Abstract
The grafting of polymeric chains to inorganic (as well as organic) particle interfaces has become an indispensable tool to engineer the physicochemical and/or biochemical properties of material interfaces. For example, polymer grafting is ubiquitously being used to compatibilize particles to polymer matrices to augment the properties of polymers in applications such as biomedical devices, lightweight aircraft wings, energy generation and storage, and for separation and environmental remediation to name a few. The recent emergence of surface-initiated controlled radical polymerization has further expanded the scope of polymer-grafted particulate materials as the precise control of the structure of the polymer grafts, offers new opportunities to tailor the properties of polymer-grafted particle systems. This chapter summarizes recent developments in synthesis of polymer-tethered nanoparticle interfaces that have afforded this fine control in the structure and properties of the resultant composite. Particular emphasis is given to the concept of “one-component hybrid materials”—that is the ability to synthesize multifunctional nanocomposite materials by the self-assembly of polymer-tethered particle systems. The role of polymer-graft modification on the interaction, dynamics, and assembly of particle brush materials is discussed to provide the context to showcase studies that have demonstrated the opportunity to harness the precision-engineered polymer-grafted particle systems for the fabrication of innovative nanocomposite material technologies.
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References
Abreu CMR, Mendonca PV, Serra AC, Popov AV, Matyjaszewski K, Guliashvili T, Coelho JFJ (2012) Inorganic sulfites: efficient reducing agents and supplemental activators for atom transfer radical polymerization. ACS Macro Lett 1(11):1308–1311. doi:10.1021/mz300458x
Advincula R (2006) Polymer brushes by anionic and cationic surface-initated polymerization (SIP). In: Jordan R (ed) Advances in polymer science: surface initiated polymerization, vol 197. Springer, Berlin, pp 107–136
Agarwal P, Chopra M, Archer LA (2011) Nanoparticle netpoints for shape- memory polymers. Angew Chem-Int Ed 50(37):8670–8673. doi:10.1002/anie.201103908
Alexander S (1977) Adsorption of chain molecules with polar head: a scaling approach. J De Phys 38(8):983–987. doi:10.1051/jphys:01977003808098300
Ball RC, Marko JF, Milner ST, Witten TA (1991) Polymers grafted to a convex surface. Macromolecules 24(3):693–703. doi:10.1021/ma00003a011
Barbey R, Lavanant L, Paripovic D, Schuwer N, Sugnaux C, Tugulu S, Klok HA (2009) Polymer brushes via surface-initiated controlled radical polymerization: synthesis, characterization, properties, and applications. Chem Rev 109(11):5437–5527. doi:10.1021/cr900045a
Binder K, Milchev A (2012) Polymer brushes on flat and curved surfaces: how computer simulations can help to test theories and to interpret experiments. J Polym Sci Part B-Polym Phys 50(22):1515–1555. doi:10.1002/polb.23168
Bombalski L, Dong HC, Listak J, Matyjaszewski K, Bockstaller MR (2007) Null-scattering hybrid particles using controlled radical polymerization. Adv Mater 19(24):4486–4490. doi:10.1002/adma.200700928
Bourlinos AB, Herrera R, Chalkias N, Jiang DD, Zhang Q, Archer LA, Giannelis EP (2005) Surface-functionalized nanoparticles with liquid-like behavior. Adv Mater 17(2):234–237. doi:10.1002/adma.2004001060
Bourlinos AB, Giannelis EP, Zhang Q, Archer LA, Floudas G, Fytas G (2006) Surface-functionalized nanoparticles with liquid-like behavior: the role of the constituent components. Eur Phys J E 20(1):109–117. doi:10.1140/epje/i2006-10007-3
Braunecker WA, Matyjaszewski K (2007) Controlled/living radical polymerization: features, developments, and perspectives. Prog Polym Sci 32(1):93–146. doi:10.1016/j.progpolymsci.2006.11.002
