Abstract
A general geometric representation of sphere-sphere interactions is derived using the bispherical coordinate system. It presents a dimensionless, scaled surface-to-surface separation parameter \( s^{*}\), which is valid for all possible combinations of sphere size and separation distance. The proposed geometric description is not limited to sphere-sphere interactions, but also describes interactions that involve a point particle or a plane. The surface-to-surface separation parameter approaches the limit of \( s^{*} = 1 \) if the radii of both spheres are much smaller than the actual surface-to-surface separation distance s, i.e. in the limit of two point particles. On the other hand, the geometric limit of \( s^{*} = 0\) corresponds to two planes, namely when the radii of both spheres are much larger than s.
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Acknowledgments
EB gratefully acknowledges an ERC Consolidator Grant for financial support. EBL is supported by a PhD scholarship from the Brazilian Government’s Science Without Borders programme (CAPES: 0702/13-7).
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Chan, HK., Lindgren, E.B., Stace, A.J., Bichoutskaia, E. (2015). A General Geometric Representation of Sphere-Sphere Interactions. In: Nascimento, M., Maruani, J., Brändas, E., Delgado-Barrio, G. (eds) Frontiers in Quantum Methods and Applications in Chemistry and Physics. Progress in Theoretical Chemistry and Physics, vol 29. Springer, Cham. https://doi.org/10.1007/978-3-319-14397-2_2
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DOI: https://doi.org/10.1007/978-3-319-14397-2_2
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