Abstract
Graphene—a two-dimensional lattice oriented monolayer of sp2-hybridized carbon atoms—has taken up considerable attention leading to a growing scientific interest due to its exceptionally high electrical conductivity (orders of magnitude higher than copper), optical transparency (>90 %), chemical robustness (more than 500 °C) and mechanical stiffness (more than 1,000 GPa) as well as high specific surface area . Design and development of graphene incorporated polymer photovoltaics is one of the promising routes to harness the extraordinary properties of graphene for the generation of efficient solar-to-power conversion devices. Graphene as well as its chemically functionalized forms, graphene oxide (GO) and reduced-GO, are the smart materials for photovoltaic cells performing specific functions depending upon their intriguing properties. Herein we review the multifunctional and practical applicability of graphene and its composite materials as the electron acceptor, counter electrode and hole transport components of polymer solar cells . We conclude the chapter with the present scenario and challenges related to the stability and commercialization of graphene–polymer based photovoltaic devices .
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References
Zhu Y, Murali S, Cai W, Xuesong Li, Suk J W, Potts J R, Ruoff R S (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22:3906–3924
Geim A K, Novoselov K S (2007) The rise of graphene. Nat Mater 6:183–191
Compton O C, Nguyen S B T (2010) Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials. Small 6:711–723
Stankovich S, Dikin D A, Dommett G H B (2006) Graphene-based composite materials. Nat 442:282–286
Soldano C, Mahmood A, Dujardin E (2010) Production, properties and potential of graphene. Carbon 48:2127–2150
Katsnelson M I (2007) Graphene: carbon in two dimensions. Mater Today 10:20–27
Geim A K (2009) Graphene: status and prospects. Science 324:1530–1534
Novoselov K S, Jiang Z, Zhang Y, Morozov S V, Stormer H L, Zeitler U, Maan J C, Boebinger G S, Kim P, Geim A K (2007) Room-temperature quantum hall effect in graphene. Science 315:1379–1379
Stoller M D, Park S, Zhu Y, An J, Ruoff R S (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502
Loh K P, Bao, Q L, Eda G, Chhowalla M (2010) Graphene oxide as a chemically tunable platform for optical applications. Nat Chem 2:1015–1024
Eda G, Fanchini G, Chhowalla M (2008) Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat Nanotechnol 3:270–274
Yu D S, Dai L (2010) Self-assembled graphene/carbon nanotube hybrid films for supercapacitors. J Phys Chem Lett 1:467–470
Wang X, Zhi L J, Mullen K (2008) Graphene electrodes for dye-sensitized solar cells. Nano Lett 8:323–327
Eda G, Chhowalla M (2009) Graphene-based composite thin films for electronics. Nano Lett 9:814–818
Yu D S, Dai L (2010) Voltage-induced incandescent light emission from large-area graphene films. Appl Phys Lett 96:143107(1–3)
Yu D S, Yang Y, Durstock M, Baek J-B, Dai L (2010) Soluble P3HT-grafted graphene for efficient bilayer-heterojunction photovoltaic devices. ACS Nano 4:5633–5640
Gilje S, Song H, Wang M, Wang K L, Kaner R B (2007) A chemical route to graphene for device applications. Nano Lett 7:3394–3398
Liu Y, Yu D, Zeng C, Miao Z, Dai L (2010) Biocompatible graphene oxide-based glucose biosensors. Langmuir 29:6158–6160
Qu L, Liu Y, Baek J, Dai L (2010) Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. ACS Nano 4:1321–1326
Dreyer D R, Park S, Bielawski C W, Ruoff R S (2009) The chemistry of graphene oxide. Chem Soc Rev 39:228–240
Lightcap V, Kamat P V (2012) Fortification of CdSe quantum dots with graphene oxide. excited state interactions and light energy conversion. J Am Chem Soc 134:7109–7116
O’Regan B, Grätzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nat 353:737–740
