Skip to main content
SpringerLink
Log in

Lithium-Sulfur Battery

  • Chapter
  • First Online:
Book cover Rechargeable Batteries

Part of the book series: Green Energy and Technology ((GREEN))

  • 6953 Accesses

Abstract

Lithium-sulfur (Li-S) batteries have been considered as one promising energy storage system for the electrification of vehicles, since their specific energy density is five times higher than that of lithium-ion batteries (2600 vs. 500 Wh kg−1). However, the insulating properties of the sulfur cathode, safety concerns of the lithium anode, and polysulfide shuttle effects in liquid electrolytes have hindered them from practical applications. In this book chapter, we first introduce brief fundamentals and key limitations associated with traditional Li-S batteries. We then focus discussion on recent advances in different components of Li-S liquid cells, including the sulfur cathode, the lithium anode, and the liquid electrolyte. We also discuss the important shift from traditional liquid cells to recent all-solid cells, with developments in both solid electrolyte and electrode material. Last but not least, we present future opportunities and perspectives for Li-S batteries.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Winter M, Brodd RJ (2004) Chem Rev 104:4245

    Article  Google Scholar 

  2. Bruce PG, Hardwick LJ, Abraham KM (2011) MRS Bull 36:506

    Article  Google Scholar 

  3. Cavaliere S, Subianto S, Savych I, Jones DJ, Roziere J (2011) Energy Environ Sci 4:4761

    Article  Google Scholar 

  4. Liu C, Li F, Ma LP, Cheng HM (2010) Adv Mater 22:E28

    Article  Google Scholar 

  5. Cairns EJ, Albertus P (2010) Annu Rev Chem Biomol 1:299

    Article  Google Scholar 

  6. Zhang WJ (2011) J Power Sources 196:13

    Article  Google Scholar 

  7. Yang Y, Zheng GY, Cui Y (2013) Chem Soc Rev 42:3018

    Article  Google Scholar 

  8. He XM, Pu WH, Ren JG, Wang L, Wang JL, Jiang CY, Wan CR (2007) Electrochim Acta 52:7372

    Article  Google Scholar 

  9. Li Q, Zhang ZA, Zhang K, Fang J, Lai YQ, Li J (2014) J Power Sources 256:137

    Article  Google Scholar 

  10. Peled E, Gorenshtein A, Segal M, Sternberg Y (1989) J Power Sources 26:269

    Article  Google Scholar 

  11. Manthiram A, Fu YZ, Su YS (2013) Acc Chem Res 46:1125

    Article  Google Scholar 

  12. Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) J Electrochem Soc 150:A796

    Article  Google Scholar 

  13. Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) J Electrochem Soc 150:A800

