Abstract
This chapter discusses the “potential” climatic role of hydrocarbon gas seepage in the geological past. Today, total geological methane emissions represent the second largest natural source of methane, following wetlands, and are comparable, in terms of magnitude, to other anthropogenic sources. To understand what happened in the past and whether or not seepage influenced pre-anthropogenic climate change, two important considerations must be taken into account. The first consideration is whether or not it is logical to assume, in the absence of man-made methane sources before the industrial revolution and during pre-anthropogenic time periods (>5,000 years ago), that gas seepage was the second largest methane source in absolute terms and therefore constituted a major control on variations in atmospheric methane burden. The second consideration is whether or not seepage has been constant over geological time periods. Using specific references to Late Quaternary and Cenozoic geological time scale changes, this chapter discusses how seepages, as a result of geological factors that change over time, may have influenced global climate. We obtain a sense of the potential impact of gas seepage on climate over long geological time scales if seepage is considered to be a part of a dynamic carbon cycle, which includes a gigantic reservoir of organic carbon buried in sedimentary basins.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Allen PA, Allen JR (2006) Basin analysis. Blackwell, Oxford, 549 pp
Blunier T, Brook E (2001) Timing of millenial-scale climate changes in antarctica and greenland during the last glacial period. Science 291:109–112
Bock M, Schmitt J, Möller L, Spahni R, Blunier T, Fischer H (2010) Hydrogen isotopes preclude marine hydrate CH4 emissions at the onset of Dansgaard-Oeschger events. Science 328:1686–1689
Brook E, Sowers T, Orchardo J (1996) Rapid variations in atmospheric methane concentration during the past 110,000 years. Science 273:1087–1091
Campbell KA (2006) Hydrocarbon seep and hydrothermal vent paleoenvironments: past developments and future research directions. Palaeogeogr Palaeoclimatol Palaeoecol 232:362–407
Cantrell CA, Shetter RE, McDaniel AH, Calvert JG, Davidson JA, Lowe DC, Tyler SC, Cicerone RJ, Greenberg JP (1990) Carbon kinetic isotope effect in the oxidation of methane by the hydroxyl radical. J Geophys Res 95:22,455–22,462
Chappellaz J, Barnola JM, Raynaud D, Korotkevich YS, Lorius C (1990) Ice-core record of atmospheric methane over the past 160,000 years. Nature 345:127–131
Chappellaz J, Fung IY, Thompson AM (1993) The atmospheric CH4 increase since the last glacial maximum (1) source estimates. Tellus 45B:228–241
Ciais P, Sabine C, Bala G, Bopp L, Brovkin V, Canadell J, Chhabra A, DeFries R, Galloway J, Heimann M, Jones C, Le Quéré C, Myneni RB, Piao S, Thornton P (2013) Carbon and other biogeochemical cycles. In: Stocker TF et al (eds) Climate change 2013: the physical science basis. Contribution of working group i to the fifth assessment report of IPCC. Cambridge University Press, Cambridge, UK and New York, NY, USA
Coleman DD, Liu C-L, Riley KM (1988) Microbial methane in the shallow paleozoic sediments and glacial deposits of illinois, U.S.A. Chem Geol 71:23–40
Colli B, De Ascentiis A (2003) Il Cenerone: vulcanello di fango di Pineto. De rerum natura. Periodico di informazione sull’ambiente, n.35–36, anno XI
Conti S, Fontana D, Gubertini A, Sighinolfi G, Tateo F, Fioroni C, Fregni P (2004) A multidisciplinary study of middle miocene seep-carbonates from the northern apennine foredeep (Italy). Sedim Geol 169:1–19
Cramer B, Poelchau HS, Gerling P, Lopatin NV, Litke R (1999) Methane released from groundwater—The source of natural gas accumulations in northern West Siberia. Mar Pet Geol 16:225–244
Crutzen PJ, Bruhl C (1993) A model study of atmospheric temperatures and the concentrations of ozone, hydroxyl, and some other photochemically active gases during the glacial, the preindustrial holocene and the present. Geoph Res Lett 20:1047–1050
Dickens GR, Paull CK, Wallace P (1997) The ODP leg 164 scientific party direct measurement of in situ methane quantities in a large gas-hydrate reservoir. Nature 385:426–428
Etiope G, Feyzullayev A, Baciu CL (2009) Terrestrial methane seeps and mud volcanoes: a global perspective of gas origin. Mar Pet Geol 26:333–344
Etiope G, Klusman RW (2002) Geologic emissions of methane to the atmosphere. Chemosphere 49:777–789
Etiope G, Klusman RW (2010) Microseepage in drylands: flux and implications in the global atmospheric source/sink budget of methane. Global Planet Change 72:265–274