Imahori H, Umeyama T, Ito S (2009) Large π-aromatic molecules as potential sensitizers for highly efficient dye-sensitized solar cells. Acc Chem Res 42:1809–1818
Ye L, Zhang S, Huo L, Zhang M, HouJ (2014) Molecular design toward highly efficient photovoltaic polymers based on two-dimensional conjugated benzodithiophene. Acc Chem Res 47:1595–1603
Park S H, Roy A, Beaupre S, Cho S, Coates N, Moon J S, Moses D, Leclerc M, Lee K, Heeger A J (2009) Bulk heterojunction solar cells with internal quantum efficiency approaching 100%. Nat Photonics 3:297–302
Li G, Shrotriya V, Huang J, Yao Y, Moriarty T, Emery K, Yang Y (2005) High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends. Nat Mater 4:864–868
Ma W, Yang C, Gong X, Lee K, Heeger A J (2005) Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology. Adv Funct Mater 15:1617–1622
Peet J, Kim J Y, Coates N E, Ma W L, Moses D, Heeger A J, Bazan G C (2007) Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols. Nat Mater 6:497–500
Chen H-Y, Hou J, Zhang S (2009) Polymer solar cells with enhanced open-circuit voltage and efficiency. Nat Photonics 3:649–653
Li G, Zhu R, Yang Y (2012) Polymer solar cells. Nat Photonics 6:153–161
He Z, Zhong C, Huang X, Wong W-Y, Wu H, Chen L, Su S, Cao Y (2011) Simultaneous enhancement of open-circuit voltage, short-circuit current density, and fill factor in polymer solar cells. Adv Mater 23:4636–4643
Small C E, Chen S, Subbiah J, Amb C M, Tsang S-W, Lai T-H, Reynolds J R, So F (2012) High-efficiency inverted dithienogermolethienopyrrolodione-based polymer solar cells. Nat Photonics 6:115–120
Chen H-Y, Hou J, Zhang S, Liang Y, Yang G, Yang Y, Yu L, Wu Y, Li G (2009) Polymer solar cells with enhanced open-circuit voltage and efficiency. Nat Photonics 3:649–653
Liang Y, Xu Z, Xia J, Tsai S-T, Wu Y, Li G, Ray C, Yu L (2010) For the bright future–bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%. Adv Mater 22:E135–E138.
You J, Dou L, Yoshimura K, Kato T, Ohya K, Moriarty T, Emery K, Chen C-C, Gao J, Li G, Yang Y (2013) A polymer tandem solar cell with 10.6% power conversion efficiency. Nat Commun 4:1446(1–10)
Clarke T M, Durrant J R, (2010) Charge photogeneration in organic solar cells. Chem Rev 110:6736–6767
Pan Z, Gu H, Wu M-T, Li Y, Chen Y (2012) Graphene-based functional materials for organic solar cells. Opt Mater Express 2:814–824
Ren L, Qiu J, Wang S (2013) Photovoltaic properties of graphene nanodisk-integrated polymer composites. Compos: Part B 55:548–557
Acik M, Chabal Y J (2011) Nature of graphene edges: a review. Jpn J Appl Phys 50:070101(1–16)
Li Y, Hu Y, Zhao Y, Shi G, Deng L, Hou Y, Qu L (2011) An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv Mater 23:776–780
Yan X, Cui X, Li B, Li L S (2010) Large, solution-processible graphene quantum dots as light absorbers for photovoltaics. Nano Lett 10:1869–1873
Gupta V, Chaudhary N, Srivastava R, Sharma G D, Bhardwaj R, Chand S (2011) Luminscent graphene quantum dots for organic photovoltaic devices. J Am Chem Soc 133:9960–9963
Yong V, Tour J M (2010) Theoretical efficiency of nanostructured graphene-based photovoltaics. Small 6:313–318
Hill I G, Kahn A, Soos Z G, Pascal R A J (2000) Charge-separation energy in films of π-conjugated organic molecules. Chem Phys Lett 327:181–188
Alvarado S F, Seidler P F, Lidzey D G, Bradley D D C (1998) Direct determination of the exciton binding energy of conjugated polymers using a scanning tunneling microscope. Phys Rev Lett 81:1082–1085
Kersting R, Lemmer U, Deussen M, Bakker H J, Mahrt R F, Kurz H, Arkhipov V I, Bässler H, Göbel E O (1994) Ultrafast field-induced dissociation of excitons in conjugated polymers. Phys Rev Lett 73:1440–1443
Xue J, Rand B P, Uchida S, Forrest S R (2005) A hybrid planar–mixed molecular heterojunction photovoltaic cell. Adv Mater 17:66–71
Scully S R, McGehee M D (2006) Effects of optical interference and energy transfer on exciton diffusion length measurements in organic semiconductors. J Appl Phys 100:034907(1–5)