    Article  Google Scholar 

  14. Mikhaylik YV, Akridge JR (2004) J Electrochem Soc 151:A1969

    Article  Google Scholar 

  15. Su YS, Fu YZ, Cochell T, Manthiram A (2013) Nat Commun 4:1331

    Article  Google Scholar 

  16. Zhang SS (2013) J Power Sources 231:153

    Article  Google Scholar 

  17. Yin YX, Xin S, Guo YG, Wan LJ (2013) Angew Chem Int Ed 52:13186

    Article  Google Scholar 

  18. Scheers J, Fantini S, Johansson P (2014) J Power Sources 255:204

    Article  Google Scholar 

  19. Evers S, Nazar LF (2013) Acc Chem Res 46:1135

    Article  Google Scholar 

  20. Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2012) Nat Mater 11

    Google Scholar 

  21. Ellis BL, Lee KT, Nazar LF (2010) Chem Mater 22:691

    Article  Google Scholar 

  22. Marom R, Amalraj SF, Leifer N, Jacob D, Aurbach D (2011) J Mater Chem 21:9938

    Article  Google Scholar 

  23. Dunn B, Kamath H, Tarascon JM (2011) Science 334:928

    Article  Google Scholar 

  24. Wang J, Xin HLL, Wang DL (2014) Part Part Syst Char 31:515

    Article  Google Scholar 

  25. Fedorkova A, Orinakova R, Cech O, Sedlarikova M (2013) Int J Electrochem Sci 8:10308

    Google Scholar 

  26. Li WY, Zheng GY, Yang Y, Seh ZW, Liu N, Cui Y (2013) Proc Natl Acad Sci 110:7148

    Article  Google Scholar 

  27. Wei SC, Zhang H, Huang YQ, Wang WK, Xia YZ, Yu ZB (2011) Energy Environ Sci 4:736

    Article  Google Scholar 

  28. Shim J, Striebel KA, Cairns EJ (2002) J Electrochem Soc 149:A1321

    Article  Google Scholar 

  29. Zhang SC, Zhang L, Wang WK, Xue WJ (2010) Synthetic Met 160:2041

    Article  Google Scholar 

  30. Wang C, Chen JJ, Shi YN, Zheng MS, Dong QF (2010) Electrochim Acta 55:7010

    Article  Google Scholar 

  31. Ji XL, Lee KT, Nazar LF (2009) Nat Mater 8:500

    Article  Google Scholar 

  32. Xu GL, Xu YF, Fang JC, Peng XX, Fu F, Huang L, Li JT, Sun SG (2013) Acs Appl Mater Inter 5:10782

    Article  Google Scholar 

  33. Yu LH, Brun N, Sakaushi K, Eckert J, Titirici MM (2013) Carbon 61:245

    Article  Google Scholar 

  34. Xi K, Cao S, Peng XY, Ducati C, Kumar RV, Cheetham AK (2013) Chem Commun 49:2192

    Article  Google Scholar 

  35. Wang XF, Fang XP, Guo XW, Wang ZX, Chen LQ (2013) Electrochim Acta 97:238

    Article  Google Scholar 

  36. Tao XY, Chen XR, Xia Y, Huang H, Gan YP, Wu R, Chen F, Zhang WK (2013) J Mater Chem A 1:3295

    Article  Google Scholar 