Etiope G, Papatheodorou G, Christodoulou D, Ferentinos G, Sokos E, Favali P (2006) Methane and hydrogen sulfide seepage in the NW Peloponnesus petroliferous basin (Greece): origin and geohazard. AAPG Bull 90:701–713
Etiope G, Martinelli G, Caracausi A, Italiano F (2007) Methane seeps and mud volcanoes in Italy: gas origin, fractionation and emission to the atmosphere. Geoph Res Lett 34:L14303. doi:10.1029/2007GL030341
Etiope G, Milkov AV, Derbyshire E (2008) Did geologic emissions of methane play any role in Quaternary climate change? Global Planet Change 61:79–88
Etiope G, Panieri G, Fattorini D, Regoli F, Vannoli P, Italiano F, Locritani M, Carmisciano C (2014) A thermogenic hydrocarbon seep in shallow Adriatic Sea (Italy): gas origin, sediment contamination and benthic foraminifera. Mar Pet Geol 57:283–293
Etiope G, Sherwood Lollar B (2013) Abiotic methane on Earth. Rev Geoph 51:276–299
Fischer H, Behrens M, Bock M, Richter U, Schmitt J, Loulergue L, Chappellaz J, Spahni R, Blunier T, Leuenberger M, Stocker TF (2008) Changing boreal methane sources and constant biomass burning during the last termination. Nature 452:864–867
Formolo MJ, Salacup JM, Petsch ST, Martini AM, Nusslein K (2008) A new model linking atmospheric methane sources to Pleistocene glaciation via methanogenesis in sedimentary basins. Geology 36:139–142
Fowler SR, Mildenhall J, Zalova S (2000) Mud volcanoes and structural development on Shah Deniz. J Pet Sci Eng 28:189–206
Greinert J, Bohrmann G, Suess E (2001) Methane venting and gas hydrate-related carbonates at the hydrate ridge: their classification, distribution and origin. In: Paull CK, Dillon WP (eds) Natural gas hydrates: occurence, distribution, and detection. Geophysical Monograph, vol 124. American Geophysical Union, Washington, DC, pp 99–113
Higgins JA, Schrag DP (2006) Beyond methane: towards a theory for the paleocene-eocene thermal maximum. Earth Planet Sci Lett 245:523–537
Hinrichs K-U, Hmelo LR, Sylva SP (2003) Molecular fossil record of elevated methane levels in late pleistocene coastal waters. Science 299:1214–1217
Huseynov DA, Guliyev IS (2004) Mud volcanic natural phenomena in the South Caspian Basin: geology, fluid dynamics and environmental impact. Environ Geol 46:1012–1023
Judd AG, Hovland M, Dimitrov LI, Garcia Gil S, Jukes V (2002) The geological methane budget at continental margins and its influence on climate change. Geofluids 2:109–126
Kennett JP, Cannariato KG, Hendy IL, Behl RJ (2003) Methane hydrates in quaternary climate change. The clathrate gun hypothesis. American Geophysical Union, Washington, DC, p 216
Klemme HD, Ulmishek GF (1991) Effective petroleum source rocks of the world: stratigraphic distribution and controlling depositional factors. AAPG Bull 75:1809–1851
Kroeger KF, di Primio R, Horsfield B (2011) Atmospheric methane from organic carbon mobilization in sedimentary basins—The sleeping giant? Earth-Sci Rev 107:423–442
Lerche I, Yu Z, Torudbakken B, Thomsen RO (1997) Ice loading effects in sedimentary basins with reference to the Barents Sea. Mar Pet Geol 14:277–339
Levine JG, Wolff EW, Jones AE, Sime LC (2011) The role of atomic chlorine in glacial-interglacial changes in the carbon-13 content of atmospheric methane. Geoph Res Lett 38:L04801. doi:10.1029/2010GL046122
Link WK (1952) Significance of oil and gas seeps in world oil exploration. AAPG Bull 36:1505–1540
Luyendyk B, Kennett J, Clark JF (2005) Hypothesis for increased atmospheric methane input from hydrocarbon seeps on exposed continental shelves during glacial low sea level. Mar Pet Geol 22:591–596
Maslin MA, Thomas E (2003) Balancing the deglacial global carbon budget; the hydrate factor. Quatern Sci Rev 22:1729–1736
Mathews MD (1996) Migration—a view from the top. In: Schumacher D, Abrams MA (eds) Hydrocarbon migration and its near-surface expression. AAPG Memoir, vol 66. Penn Well Publishing, Tulsa, pp 139–155
Mellors R, Kilb D, Aliyev A, Gasanov A, Yetirmishli G (2007) Correlations between earthquakes and large mud volcano eruptions. J Geophys Res 112:B04304. doi:10.1029/2006JB004489
Melton JR, Whiticar MJ, Eby P (2011) Stable carbon isotope ratio analyses on trace methane from ice samples. Chem Geol 288:88–96
Milkov AV (2000) Worldwide distribution of submarine mud volcanoes and associated gas hydrates. Mar Geol 167:29–42
Milkov AV (2005) Molecular and stable isotope compositions of natural gas hydrates: a revised global dataset and basic interpretations in the context of geological settings. Org Geochem 36:681–702
Milkov AV, Sassen R (2002) Economic geology of offshore gas hydrate accumulations and provinces. Mar Pet Geol 19:1–11