Markov D E, Hummelen J C, Blom P W M, Sieval A B (2005) Dynamics of exciton diffusion in poly(p-phenylene vinylene)/fullerene heterostructures. Phys Rev B 72:045216(1–5)
Peumans P, Yakimov A, Forrestb S R (2003) Small molecular weight organic thin-film photodetectors and solar cells. J Appl Phys 93:3693–3723
Hoppe H, Sariciftci N S (2004) Organic solar cells: an overview. J Mater Res 19:1924–1945
Dennler G, Scharber M C, Brabec C J (2009) Polymer-fullerene bulk-heterojunction solar cells. Adv Mater 21:1323–1338
Kniepert J, Lange I, Kaap N J v d, Koster L J A, Dieter Neher (2014) A conclusive view on charge generation, recombination, and extraction in as-prepared and annealed P3HT:PCBM blends: combined experimental and simulation work. Adv Energy Mater 4:1301401(1–10)
Wang T, Pearson A J, Lidzey D G, Jones R A L (2013) Evolution of structure, optoelectronic properties, and device performance of polythiophene:fullerene solar cells during thermal annealing. Adv Funct Mater 21:1383–1390
Oklobia O, Shafai T S (2013) A study of donor/acceptor interfaces in a blend of P3HT/PCBM solar cell: effects of annealing and PCBM loading on optical and electrical properties. Solid-State Electron 87:64–68
Kasry A, Ashry M E, Nistor R A, Bola A A, Tulevskia G S, Martynaa G J, Newns D M (2012) High performance metal microstructure for carbon-based transparent conducting electrodes. Thin Solid Films 520:4827–4830
Søndergaard R, Hösel M, Angmo D, Larsen-Olsen T T, Krebs F C (2012) Roll-to-roll fabrication of polymer solar cells. Mater Today 15:36–49
Carle J E, Helgesen M, Madsen M V, Bundgaarda E, Krebs F C (2014) Upscaling from single cells to modules – fabrication of vacuum- and ITO-free polymer solar cells on flexible substrates with long lifetime. J Mater Chem C 2:1290–1297
Lee S, Yeo J-S, Ji Y, Cho C, Kim D-Y, Na S-I, Lee B H, LeeT (2012) Flexible organic solar cells composed of P3HT:PCBM using chemically doped graphene electrodes. Nanotechnol 23:344013
Na S-I, Kim S-S, Jo J, Kim D-Y (2008) Efficient and flexible ITO-free organic solar cells using highly conductive polymer anodes. Adv Mater 20:4061–4067
Ohzeki M, Fujii S, Arai Y, Yanagidate T, Yanagi Y, Okukawa T, Yoshida A, Kataura H, Nishioka Y (2014) Performance improvement of flexible bulk heterojunction solar cells using PTB7:PC71BM by optimizing spin coating and drying processes. J Appl Phys, Part 1 53:02BE04(1–5)
Bässler H (1994) Non-dispersive and dispersive transport in random organic photoconductors. Mol Cryst Liq Cryst Sci A 252:11–21;
Huynh W U, Dittmer J J, Paul A (2002) Hybrid nanorod-polymer solar cells. Science 295:2425–2427
Yin Z, Zhu J, He Q, Cao X, Tan C, Chen H, Yan Q, Zhang H (2014) Graphene-based materials for solar cell applications. Adv Energy Mater 4:1300574(1–19)
Liu Z, He D, Wang Y, Wu H, Wang J (2010) Graphene doping of P3HT:PCBM photovoltaic devices. Synth Met 160:1036–1039
Chen D, Zhang H, Liu Y, Li J (2013) Graphene and its derivatives for the development of solar cells, photoelectrochemical, and photocatalytic applications. Energy Environ Sci 6:1362–1387
Liu Q, Liu Z, Zhang X, Zhang N, Yang L, Yin S, Chen Y (2008) Organic photovoltaic cells based on an acceptor of soluble graphene. Appl Phys Lett 92:223303(1–3)
Liu Z, He D W, Wang Y, Wu H, Wang J (2010) Solution-processible functionalized graphene in donor/acceptor-type organic photovoltaic cells. Sol Energy Mater Sol Cells 94:1196–1200
Yu D, Park K, Durstock M, Dai L (2011) Fullerene-grafted graphene for efficient bulk heterojunction polymer photovoltaic devices. J Phys Chem Lett 2:1113–1118
Chauhan A K, Gusain A, Jha P, Koiry S P, Saxena V, Veerender P, Aswal D K, Gupta S K (2014) Graphene composite for improvement in the conversion efficiency of flexible poly 3-hexyl-thiophene:[6,6]-phenyl C71 butyric acid methyl ester polymer solar cells. Appl Phys Lett 104:133901(1–5)