Carrot G, Diamanti S, Manuszak M, Charleux B, Vairon IP (2001) Atom transfer radical polymerization of n-butyl acrylate from silica nanoparticles. J Polym Sci Part A-Polym Chem 39(24):4294–4301. doi:10.1002/pola.10085
Choi J, Dong H, Matyjaszewski K, Bockstaller MR (2010) Flexible particle array structures by controlling polymer graft architecture. J Am Chem Soc 132(36):12537–12539. doi:10.1021/ja105189s
Choi J, Hui CM, Pietrasik J, Dong HC, Matyjaszewski K, Bockstaller MR (2012) Toughening fragile matter: mechanical properties of particle solids assembled from polymer-grafted hybrid particles synthesized by ATRP. Soft Matter 8(15):4072–4082. doi:10.1039/c2sm06915f
Choi J, Hui CM, Schmitt M, Pietrasik J, Margel S, Matyjazsewski K, Bockstaller MR (2013) Effect of polymer-graft modification on the order formation in particle assembly structures. Langmuir 29(21):6452–6459. doi:10.1021/la4004406
Dan N, Tirrell M (1992) Polymers tethered to curved interfaces-a self-consistent-field analysis. Macromolecules 25(11):2890–2895. doi:10.1021/ma00037a016
Daoud M, Cotton JP (1982) Star shaped polymers—a model for the conformation and its concentration dependence. J De Phys 43(3):531–538. doi:10.1051/jphys:01982004303053100
de Gennes PG (1980) Conformations of polymers attached to an interface. Macromolecules 13(5):1069–1075. doi:10.1021/ma60077a009
Dong HC, Zhu MZ, Yoon JA, Gao HF, Jin RC, Matyjaszewski K (2008) One-pot synthesis of robust core/shell gold nanoparticles. J Am Chem Soc 130(39):12852–12853. doi:10.1021/ja8038097
Dukes D, Li Y, Lewis S, Benicewicz B, Schadler L, Kumar SK (2010) Conformational transitions of spherical polymer brushes: synthesis, characterization, and theory. Macromolecules 43(3):1564–1570. doi:10.1021/ma901228t
Edmondson S, Osborne VL, Huck WTS (2004) Polymer brushes via surface-initiated polymerizations. Chem Soc Rev 33(1):14–22. doi:10.1039/b210143m
Fernandes NJ, Koerner H, Giannelis EP, Vaia RA (2013) Hairy nanoparticle assemblies as one-component functional polymer nanocomposites: opportunities and challenges. MRS Commun 3(1):13–29. doi:10.1557/mrc.2013.9
Gao X, Feng W, Zhu SP, Sheardown H, Brash JL (2010) Kinetic modeling of surface-initiated atom transfer radical polymerization. Macromol React Eng 4(3–4):235–250. doi:10.1002/mren.200900063
Glotzer SC, Solomon MJ (2007) Anisotropy of building blocks and their assembly into complex structures. Nat Mater 6(8):557–562. doi:10.1038/nmat1949
Goel V, Pietrasik J, Dong H, Sharma J, Matyjaszewski K, Krishnamoorti R (2011) Structure of polymer tethered highly grafted nanoparticles. Macromolecules 44(20):8129–8135. doi:10.1021/ma200621r
Hamer MJ, Iyer BVS, Yashin VV, Kowalewski T, Matyjaszewski K, Balazs AC (2014) Modeling polymer grafted nanoparticle networks reinforced by high-strength chains. Soft Matter 10(9):1374–1383. doi:10.1039/c3sm52300d
Hui CM, Pietrasik J, Schmitt M, Mahoney C, Choi J, Bockstaller MR, Matyjaszewski K (2014) Surface-Initiated polymerization as an enabling tool for multifunctional (nano-)engineered hybrid materials. Chem Mater 26(1):745–762. doi:10.1021/cm4023634
Ignatova M, Voccia S, Gilbert B, Markova N, Cossement D, Gouttebaron R, Jerome R, Jerome C (2006) Combination of electrografting and atom-transfer radical polymerization for making the stainless steel surface antibacterial and protein antiadhesive. Langmuir 22(1):255–262. doi:10.1021/la051954b
Iyer BVS, Salib IG, Yashin VV, Kowalewski T, Matyjaszewski K, Balazs AC (2013a) Modeling the response of dual cross-linked nanoparticle networks to mechanical deformation. Soft Matter 9(1):109–121. doi:10.1039/c2sm27121d
Iyer BVS, Yashin VV, Kowalewski T, Matyjaszewski K, Balazs AC (2013b) Strain recovery and self-healing in dual cross-linked nanoparticle networks. Polym Chem 4(18):4927–4939. doi:10.1039/c3py00075c
Jakubowski W, Matyjaszewski K (2006) Activators regenerated by electron transfer for atom-transfer radical polymerization of (meth)acrylates and related block copolymers. Angew Chem-Int Ed 45(27):4482–4486. doi:10.1002/anie.200600272
