Abstract
An attempt was made to prepare carbon-coated tourmaline by mixing tourmaline powders and polyvinyl alcohol (PVA), followed by heat treatment in argon atmosphere. All samples were characterized by powder X-ray diffraction, high-resolution transmission electron microscopy, and UV diffuse reflectance spectroscopy. Results showed that the residual carbon content was influenced by heat treatment temperature and the amount of PVA. The degradation of methylene blue by carbon-coated tourmaline was also studied. The experiments pointed out that the carbon-coated effects were best when the heating temperature was 900 °C and the weight content of PVA was 70 %. And the tourmaline prepared under 900 °C in the oxidation atmosphere has the best degradation efficiency. The results also proved that the infrared radiation of tourmaline had no effect in the degradation progress.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Guo Y, Sang WB, Wang RC (2008) Cluster analysis of Mossbauer spectra of tourmaline crystals. J Funct Mater 39(12):2113–2116
Hawthorne FC, Henry DJ (1999) Classification of the minerals of the tourmaline group. Eur J Mineral 11:201–215
Kubo TJ (1989) Interface activity of water given rise by tourmaline. Solid State Phys 24(12):279–285
Barton RJ, Donnay G (1968) Absolute orientation of tourmaline by arcomalous dispersion of X-rays (abst). Geol Soc Am 101:12–13
Barton RJ (1969) Refinement of the crystal structure of buergerite and absolute orientation of tourmaline. Acta Crystallogr B25:1524–1533
Zhan J, Ge BH, Wang P et al (2009) Study on the microstructure of natural tourmaline and mechanism of its influence on PH value of water. J Funct Mater 40(4):556–559
Li L, Chuan XY (2008) Microstructure, properties and application of tourmaline. China Non-metallic Miner Ind 71:33–37
Dong FQ, He DL, Yuan CL (2005) The environmental functional property and trends of application of tourmaline. J Funct Mater 36(10):1485–1488
Liu LB, Zhang YS, He DL (2012) Kinetic study on photocatalysis degradation of phenol by using tourmaline/TiO2 system as catalyst. J Funct Mater 43(4):512–515
Zhan J, Wang ZY, Wang P et al (2010) The influence of natural mineral tourmaline on water cluster. J Funct Mater 41(1):159–161
Wang Y, Yeh JT, Yue TJ et al (2006) Influence of tourmaline on negative air ion emitting property of poly(ethylene terephthalate). J Macromol Sci, Phys 43:1749–1756
Nashi Y, Yazawa A, Oguri K (1996) pH self-controlling induced by tourmaline. J Intell Mater Syst Struct 7(3):260–263
Mashi Y (2001) Physiology effects when wearing AP fiber cloth containing special tourmaline crystal powder. J Int Soc Life Inf Sci 19(1):73–74
Fox GW, Fink GA (1934) The piezoelectric properties of quartz and tourmaline. Physics 5:302–306
Zhang H, Xu XP (2004) Purification of taltalite by magnetic separation. Min Metall Eng 4:38–40
Ren F, Han YX, Yin WZ (2005) Investigation on schorl purification by wet high-intensity magnetic separation. Metal Mine 5:31–33
Ji ZJ, Liang JS, Jin ZZ et al (2002) Structure change of dravite-schorl after heat treatment. Acta Mineral Sin 22(3):281–284
Liang JS, Meng JP, Zhu DB (2008) Effect of heat treatment of Hesur tourmaline powders. J Chin Ceram Soc 36(2):258–260
Zhang LJ, Guo XH, Yang H et al (2009) Effects of heat treatment on far-infrared emissivity of tourmaline. J Ceram 30(3):286–289
Liao CC, Liao LB, Shen L (2011) Influence of heat treatment on the intrinsic influence of heat treatment on the intrinsic. Acta Mineral Sin 31(1):108–112
Li WW, Zhang XH, Wu RH (2007) Piezoelectricity and magnetic properties of diverse tourmalines. Bull Chin Ceram Soc 26(6):1116–1120
Zhou WW, Chuan XY, Wang SQ (2011) Infrared emission function and its influencing factors of Yingkou serpentine jade. Acta Mineral Sin 31(4):750–756
Cao HL, Zhang L, Lu GY et al (2007) Absorption and degradation of organic dyestuff like methylene blue by tourmaline. Guangdong Chem 1(34):30–34
Xu HY, Wang P, Mao GJ et al (2007) Novel application of tourmaline in environmental field: treatment of argazol blue BF-BR dyeing waste water. Chin J Environ Eng 1(4):65–69
Lu T, Li HY, Zhang HM (2009) Study on degradation of methylene blue by tourmaline/H2O2 system. Non-Metallic Mines 32(2):64–67
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this paper
Cite this paper
Wang, Y., Chuan, X., Li, L., Huang, D. (2015). Preparation of Carbon-Coated Tourmaline and the Degradation of Methylene Blue. In: Dong, F. (eds) Proceedings of the 11th International Congress for Applied Mineralogy (ICAM). Springer Geochemistry/Mineralogy. Springer, Cham. https://doi.org/10.1007/978-3-319-13948-7_38
Download citation
DOI: https://doi.org/10.1007/978-3-319-13948-7_38
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-13947-0
Online ISBN: 978-3-319-13948-7
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)