Sci 105:2978
Wada M, Okano T (2001) Localization of Iα and Iβ phases in algal cellulose revealed by acid treatments. Cellulose 8:183
Yan Z, Chen S, Wang H et al (2008) Biosynthesis of bacterial cellulose/multi-walled carbon nanotubes in agitated culture. Carbohydr Res 74:659
Menczel JD, Prime RB (eds) (2009) Thermal analysis of polymers: fundamentals and applications. Wiley, Hoboken
Hatakeyama T, Quinn FX (1994) Thermal analysis: fundamentals and applications to polymer science. Wiley, Chichester
Tsukame T, Kutsuzawa M, Sekine H et al (1999) Identification of polyethylene by differential scanning calorimetry: application to forensic science. J Therm Anal Calorim 57:847
Sajwan M, Aggarwal S, Singh RB (2008) Forensic characterization of HDPE pipes by DSC. Forensic Sci Int 175:130
Causin V, Marega C, Marigo A et al (2009) A method based on thermogravimetry/differential scanning calorimetry for the forensic differentiation of latex gloves. Forensic Sci Int 188:57
Causin V, Marega C, Carresi P et al (2006) A quantitative differentiation method for plastic bags by infrared spectroscopy, thickness measurement and differential scanning calorimetry for tracing the source of illegal drugs. Forensic Sci Int 164:148
Yang L, Thomas P, Stuart B (2012) Discrimination of thermally treated low density polyethylenes using DSC and principal component analysis. J Therm Anal Calorim 108:445
Causin V, Marega C, Marigo A (2007) When polymers fail: a case report on a defective epoxy resin flooring. Eng Fail Anal 14:1394
Causin V, Marega C, Guzzini G et al (2004) Forensic analysis of poly(ethylene terephthalate) fibers by infrared spectroscopy. Appl Spectrosc 58:1272
Causin V, Marega C, Guzzini G et al (2005) The effect of exposure to the elements on the forensic characterization by infrared spectroscopy of poly(ethylene terephthalate) fibers. J Forensic Sci 50:887
Rajakumar K, Sarasvathy V, Thamarai Chelvan A et al (2009) Natural weathering studies of polypropylene. J Polym Environ 17:191
Horrocks AR, Mwila J, Miraftab M et al (1999) The influence of carbon black on properties of orientated polypropylene 2. Thermal and photodegradation. Polym Degrad Stab 65:25
Cherukupalli SS, Ogale AA (2004) Online measurements of crystallinity using Raman spectroscopy during blown film extrusion of a linear low-density polyethylene. Polym Eng Sci 44:1484
Quynn RG, Riley JL, Young DA et al (1959) Density, crystallinity, and heptane insolubility in isotactic polypropylene. J Appl Polym Sci 2:166
Nielsen AS, Batchelder DN, Pyrz R (2002) Estimation of crystallinity of isotactic polypropylene using Raman spectroscopy. Polymer 43:2671
Samuels RJ (1981) Application of refractive index measurements to polymer analysis. J Appl Polym Sci 26:1383
Dabbs MDG, Pearson EF (1972) Some physical properties of a large number of window glass specimens. J Forensic Sci 17:70
Causin V, Marega C, Schiavone S et al (2005) Employing glass refractive index measurement (GRIM) in fiber analysis: a simple method for evaluating the crystallinity of acrylics. Forensic Sci Int 149:193
Palenik SJ (1999) Microscopical examination of fibres. In: Robertson J, Grieve M (eds) Forensic examination of fibres. Taylor and Francis, London
Curran JM, Hicks TN, Buckleton JS (eds) (2000) Forensic interpretation of glass evidence. CRC Press, Boca Raton
Ojena SM, DeForest PR (1972) Precise refractive index determination by the immersion method, using phase contrast microscopy and the Mettler hot stage. J Forensic Sci 12:315
Abragam A (1983) Principles of nuclear magnetism. Oxford University Press, Oxford
Orza RA, Magusin PCMM, Litvinov VM et al (2007) Solid-state 1H NMR study on chemical cross-links, chain entanglements, and network heterogeneity in peroxide-cured EPDM rubbers. Macromolecules 40:8999