  37. Wang DW, Zeng QC, Zhou GM, Yin LC, Li F, Cheng HM, Gentle IR, Lu GQM (2013) J Mater Chem A 1:9382

    Article  Google Scholar 

  38. Ye H, Yin YX, Xin S, Guo YG (2013) J Mater Chem A 1:6602

    Article  Google Scholar 

  39. Zhao SR, Li CM, Wang WK, Zhang H, Gao MY, Xiong X, Wang AB, Yuan KG, Huang YQ, Wang F (2013) J Mater Chem A 1:3334

    Article  Google Scholar 

  40. Hwang TH, Jung DS, Kim JS, Kim BG, Choi JW (2013) Nano Lett 13:4532

    Article  Google Scholar 

  41. Lu ST, Cheng YW, Wu XH, Liu J (2013) Nano Lett 13:2485

    Article  Google Scholar 

  42. Park MS, Yu JS, Kim KJ, Jeong G, Kim JH, Yim T, Jo YN, Hwang U, Kang S, Woo T, Kim H, Kim YJ (2013) Rsc Adv 3:11774

    Article  Google Scholar 

  43. Yang X, Zhang L, Zhang F, Huang Y, Chen YS (2014) ACS Nano 8:5208

    Article  Google Scholar 

  44. Ma XZ, Jin B, Xin PM, Wang HH (2014) Appl Surf Sci 307:346

    Article  Google Scholar 

  45. He G, Mandlmeier B, Schuster J, Nazar LF, Bein T (2014) Chem Mater 26:3879

    Article  Google Scholar 

  46. Ding B, Yuan CZ, Shen LF, Xu GY, Nie P, Zhang XG (2013) Chem Eur J 1013:19

    Google Scholar 

  47. Wang B, Wen YF, Ye DL, Yu H, Sun B, Wang GX, Hulicova-Jurcakova D, Wang LZ (2014) Chem Eur J 20:5224

    Article  Google Scholar 

  48. Wang JL, Yin LC, Jia H, Yu HT, He YS, Yang J, Monroe CW (2014) ChemSusChem 7:563

    Article  Google Scholar 

  49. Chung SH, Manthiram A (2014) Electrochem Commun 38:91

    Article  Google Scholar 

  50. Zhou L, Lin XJ, Huang T, Yu AS (2014) Electrochim Acta 116:210

    Article  Google Scholar 

  51. Huang JQ, Peng HJ, Liu XY, Nie JQ, Cheng XB, Zhang Q, Wei F (2014) J Mater Chem A 2:10869

    Article  Google Scholar 

  52. Qu YH, Zhang ZA, Wang XW, Lai YQ, Liu YX, Li J (2013) J Mater Chem A 1:14306

    Article  Google Scholar 

  53. Jin KK, Zhou XF, Zhang LZ, Xin X, Wan GH, Liu ZP (2013) J Phys Chem C 117:21112

    Article  Google Scholar 

  54. Cheng XB, Huang JQ, Zhang Q, Peng HJ, Zhao MQ, Wei F (2014) Nano Energy 4:65

    Article  MATH  Google Scholar 

  55. Brun N, Sakaushi K, Yu LH, Giebeler L, Eckert J, Titirici MM (2013) Phys Chem Chem Phys 15:6080

    Article  Google Scholar 

  56. Lu ST, Chen Y, Wu XH, Wang ZD, Lv LY, Qin W, Jiang LX (2014) Rsc Adv 4:18052

    Article  Google Scholar 

  57. Tang JJ, Yang J, Zhou XY (2013) Rsc Adv 3:16936

    Article  Google Scholar 

  58. Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ (2012) J Am Chem Soc 134:18510