Hill C M, Zhu Y, Pan S (2011) Fluorescence and electroluminescence quenching evidence of interfacial charge transfer in poly (3-hexylthiophene): graphene oxide bulk heterojunction photovoltaic devices. ACS Nano 5:942–951
Liu Q, Liu Z, Zhang X, Yang L, Zhang N, Pan G, Yin S, Chen Y, Wei J (2009) Polymer photovoltaic cells based on solution-processible graphene and P3HT. Adv Funct Mater 19:894–904
Jr W S H, Offeman R E (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1339
Becerril H A, Mao J, Liu Z, Stoltenberg R M, Bao Z, ChenY (2008) Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2:463–470
Stankovich S, Piner R D, Nguyen S B T, Ruoff R S (2006) Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44:3342–3347
Zhang B, Liu G, Chen Y, Zeng L-J, Zhu C-X, Neoh K-G, Wang C, Kang E-T (2011) Conjugated polymer-grafted reduced graphene oxide for nonvolatile rewritable memory. Chem Eur J 17:13646–13652
Li P-P, Chen Y, Zhu J, Feng M, Zhuang X, Lin Y, Zhan H (2011) Charm-bracelet-type poly(N-vinylcarbazole) functionalized with reduced graphene oxide for broadband optical limiting. Chem Eur J 17:780–785
Zhang B, Chen Y, Liu G, Xu L-Q, Chen J, Zhu C-X, Neoh K-G, Kang E-T (2012) “Push-pull archetype of reduced graphene oxide functionalized with polyfluorene for nonvolatile rewritable memory. J Polym Sci, Part A: Polym Chem 2:378–387
Li Y, Pan Z, Fu Y, Chen Y, Xie Z, Zhang B (2012) Soluble reduced graphene oxide functionalized with conjugated polymer for heterojunction solar cells. J Polym Sci, Part A: Polym Chem 50(9):1663–1671
Jayawardena K D G I, Rhodes R, Gandhi K K, Prabhath M R R, Dabera G D M R, Beliatis m J, Rozanski L J, Henley S J, Silva S R P (2013) Solution processed reduced graphene oxide/metal oxide hybrid electron transport layers for highly efficient polymer solar cells. J Mater Chem A 1: 9922–9927
Wu J, Becerril H A, Bao Z, Liu Z, Chen Y, Peumans P (2008) Organic solar cells with solution-processed graphene transparent electrodes. Appl Phys Lett 92:263302(1–3)
Yin Z, Sun S, Salim T, Wu S, Huang X, He Q, Lam Y M, Zhang H (2010) Organic photovoltaic devices using highly flexible reduced graphene oxide films as transparent electrodes. ACS Nano 4:5263–5268
Bae S, Kim H, Lee Y, Xu X, Park J-S, Zheng Y, Balakrishnan J, Lei T, Kim H R, Song Y I, Kim Y-J, Kim K S, Özyilmaz B, Ahn J-H, Hong B H, Iijima S (2010) Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat Nanotechnol 5:574–578
Arco L G D, Zhang Y, Schlenker C W, Ryu K, Thompson M E, Zhou C (2010) Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. ACS Nano 4:2865–2873
Bonaccorso F, Sun Z, Hasan T, Ferrari A C (2010) Graphene photonics and optoelectronics. Nat Photonics 4: 611–622
Choi Y Y, Kang S J, Kim H- K, Choi W M, Na S-I (2012) Multilayer graphene films as transparent electrodes for organic photovoltaic devices. Sol Energy Mater Sol Cells 96:281–285
Choe M, Lee B H, Jo G, Park J, Park W, Lee S, Hong W-K, Seong M-J, Kahng Y H, Lee K, LeeT (2010) Efficient bulk-heterojunction photovoltaic cells with transparent multi-layer graphene electrodes. Org Electron 11:1864–1869
Park H S, Rowehl J A, Kim K K, Bulovic V, Kong J (2010) Doped graphene electrodes for organic solar cells. Nanotechnol 21:505204
Wang Y, Tong S W, Xu X F, Özyilmaz B, Loh K P (2011) Interface engineering of layer-by-layer stacked graphene anodes for high-performance organic solar cells. Adv Mater 23:1514–1518
Lee Y- Y, Tu K- H, Yu C- C, Li S-S, Hwang J-Y, Lin C-C, Chen K-H, Chen L-C, Chen H-L, Chen C-W (2011) Top laminated graphene electrode in a semitransparent polymer solar cell by simultaneous thermal annealing/releasing method. ACS Nano 5:6564–6570
Hsu C- L, Lin C- T, Huang J- H, Chu C-W, Wei K-H, Li L-J (2012) Layer-by-layer graphene/TCNQ stacked films as conducting anodes for organic solar cells. ACS Nano 6:5031–5039