Chinn SC, Cook-Tendulkar A, Maxwell R et al (2007) Qualification of automated low-field NMR relaxometry for quality control of polymers in a production setting. Polym Test 26:1015
Jensen SM, Pedersen HT, Engelsen SB (1999) Application of chemometrics to low-field 1H NMR relaxation data of intact fish flesh. J Sci Food Agric 79:1793
Standard test method for hydrogen content of middle distillate petroleum products by low-resolution pulsed nuclear magnetic resonance spectroscopy (2005) ASTM International, 2003, West Conshohocken
Maus A, Hertlein C, Saalwaechter K (2006) A robust proton NMR method to investigate hard/soft ratios, crystallinity, and component mobility in polymers. Macromol Chem Phys 207:1150
Mauri M, Thomann Y, Schneider H et al (2008) Spin-diffusion NMR at low field for the study of multiphase solids. Solid State Nucl Magn Reson 34:125
Mauri M, Dibbanti MK, Calzavara M et al (2013) Time domain nuclear magnetic resonance: a key complementary technique for the forensic differentiation of foam traces. Anal Methods 5:4336
Mauri M, Mauri L, Causin V et al (2011) A method based on time domain nuclear magnetic resonance for the forensic differentiation of latex gloves. Anal Methods 3:1802
Carr HY, Purcell EM (1954) Effects of diffusion on free precession in nuclear magnetic resonance experiments. Phys Rev 94:630
Schmidt-Rohr K, Spiess HW (1999) Multidimensional solid-state NMR and polymers. Academic, San Diego
Smith JM (2007) Forensic examination of pressure sensitive tape. In: Blackledge RD (ed) Forensic analysis on the cutting edge. Wiley, Hoboken
De Wael K (2012) Dichroism measurements in forensic fibre examination. Part 4—dyed acrylic and acetate fibres. Sci Justice 52:81
De Wael K, Lepot L (2012) Dichroism measurements in forensic fibre examination: part 5—pigmented fibres. Sci Justice 52:161
De Wael K, Lepot L, Lunstroot K (2012) The use of linear dichroism in forensic fibre examinations—part 6. Validation and practical aspects of MSP-PPL. Sci Justice 52:249
De Wael K, Lepot L (2011) Dichroism measurements in forensic fibre examination part 3—dyed cotton and viscose fibres. Sci Justice 51:173
De Wael K, Vanden Driessche T (2011) Dichroism measurements in forensic fibre examination. Part 2—dyed polyamide, wool and silk fibres. Sci Justice 51:163
De Wael K, Vanden Driessche T (2011) Dichroism measurements in forensic fibre examination part 1—dyed polyester fibres. Sci Justice 51:57
Hedesiu C, Demco DE, Remerie K et al (2008) Study of uniaxially stretched isotactic poly(propylene) by 1H solid-state NMR and IR spectroscopy. Macromol Chem Phys 209:734
Cho LL, Reffner JA, Gatewood BM et al (1999) A new method for fiber comparison using polarized infrared microspectroscopy. J Forensic Sci 44:275
Boulet-Audet M, Lefevre T, Buffeteau T et al (2008) Attenuated total reflection infrared spectroscopy: an efficient technique to quantitatively determine the orientation and conformation of proteins in single silk fibers. Appl Spectrosc 62:956
Cho LL, Reffner JA, Wetzel DL (1999) Forensic classification of polyester fibers by infrared dichroic ratio pattern recognition. J Forensic Sci 44:283
Wetzel DL, Cho LL (1997) Single fiber characterization by polarization FT-IR microspectroscopy. Mikrochim Acta Suppl 14:349
Causin V (2010) Polymers on the crime scene: how can analytical chemistry help to exploit the information from these mute witnesses? Anal Methods 2:792
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Causin, V. (2015). Processing-Dependent Parameters: Structure and Morphology of Polymeric Materials. In: Polymers on the Crime Scene. Springer, Cham. https://doi.org/10.1007/978-3-319-15494-7_7
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DOI: https://doi.org/10.1007/978-3-319-15494-7_7
Publisher Name: Springer, Cham
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