Milkov AV, Sassen R (2003) Two-dimensional modeling of gas hydrate decomposition in the northwestern Gulf of Mexico: Significance to global change assessment. Global Planet Change 36:31–46
Milkov AV, Claypool GE, Lee Y-J, Dickens GR, Xu W, Borowski WS (2003) The ODP Leg 204 Scientific Party. In situ methane concentrations at Hydrate Ridge offshore Oregon: new constraints on the global gas hydrate inventory from an active margin. Geology 31:833–836
Möller L, Sowers T, Bock M, Spahni R, Behrens M, Schmitt J, Miller H, Fischer H (2013) Independent variations of CH4 emissions and isotopic composition over the past 160,000 years. Nat Geosci 6:885–890
Morner NA (1978) Faulting, fracturing and seismicity as functions of glacioisostasy in Fennoscandia. Geology 6:41–45
Nisbet EG (2002) Have sudden large releases of methane from geological reservoirs occurred since the Last Glacial Maximum, and could such releases occur again? Phil Trans R Soc London 360:581–607
Pentecost A (1995) The Quaternary travertine deposits of Europe and Asia Minor. Quat Sci Rev 14:1005–1028
Petit JR, Jouzel J, Raynaud D, Barkov NI, Barnola JM, Basile I, Bender M, Chappellaz J, Davis M, Delaygue G, Delmotte M, Kotlyakov VM, Legrand M, Lipenkov VY, Lorius C, Pepin L, Ritz C, Saltzman E, Stievenard M (1999) Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica. Nature 399:429–436
Petrenko VV, Smith AM, Brook EJ, Lowe D, Riedel K, Brailsford G, Hua Q, Schaefer H, Reeh N, Weiss RF, Etheridge D, Severinghaus JP (2009) 14CH4 measurements in Greenland Ice: investigating Last Glacial Termination CH4 sources. Science 324:506–508
Quigley DC, Hornafius JS, Luyendyk BP, Francis RD, Clark J, Washburn L (1999) Decrease in natural marine hydrocarbon seepage near Coal Oil Point, California, associated with offshore oil production. Geology 27:1047–1050
Revil A (2002) Genesis of mud volcanoes in sedimentary basins: a solitary wave-based mechanism. Geophys Res Lett 29:15-1–15-4
Saueressig G, Crowley JN, Bergamaschi P, Bruehl C, Brenninkmeijer CA, Fischer H (2001) Carbon 13 and D kinetic isotope effects in the reactions of CH4 with O(1D) and OH: new laboratory measurements and their implications for the isotopic composition of stratospheric methane. J Geophys Res 106:23127–23138
Schaefer H, Whiticar MJ, Brook EJ, Petrenko VV, Ferretti DF, Severinghaus JP (2006) Ice record of δ13C for atmospheric CH4 across the Younger Dryas-Preboreal transition. Science 313:1109–1112
Severinghaus JP, Sowers T, Brook EJ, Alley RB, Bender ML (1998) Timing of abrupt climate change at the end of the Younger Dryas interval from thermally fractionated gases in polar ice. Nature 391:141–146
Sowers T (2006) Late Quaternary atmospheric CH4 isotope record suggests marine clathrates are stable. Science 311:838–840
Spulber L, Etiope G, Baciu C, Malos C, Vlad SN (2010) Methane emission from natural gas seeps and mud volcanoes in Transylvania (Romania). Geofluids 10:463–475
Stewart I, Sauber J, Rose J (2000) Glacio-seismotectonics: ice sheets, crustal deformation and seismicity. Quatern Sci Rev 19:1367–1389
Svensen H, Planke S, Malthe-Sørenssen A, Jamtveit B, Myklebust R, Eidem T, Rey SS (2004) Release of methane from a volcanic basin as a mechanism for initial Eocene global warming. Nature 429:542–545
Thompson AM, Chappellaz JA, Fung IY, Kucsera TL (1993) The atmospheric CH4 increase since the Last Glacial Maximum (2). Interactions with oxidants. Tellus 45B:242–257
Torres ME, Mix AC, Kinports K, Haley B, Klinkhammer GP, McManus J, de Angelis MA (2003) Is methane venting at the seafloor recorded by δ13C of benthic foraminifera shells? Paleoceanography 18, 1062, doi:10.1029/2002PA000824
Valentine DL, Blanton DC, Reeburgh WS, Kastner M (2001) Water column methane oxidation adjacent to an area of active hydrate dissociation, Eel river Basin. Geochim Cosmochim Acta 65:2633–2640
Whiticar MJ, Schaefer H (2007) Constraining past global tropospheric methane budgets with carbon and hydrogen isotope ratios in ice. Philos Trans R Soc London Ser. A 365:1793–1828
Wu P, Johnston P, Lambeck K (1999) Postglacial rebound and fault instability in Fennoscandia. Geophy J Int 139:657–670
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Etiope, G. (2015). Gas Seepage and Past Climate Change. In: Natural Gas Seepage. Springer, Cham. https://doi.org/10.1007/978-3-319-14601-0_8
Download citation
DOI: https://doi.org/10.1007/978-3-319-14601-0_8
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-14600-3
Online ISBN: 978-3-319-14601-0
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)