Skip to main content

The Design of a Single-Molecule Motor

  • Conference paper
  • First Online:
Single Molecular Machines and Motors

Abstract

Several methods have been developed in the last decades to manipulate molecules on surfaces using the tip of a scanning tunneling microscope. Some of those molecules have been designed with the aim of achieving controllable unidirectional motion and, eventually, to generate a motive power and perform work. Single-molecule motors have been mainly inspired by their macroscopic analogous, and their capacity to act as real motors is fairly limited to date. Here, we present some advances in the understanding of molecule motors based on their chemical composition and on their intramolecular electronic characteristics. Thinking of a single-molecule motor as a molecule with specific electronic states and thousands of mechanical degrees of freedom will open the path for the design of new improved and more efficient prototypes.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Tierney, H.L., Murphy, C.J., Jewell, A.D., Baber, A.E., Iski, E.V., Khodaverdian, H.Y., McGuire, A.F., Klebanov, N., Sykes, E.C.H.: Experimental demonstration of a single-molecule electric motor. Nat. Nanotechnol. 6, 625–629 (2011)

    Google Scholar 

  2. Vives, G., de Rouville, H.-P.J., Carella, A., Launay, J.-P., Rapenne, G.: Prototypes of molecular motors based on star-shaped organometallic ruthenium complexes. Chem. Soc. Rev. 38, 1551–1561 (2009)

    Google Scholar 

  3. Vives, G., Rapenne, G.: Directed synthesis of symmetric and dissymmetric molecular motors built around a ruthenium cyclopentadienyl tris(indazolyl)borate complex. Tetrahedron 64, 11462–11468 (2008)

    Google Scholar 

  4. Ample, F., Joachim, C.: A semi-empirical study of polyacene molecules adsorbed on a Cu(110) surface. Surf. Sci. 600, 3243–3251 (2006)

    Google Scholar 

  5. Echeverría, J., Carreras, A., Casanova, D., Alemany, P., Alvarez, S.: Concurrent symmetries: the interplay between local and global molecular symmetries. Chem. Eur. J. 17, 359–367 (2011)

    Google Scholar 

  6. Sheppard, D., Terrell, R., Henkelman, G.: Optimization methods for finding minimum energy paths. J. Chem. Phys. 128, 134106–134110 (2008)

    Google Scholar 

  7. Perera, U.G.E., Ample, F., Kersell, H., Zhang, Y., Vives, G., Echeverria, J., Grisolia, M., Rapenne, G., Joachim, C., Hla, S.-W.: Controlled clockwise and anticlockwise rotational switching of a molecular motor. Nat. Nanotechnol. 8, 46–51 (2013)

    Google Scholar 

  8. Joachim, C.: The driving power of the quantum superposition principle for molecule-machines. J. Phys. Condens. Matter 18, S1935–S1942 (2006)

    Google Scholar 

  9. Persson, B.N.J., Nitzan, A.: Linear sliding friction: on the origin of the microscopic friction for Xe on silver. Surf. Sci. 367, 261–275 (1996)

    Google Scholar 

  10. Lensen, D., Elemans, J.A.A.W.: Artificial molecular rotors and motors on surfaces: STM reveals and triggers. Soft Matter 8, 9053–9063 (2012)

    Google Scholar 

  11. Astumian, R.: Thermodynamics and kinetics of a Brownian motor. Science 276, 917–922 (1997)

    Google Scholar 

  12. Joachim, C., Ratner, M.A.: Molecular electronics: some views on transport junctions and beyond. Proc. Natl. Acad. Sci. U.S.A. 102, 8801–8808 (2005)

    Google Scholar 

  13. Sanchez-Palencia, L.: Directed transport of Brownian particles in a double symmetric potential. Phys. Rev. E 70, 011102 (2004)

    Google Scholar 

  14. García-Iriepa, C., Marazzi, M., Zapata, F., Valentini, A., Sampedro, D., Frutos, L.M.: Chiral hydrogen bond environment providing unidirectional rotation in photoactive molecular motors. J. Phys. Chem. Lett. 4, 1389–1396 (2013)

    Google Scholar 

  15. Marden, J.H., Allen, L.R.: Molecules, muscles, and machines: universal performance characteristics of motors. Proc. Natl. Acad. Sci. U.S.A. 99, 4161–4166 (2002)

    Google Scholar 

  16. Nie, L.-R., Mei, D.-C.: Effect of correlated noises on Brownian motor. Phys. Lett. A 373, 3816–3821 (2009)

    Google Scholar 

  17. Ai, B., Xie, H., Liao, H., Liu, L.: Efficiency in a temporally asymmetric Brownian motor with stochastic potentials. J. Stat. Mech. Theory Exp. 2006, P09016–P09016 (2006)

    Google Scholar 

  18. Parrondo, J.M.R., de Cisneros, B.J.: Energetics of Brownian motors: a review. Appl. Phys. Mater. Sci. Process. 75, 179–191 (2002)

    Google Scholar 

Download references

Acknowledgments

J.E. thanks the Generalitat de Catalunya and the European Union for a Beatriu de Pinós scholarship.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Christian Joachim .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this paper

Cite this paper

Echeverria, J., Joachim, C. (2015). The Design of a Single-Molecule Motor. In: Joachim, C., Rapenne, G. (eds) Single Molecular Machines and Motors. Advances in Atom and Single Molecule Machines. Springer, Cham. https://doi.org/10.1007/978-3-319-13872-5_5

Download citation

Publish with us

Policies and ethics