    Article  Google Scholar 

  59. Qu Y, Zhang Z, Zhang X, Ren G, Lai Y, Liu Y, Li J (2015) J Mater Chem A 84:399

    Google Scholar 

  60. Strubel P, Thieme S, Biemelt T, Helmer A, Oschatz M, Brückner J, Althues H, Kaskel S (2015) Adv Funct Mater 25:287

    Article  Google Scholar 

  61. Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Nature 438:197

    Article  Google Scholar 

  62. Zhang YG, Zhao Y, Konarov A, Gosselink D, Soboleski HG, Chen P (2013) J Power Sources 241:517

    Article  Google Scholar 

  63. Lu LQ, Lu LJ, Wang Y (2013) J Mater Chem A 1:9173

    Article  Google Scholar 

  64. Lin TQ, Tang YF, Wang YM, Bi H, Liu ZQ, Huang FQ, Xie XM, Jiang MH (2013) Energ. Environ Sci 6:1283

    Google Scholar 

  65. Huang JQ, Liu XF, Zhang Q, Chen CM, Zhao MQ, Zhang SM, Zhu WC, Qian WZ, Wei F (2013) Nano Energy 2:314

    Article  Google Scholar 

  66. Yan Y, Yin YX, Xin S, Guo YG, Wan LJ (2012) Chem Commun 48:10663

    Article  Google Scholar 

  67. Li NW, Zheng MB, Lu HL, Hu ZB, Shen CF, Chang XF, Ji GB, Cao JM, Shi Y (2012) Chem Commun 48:4106

    Article  Google Scholar 

  68. Ji LW, Rao MM, Zheng HM, Zhang L, Li YC, Duan WH, Guo JH, Cairns EJ, Zhang YG (2011) J Am Chem Soc 133:18522

    Article  Google Scholar 

  69. Yu M, Wang A, Tian F, Song H, Wang Y, Li C, Hong J-D, Shi G (2015) Nanoscale 7:5292

    Article  Google Scholar 

  70. Zhao Y, Wu W, Li J, Xu Z, Guan L (2014) Adv Mater 26:5113

    Article  Google Scholar 

  71. Sun L, Kong W, Jiang Y, Wu H, Jiang K, Wang J, Fan S (2015) J Mater Chem A 3:5305

    Article  Google Scholar 

  72. Yin LC, Wang JL, Yang J, Nuli YN (2011) J Mater Chem 21:6807

    Article  Google Scholar 

  73. Xiao LF, Cao YL, Xiao J, Schwenzer B, Engelhard MH, Saraf LV, Nie ZM, Exarhos GJ, Liu J (2012) Adv Mater 24:1176

    Article  Google Scholar 

  74. Wu F, Chen JZ, Chen RJ, Wu SX, Li L, Chen S, Zhao T (2011) J Phys Chem C 115:6057

    Article  Google Scholar 

  75. Zhang Z, Li Q, Lai YQ, Li J (2014) J Phys Chem C 118:13369

    Article  Google Scholar 

  76. Jin J, Wen ZY, Ma GQ, Lu Y, Rui K (2014) Solid State Ionics 262:170

    Article  Google Scholar 

  77. Aleksandrov IA, Abramchuk SS, Solodovnikov SP, Zezin SB, Shevchenko VG, Aleksandrov AI (2012) Polym Sci Ser 54:407

    Article  Google Scholar 

  78. Wang W, Li GC, Wang Q, Li GR, Ye SH, Gao XP (2013) J Electrochem Soc 160:A805

    Article  Google Scholar 

  79. Zhang YG, Bakenov Z, Zhao Y, Konarov A, The NLD, Malik M, Paron T, Chen P (2012) J Power Sources 208:1

    Article  Google Scholar 

  80. Zhou WD, Yu YC, Chen H, DiSalvo FJ, Abruna HD (2013) J Am Chem Soc 135:16736

    Article  Google Scholar 

  81. Wang X, Zhang Z, Yan X, Qu Y, Lai Y, Li J (2015) Interface polymerization synthesis of conductive polymer/graphite oxide@sulfur composites for high-rate lithium-sulfur batteries. Electrochem Acta 155:54

