Abstract
The salts of milk are mainly the phosphates, citrates, chlorides, sulphates, carbonates and bicarbonates of sodium, potassium, calcium and magnesium. Approximately 20 other elements are found in milk in trace quantities, including copper, iron, lead, boron, manganese, zinc, iodine, etc. Strictly speaking, the proteins of milk should be included as part of the salt system since these carry positively and negatively charged groups and can form salts with counter-ions; however, they are not normally treated as such. There is no lactate in freshly drawn milk but may be present in stored milk and in milk products. Many of the inorganic elements are of importance in nutrition, in the preparation, processing and storage of milk products due to their marked influence on the conformation and stability of milk proteins, especially caseins, in the activity of some indigenous enzymes and to a lesser extent in the stability of lipids.
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References
Buldini, P. L., Cavalli, S., & Sharma, J. L. (2002). Matrix removal for the ion chromatographic determination of some trace elements in milk. Microchemical Journal, 72, 277–284.
Choi, J., Horne, D. S., & Lucey, J. A. (2011). Determination of molecular weight of a purified fraction of colloidal calcium phosphate derived from the casein micelles of bovine milk. Journal of Dairy Science, 94, 3250–3261.
Crowley, S. V., Kelly, A. L., & O’Mahony, J. A. (2014a). Fortification of reconstituted skim milk powder with different calcium salts: Impact of physicochemical changes on stability to processing. International Journal of Dairy Technology, 67, 474–482.
Crowley, S. V., Megemont, M., Gazi, I., Kelly, A. L., Huppertz, T., & O’Mahony, J. A. (2014b). Heat stability of reconstituted milk protein concentrate powders. International Dairy Journal, 37, 104–110.
Davies, D. T., & White, J. C. D. (1962). The determination of calcium and magnesium in milk and milk diffusate. Journal of Dairy Research, 29, 285–296.
Demott, B. J. (1968). Ionic calcium in milk and whey. Journal of Dairy Science, 51, 1008–1012.
Gaucheron, F. (2010). Analysing and improving the mineral content of milk. Cambridge: Woodhead Publishing.
Gaucheron, F. (2011). Milk salts: Distribution and analysis. In Encyclopedia of dairy sciences (2nd ed., pp. 908–916). Academic Press, Oxford, UK.
Holt, C. (1985). The milk salts: Their secretion, concentration and physical chemistry. In P. F. Fox (Ed.), Developments in dairy chemistry, volume 3, lactose and minor constituents (pp. 143–181). London: Elsevier Applied Science.
Holt C., Dalgleish, D.G. and Jenness, R. (1981). Calculation of the ion equilibria in milk diffusate and comparison with experiment. Analytical Biochemistry, 113, 154–163.
Holt, C., Timmins, P. A., Errington, N., & Leaver, J. (1998). A core-shell model of calcium phosphate nanoclusters stabilised by β-casein phosphopeptides, derived from sedimentation equilibrium and small-angle X-ray and neutron-scattering measurements. European Journal of Biochemistry, 252, 73–78.
Holt, C., Carver, J. A., Ecroyd, H., & Thorn, D. C. (2013). Caseins and the casein micelle: Their biological functions, structures, and behaviour in foods. Journal of Dairy Science, 96, 6127–6146.
Holt, C., Lenton, S., Nylander, T., Sørensen, E. S., & Teixeira, S. C. M. (2014). Mineralisation of soft and hard tissues and the stability of biofluids. Journal of Structural Biology, 185, 383–396.
Izco, J. M., Tormo, M., Harris, A., Tong, P. S., & Jimenez-Flores, R. (2003). Optimisation and validation of a rapid method to determine citrate and inorganic phosphate in milk by capillary electrophoresis. Journal of Dairy Science, 86, 86–95.
Jenness, R., & Koops, J. (1962). Preparation and properties of salt solution which simulates milk ultrafiltrate. Netherlands Milk and Dairy Journal, 16, 153–164.
Lewis, M. J. (2011). The measurement and significance of ionic calcium in milk – a review. International Journal of Dairy Technology, 1, 1–13.
Lucey, J. A., Hauth, B., Gorry, C., & Fox, P. F. (1993). The acid-base buffering properties of milk. Milchwissenschaft, 48, 268–272.
Lyster, R. L. J. (1981). Calculation by computer of individual concentrations in a simulated milk salt solution. II. An extension to the previous model. Journal of Dairy Research, 48, 85–89.
McGann, T. C. A., Buchheim, W., Kearney, R. D., & Richardson, T. (1983). Composition and ultrastructure of calcium phosphate - citrate complexes in bovine milk systems. Biochimica et Biophysica Acta, 760, 415–420.
Mutzelburg, I. D. (1979). An enzymatic method for the determination of citrate in milk. Australian Journal of Dairy Technology, 34, 82–84.
Pierre, A., & Brule, G. (1983). Dosage rapide du citrate dans l’ultrafiltrat de lait par complexation cuivrique. Le Lait, 63, 66–74.
Pyne, G. T. (1962). A review on the progress of dairy science. Some aspects of the physical chemistry of the salts in milk. Journal of Dairy Research, 29, 101–130.
Pyne, G. T., & McGann, T. C. A. (1960). The colloidal phosphate of milk. II. Influence of citrate. Journal of Dairy Research, 27, 9–17.
Rose, D., & Tessier, H. (1959). Composition of ultra-filtrates from milk heated at 80 to 220 °F in relation to heat stability. Journal of Dairy Science, 42, 969–980.
Rulliere, C., Rondeau-Mouro, C., Raouche, S., Dufrechou, M., & Marchesseau, S. (2013). Studies of polyphosphate composition and their interaction with dairy matrices by ion chromatography and 31P NMR spectroscopy. International Dairy Journal, 28, 102–108.
