Abstract
Based on surface/interfacial tension isotherms measured for the homologous series of alkyl trimethyl ammonium bromides (CnTAB) using the drop profile analysis tensiometry the adsorption behavior at three different liquid-fluid interfaces is discussed: solution/air, solution/hexane vapor and solution/hexane bulk liquid. The adsorption behavior can be described by different models. In the presence of hexane molecules (as a bulk liquid or as vapor in the air phase) the adsorption of the CnTAB molecules can be best described by a competitive adsorption with hexane molecules. This competitive thermodynamic model can be applied successfully to all three interfaces.
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Acknowledgements
The work was supported by projects of the DFG (Mi418/18-2), the DLR (50WM1129), and the COST actions CM1101 and MP1106.
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Mucic, N. et al. (2015). Thermodynamic Models for the Adsorption of Alkyl Trimethyl Ammonium Bromides at the Water/Hexane Interface. In: Kind, M., Peukert, W., Rehage, H., Schuchmann, H. (eds) Colloid Process Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-15129-8_13
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DOI: https://doi.org/10.1007/978-3-319-15129-8_13
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