    Google Scholar 

  82. Yang Y, Zheng GY, Misra S, Nelson J, Toney MF, Gui Y (2012) J Am Chem Soc 134:15387

    Article  Google Scholar 

  83. Yang ZC, Guo JC, Das SK, Yu YC, Zhou ZH, Abruna HD, Archer LA (2013) J Mater Chem A 1:1433

    Article  Google Scholar 

  84. Jeong S, Bresser D, Buchholz D, Winter M, Passerini S (2013) J Power Sources 235:220

    Article  Google Scholar 

  85. Yang Y, McDowell MT, Jackson A, Cha JJ, Hong SS, Cui Y (2010) Nano Lett 10:1486

    Article  Google Scholar 

  86. Hassoun J, Sun YK, Scrosati B (2011) J Power Sources 196:343

    Article  Google Scholar 

  87. Fu YZ, Su YS, Manthiram A (2014) Adv Energy Mater 4:1300655

    Google Scholar 

  88. Lin Z, Nan C, Ye Y, Guo J, Zhu J, Cairns EJ (2014) Nano Energy 9:408

    Article  Google Scholar 

  89. Nan C, Lin Z, Liao H, Song M-K, Li Y, Cairns EJ (2014) J Am Chem Soc 136:4659

    Article  Google Scholar 

  90. Xiong SZ, Kai X, Hong XB, Diao Y (2012) Ionics 18:249

    Article  Google Scholar 

  91. Aurbach D, Pollak E, Elazari R, Salitra G, Kelley CS, Affinito J (2009) J Electrochem Soc 156:A694

    Article  Google Scholar 

  92. Lin Z, Liu ZC, Fu WJ, Dudney NJ, Liang CD (2013) Adv Funct Mater 1064:23

    Google Scholar 

  93. Zheng G, Lee SW, Liang Z, Lee H-W, Yan K, Yao H, Wang H, Li W, Chu S, Cui Y (2014) Nat Nanotech 9:618

    Article  Google Scholar 

  94. Zhao Y, Wu WL, Li JX, Xu ZC, Guan LH (2014) Adv Mater 26:5113

    Article  Google Scholar 

  95. Wu FX, Kim H, Magasinski A, Lee JT, Lin HT, Yushin G (2014) Adv Energy Mater 4. doi:10.1002/aenm.201400196

  96. Sun L, Li MY, Jiang Y, Kong WB, Jiang KL, Wang JP, Fan SS (2014) Nano Lett 14:4044

    Article  Google Scholar 

  97. Rong JP, Ge MY, Fang X, Zhou CW (2014) Nano Lett 14:473

    Article  Google Scholar 

  98. Chang DR, Lee SH, Kim SW, Kim HT (2002) J Power Sources 112:452

    Article  Google Scholar 

  99. Ryu HS, Ahn HJ, Kim KW, Ahn JH, Cho KK, Nam TH, Kim JU, Cho GB (2006) J Power Sources 163:201

    Article  Google Scholar 

  100. Choi JW, Kim JK, Cheruvally G, Ahn JH, Ahn HJ, Kim KW (2007) Electrochim Acta 52:2075

    Article  Google Scholar 

  101. Gao J, Lowe MA, Kiya Y, Abruna HD (2011) J Phys Chem C 115:25132

    Article  Google Scholar 

  102. Wang JL, Yang J, Wan CR, Du K, Xie JY, Xu NX (2003) Adv Funct Mater 13:487

    Article  Google Scholar 

  103. Wang JL, Yang J, Xie JY, Xu NX (2002) Adv Mater 14:963

    Article  Google Scholar 

  104. Yuan LX, Feng JK, Ai XP, Cao YL, Chen SL, Yang HX (2006) Electrochem Commun 8:610

    Article  Google Scholar 

  105. Rao MM, Song XY, Cairns EJ (2012) J Power Sources 205:474

    Article  Google Scholar 

  106. Shin JH, Cairns EJ (2008) J Power Sources 177:537

    Article  Google Scholar 

  107. Song M-K, Zhang Y, Cairns EJ (2013) Nano Lett 13:5891

    Article  Google Scholar 

  108. Peled E, Sternberg Y, Gorenshtein A, Lavi Y (1989) J Electrochem Soc 136:1621

    Article  Google Scholar 

  109. Yamin H, Gorenshtein A, Penciner J, Sternberg Y, Peled E (1988) J Electrochem Soc 1045:135

    Google Scholar 

  110. Park JW, Ueno K, Tachikawa N, Dokko K, Watanabe M (2013) J Phys Chem C 117:20531

    Article  Google Scholar 

  111. Ueno K, Park JW, Yamazaki A, Mandai T, Tachikawa N, Dokko K, Watanabe M (2013) J Phys Chem C 117:20509

    Article  Google Scholar 

  112. Weng W, Pol VG, Amine K (2013) Adv Mater 25:1608

    Article  Google Scholar 

  113. Park MS, Jeong BO, Kim TJ, Kim S, Kim KJ, Yu JS, Jung Y, Kim YJ (2014) Carbon 68:265

    Article  Google Scholar 

  114. Agrawal RC, Pandey GP (2008) J Phys D-Appl Phys 41

    Google Scholar 

  115. Quartarone E, Mustarelli P (2011) Chem Soc Rev 40:2525

    Article  Google Scholar 

  116. Bouchet R, Maria S, Meziane R, Aboulaich A, Lienafa L, Bonnet JP, Phan TNT, Bertin D, Gigmes D, Devaux D, Denoyel R, Armand M (2013) Nat Mater 12:452