Salaun, F., Mietton, B., & Gaucheron, F. (2005). Buffering capacity of dairy products. International Dairy Journal, 15, 95–109.
Schmidt, D. G. (1982). Association of caseins and casein micelle structure. In P. F. Fox (Ed.), Developments in Dairy Chemistry, Vol. 1. Protein (pp. 61–86). London: Elsevier Applied Science.
Smeets, W. J. G. M. (1955). The determination of the concentration of calcium ions in milk ultrafiltrate. Netherland Milk and Dairy Journal, 9, 249–260.
Sundekilde, U. K., Poulsen, N. A., Larsen, L. B., & Bertram, H. C. (2013). Nuclear magnetic resonance metabonomics reveals strong association between milk metaolites and somatic cell count in bovine milk. Journal of Dairy Science, 96, 290–299.
Tessier, H., & Rose, D. (1958). Calcium ion concentration in milk. Journal of Dairy Science, 41, 351–359.
White, J. C. D., & Davies, D. T. (1963). The determination of citric acid in milk and milk sera. Journal of Dairy Research, 30, 171–189.
Suggested Reading
Considine, T., Flanagan, J. and Loveday, S.M. (2014). Interations between Milk Proteins and Micronutrients. Milk Proteins: From Expression to Food. 2nd Edition. H. Singh, M. Boland, A. Thompson, eds. Academic Press, London. pp. 421–449.
Davies, D. T., & White, J. C. D. (1960). The use of ultrafiltration and dialysis in isolating the aqueous phase of milk and in determining the partition of milk constituents between the aqueous and disperse phases. Journal of Dairy Research, 27, 171–190.
de la Fuente, M. A. (1998). Changes in the mineral balance of milk submitted to technological treatments. Trends in Food Science and Technology, 9, 281–288.
Edmonson, L. F., & Tarassuk, N. P. (1956). Studies on the colloidal proteins of skim milk. II. The effect of heat and disodium phosphate on the composition of the casein complex. Journal of Dairy Science, 49, 123–128.
Fiske, C. H., & Stubbarow, J. J. (1925). The colorimetric determination of phosphorus. Journal of Biological Chemistry, 66, 375–400.
Gao, R., Temminghoff, E. J. M., van Leeuwen, H. P., van Valenberg, H. J. F., Eisner, M. D., & van Boekel, M. A. J. S. (2009). Simultaneous determination of free calcium, magnesium, sodium and potassium ion concentrations in simulated milk ultrafiltrate and reconstituted skim milk using the Donnan Membrane Technique. International Dairy Journal, 19, 431–436.
Gaucheron, F. (2000). Iron fortification in dairy industry. Trends in Food Science and Technology, 11, 403–409.
Greenwald, I., Redish, J., & Kibrick, A. (1940). The dissociation of calcium phosphates. Journal of Biological Chemistry, 135, 65–76.
Hastings, A. B., McLean, F. C., Eichelberger, L., Hall, J. L., & DaCosta, E. (1934). The ionization of calcium, magnesium, and strontium citrates. Journal of Biological Chemistry, 107, 351–370.
Jenness, R., & Patton, S. (1959). The effects of heat on milk. In Principles of dairy chemistry (pp. 329–334). New York: John Wiley & Sons.
Marier, J. R., & Boulet, M. (1958). Direct determination of citric acid in milk with an improved pyridine-acetic anhydride method. Journal of Dairy Science, 41, 1683–1692.
McMeckin, J. L., & Groves, M. L. (1964). In B. H. Webb, A. H. Johnson, & J. A. Alford (Eds.), Fundamentals of dairy chemistry (2nd ed.). Westport, CT: AVI Publication Corporation.
Mekmene, O., Le Graet, Y. L., & Gaucheron, F. (2009). A model for predicting salt equilibria in milk and mineral-enriched milks. Food Chemistry, 116, 233–239.
Miller, P. G., & Sommer, H. H. (1940). The coagulation temperature of milk as affected by pH, salts, evaporation and previous heat treatment. Journal of Dairy Science, 23, 405–421.
On-Nom, N., Grandison, A. S., & Lewis, M. J. (2010). Measurement of ionic calcium, pH and soluble divalent cations in milk at high temperature. Journal of Dairy Science, 93, 515–523.
Pyne, G. T., & Ryan, J. J. (1950). The colloidal phosphate of milk. I. Composition and titrimetric estimation. Journal of Dairy Research, 17, 200–205.
Rose, D. (1965). Protein stability problems. Journal of Dairy Science, 48, 139–146.
Tabor, H., & Hastings, A. B. (1943). The ionization constant of secondary magnesium phosphate. Journal of Biological Chemistry, 148, 627–632.
Verma, T. S., & Sommer, H. H. (1957a). Study of the naturally occurring salts in milk. Journal of Dairy Science, 40, 331.
Verma, T. S., & Sommer, H. H. (1957b). Study of the naturally occurring salts in milk. Journal of Dairy Science, 40, 331.
White, J. C. D., & Davies, D. T. (1958). The relation between the chemical composition of milk and the stability of the caseinate complex. I. General introduction, description of samples, methods, and chemical composition of samples. Journal of Dairy Research, 25, 236–255.
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Fox, P.F., Uniacke-Lowe, T., McSweeney, P.L.H., O’Mahony, J.A. (2015). Salts of Milk. In: Dairy Chemistry and Biochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-14892-2_5
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DOI: https://doi.org/10.1007/978-3-319-14892-2_5
Publisher Name: Springer, Cham
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