Tung V C, Chen L M, Allen M J, Wassei J K, Nelson K, Kaner R B, Yang Y (2009) Low-temperature solution processing of graphene–carbon nanotube hybrid materials for high-performance transparent conductors. Nano Lett 9:1949–1955
Ni G- X, Zheng Y, Bae S, Tan C Y, Kahya O, Wu J, Hong B H, Yao K, Özyilmaz B (2012) Graphene–ferroelectric hybrid structure for flexible transparent electrodes. ACS Nano 6:3935–3942
Emmanuel K, Kyriaki S, Minas M S, Fotakis C, Stratakis E (2013) Flexible organic photovoltaic cells with in situ nonthermal photoreduction of spin-coated graphene oxide electrodes. Adv Funct Mater 23:2742–2749
M. Jørgensen, K. Norrman, F. C. Krebs, Stability/degradation of polymer solar cells. Sol Energy Mater Sol Cells 92:686–714
Kim Y- H, Lee S- H, Noh J, han S-H (2006) Performance and stability of electroluminescent device with self-assembled layers of poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) and polyelectrolytes. Thin Solid Films 510:305–310
Lagemaat J, Barnes T M, Rumbles G, Shaheen S E, Coutts T J, Weeks C, Levitsky I, Peltola J, Glatkowski P (2006) Organic solar cells with carbon nanotubes replacing In2O3:Sn as the transparent electrode. Appl Phys Lett 8:233503 (1–3)
Matyba P, Yamaguchi H, Chhowalla M, Robinson N D, Edman L (2010) Flexible and metal-free light-emitting electrochemical cells based on graphene and PEDOT:PSS as the electrode materials. ACS Nano 5:574–580
Dreyer D R, Park S, Bielawski C W, Ruoff R S (2010) The chemistry of graphene oxide. Chem Soc Rev 39:228–240
Loh K P, Bao Q, Eda G, Chhowalla M (2010) Graphene oxide as a chemically tunable platform for optical applications. Nat Chem 2:1015–1024
Li S-S, Tu K-H, Lin C-C, Chen C-W, Chhowalla M (2010) Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cells. ACS Nano 4:3169–3174
Kim J, Tung V C, Huang J X (2011) Water processable graphene oxide:single walled carbon nanotube composite as anode modifier for polymer solar cells. Adv Energy Mater 1:1052–1057
Yun J M, Yeo J S, Kim J, Jeong H-G, Kim D-Y, Noh Y-J, Kim S-S, Ku B-C, Na S-I (2011) Solution-processable reduced graphene oxide as a novel alternative to PEDOT:PSS hole transport layers for highly efficient and stable polymer solar cells. Adv Mater 23:4923–4928
Murray I P, Lou S J, Cote L J, Loser S, Kadleck C J, Xu T, Szarko J M, Rolczynski B S, Johns J E, Huang J, Yu L, Chen L X, Marks T J, HersamM C (2011) Graphene Oxide Interlayers for Robust, High-Efficiency Organic Photovoltaics. J Phys Chem Lett 2:3006–3012
Park H, Chang S, Jean J, Cheng J J, Araujo P T, Wang M, Bawendi M G, Dresselhaus M S, Bulović V, Kong J, Gradečak S (2013) Graphene cathode-based ZnO nanowire hybrid solar cells. Nano Lett 13: 233–239
Tong S W, Mishra N, Su C L, Nalla V, Wu W, Ji W, Zhang J, Chan Y, Loh K P (2014) High-performance hybrid solar cell made from CdSe/CdTe nanocrystals supported on reduced graphene oxide and PCDTBT. Adv Funct Mater 24:1904–1910
Liu J, Xue Y, Gao Y, Yu D, Durstock M, Dai L (2012) Hole and electron extraction layers based on graphene oxide derivatives for high-performance bulk heterojunction solar cells. Adv Mater 24:2228–2233
Iwan A, Chuchmała A (2012) Perspectives of applied graphene: Polymer solar cells. Prog Polym Sci 37:1805–1828
Wan X, Huang Y, Chen Y (2012) Focusing on energy and optoelectronic applications: a journey for graphene and graphene oxide at large scale, Acc Chem Res 45(4):598-607
Barpuzary D, Qureshi M (2013) Enhanced photovoltaic performance of semiconductor-sensitized ZnO-CdS coupled with graphene oxide as a novel photoactive material. ACS Appl Mater Interfaces 5:11673–11682
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Barpuzary, D., Qureshi, M. (2015). Graphene Filled Polymers in Photovoltaic. In: Sadasivuni, K., Ponnamma, D., Kim, J., Thomas, S. (eds) Graphene-Based Polymer Nanocomposites in Electronics. Springer Series on Polymer and Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-13875-6_7
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