    Article  Google Scholar 

  117. Jeddi K, Ghaznavi M, Chen P (2013) J Mater Chem A 1:2769

    Article  Google Scholar 

  118. Marmorstein D, Yu TH, Striebel KA, McLarnon FR, Hou J, Cairns EJ (2000) J Power Sources 89:219

    Article  Google Scholar 

  119. Nagao M, Imade Y, Narisawa H, Kobayashi T, Watanabe R, Yokoi T, Tatsumi T, Kanno R (2013) J Power Sources 222:237

    Article  Google Scholar 

  120. Youngsik K, Arumugam N, Goodenough JB (2008) Chem Mater 20:470

    Article  Google Scholar 

  121. Nagao M, Hayashi A, Tatsumisago M (2011) Electrochim Acta 56:6055

    Article  Google Scholar 

  122. Liang XA, Wen ZY, Liu Y, Zhang H, Huang LZ, Jin J (2011) J Power Sources 196:3655

    Article  Google Scholar 

  123. Kamaya N, Homma K, Yamakawa Y, Hirayama M, Kanno R, Yonemura M, Kamiyama T, Kato Y, Hama S, Kawamoto K, Mitsui A (2011) Nat Mater 10:682

    Article  Google Scholar 

  124. Hakari T, Nagao M, Hayashi A, Tatsumisago M (2014) Solid State Ionics 262:147

    Article  Google Scholar 

  125. Nagao M, Hayashi A, Tatsumisago M (2011) J Power Sources 196:6902

    Article  Google Scholar 

  126. Hayashi A, Ohtsubo R, Nagao M, Tatsumisago M (2010) J Mater Sci 45:377

    Article  Google Scholar 

  127. Ohtomo T, Hayashi A, Tatsumisago M, Kawamoto K (2013) J Non-Cryst Solids 364:57

    Article  Google Scholar 

  128. Ito Y, Sakuda A, Ohtomo T, Hayashi A, Tatsumisago M (2013) Solid State Ionics 236:1

    Article  Google Scholar 

  129. Muramatsu H, Hayashi A, Ohtomo T, Hama S, Tatsumisago M (2011) Solid State Ionics 182:116

    Article  Google Scholar 

  130. Liu ZC, Fu WJ, Payzant EA, Yu X, Wu ZL, Dudney NJ, Kiggans J, Hong KL, Rondinone AJ, Liang CD (2013) J Am Chem Soc 135:975

    Article  Google Scholar 

  131. Lin Z, Liu ZC, Dudney NJ, Liang CD (2013) ACS Nano 7:2829

    Article  Google Scholar 

  132. Lin Z, Liu Z, Fu W, Dudney NJ, Liang C (2013) Angew Chem Int Ed 52:7460

    Article  Google Scholar 

  133. Sahu G, Lin Z, Li JC, Liu ZC, Dudney N, Liang CD (2014) Energy Environ Sci 1053:7

    Google Scholar 

  134. Hayashi A, Ohtomo T, Mizuno F, Tadanaga K, Tatsumisago M (2003) Electrochem Commun 5:701

    Article  Google Scholar 

  135. Takeuchi T, Kageyama H, Nakanishi K, Tabuchi M, Sakaebe H, Ohta T, Senoh H, Sakai T, Tatsumi K (2010) J Electrochem Soc 157:A1196

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, People’s Republic of China

    Shuli Li & Zhan Lin

Authors
  1. Shuli Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhan Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhan Lin .

Editor information

Editors and Affiliations

  1. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois, USA

    Zhengcheng Zhang

  2. Sensors and Electron Devices Directorate, U.S. Army Research Laboratory, Adelphi, Maryland, USA

    Sheng Shui Zhang

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Li, S., Lin, Z. (2015). Lithium-Sulfur Battery. In: Zhang, Z., Zhang, S. (eds) Rechargeable Batteries. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-15458-9_21

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-15458-9_21

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-15457-2

  • Online ISBN: 978-3-319-15458-9

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics

Search

Navigation