Jayaraman A (2013) Polymer grafted nanoparticles: effect of chemical and physical heterogeneity in polymer grafts on particle assembly and dispersion. J Polym Sci Part B-Polym Phys 51(7):524–534. doi:10.1002/polb.23260
Jayaraman A, Schweizer KS (2008a) Effect of the number and placement of polymer tethers on the structure of concentrated solutions and melts of hybrid nanoparticles. Langmuir 24(19):11119–11130. doi:10.1021/la801432b
Jayaraman A, Schweizer KS (2008b) Structure and assembly of dense solutions and melts of single tethered nanoparticles. J Chem Phys 128(16):164904. doi:10.1063/1.2907717
Jayaraman A, Schweizer KS (2009) Effective interactions and self-assembly of hybrid polymer grafted nanoparticles in a homopolymer matrix. Macromolecules 42(21):8423–8434. doi:10.1021/ma901631x
Kim D, Srivastava S, Narayanan S, Archer LA (2012) Polymer nanocomposites: polymer and particle dynamics. Soft Matter 8(42):10813–10818. doi:10.1039/c2sm26325d
Kim JU, Matsen MW (2008) Interaction between polymer-grafted particles. Macromolecules 41(12):4435–4443. doi:10.1021/ma8002856
Koerner H, Drummy LF, Benicewicz B, Li Y, Vaia RA (2013) Nonisotropic self-organization of single-component hairy nanoparticle assemblies. ACS Macro Lett 2(8):670–676. doi:10.1021/mz4001805
Li F, Josephson DP, Stein A (2011) Colloidal assembly: The road from particles to colloidal molecules and crystals. Angew Chem-Int Ed 50(2):360–388. doi:10.1002/anie.201001451
Li Y, Tao P, Viswanath A, Benicewicz BC, Schadler LS (2013) Bimodal surface ligand engineering: the key to tunable nanocomposites. Langmuir 29(4):1211–1220. doi:10.1021/la3036192
Li Y, Krentz TM, Wang L, Benicewicz BC, Schadler LS (2014) Ligand engineering of polymer nanocomposites: from the simple to the complex. ACS Appl Mater Interfaces 6(9):6005–6021. doi:10.1021/am405332a
Luzinov I, Minko S, Tsukruk VV (2004) Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers. Prog Polym Sci 29(7):635–698. doi:10.1016/j.progpolymsci.2004.03.001
Magenau AJD, Strandwitz NC, Gennaro A, Matyjaszewski K (2011) Electrochemically mediated atom transfer radical polymerization. Science 332(6025):81–84. doi:10.1126/science.1202357
Matyjaszewski K (2012) Atom transfer radical polymerization (ATRP): current status and future perspectives. Macromolecules 45(10):4015–4039. doi:10.1021/ma3001719
Matyjaszewski K, Tsarevsky NV (2009) Nanostructured functional materials prepared by atom transfer radical polymerization. Nat Chem 1(4):276–288. doi:10.1038/nchem.257
Matyjaszewski K, Xia JH (2001) Atom transfer radical polymerization. Chem Rev 101(9):2921–2990. doi:10.1021/cr940534g
Matyjaszewski K, Coca S, Gaynor SG, Wei ML, Woodworth BE (1997) Zerovalent metals in controlled ''living'' radical polymerization. Macromolecules 30(23):7348–7350. doi:10.1021/ma971258l
Matyjaszewski K, Jakubowski W, Min K, Tang W, Huang JY, Braunecker WA, Tsarevsky NV (2006) Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents. In: Proceedings of the National Academy of Sciences of the United States of America 103(42):15309–15314. doi:10.1073/pnas.0602675103
Milner ST (1991) Polymer brushes. Science 251(4996):905–914. doi:10.1126/science.251.4996.905
Milner ST, Witten TA, Cates ME (1988) A parabolic density profile for garfted polymers. Europhys Lett 5(5):413–418. doi:10.1209/0295-5075/5/5/006
Mirkin CA, Letsinger RL, Mucic RC, Storhoff JJ (1996) A DNA-based method for rationally assembling nanoparticles into macroscopic materials. Nature 382(6592):607–609. doi:10.1038/382607a0
Narayanan S, Choi J, Porter L, Bockstaller MR (2013) Flexible transparent metal/polymer composite materials based on optical resonant laminate structures. ACS Appl Mater Interfaces 5(10):4093–4099. doi:10.1021/am303211g
Ohno K, Morinaga T, Takeno S, Tsujii Y, Fukuda T (2006) Suspensions of silica particles grafted with concentrated polymer brush: a new family of colloidal crystals. Macromolecules 39(3):1245–1249. doi:10.1021/ma0521708
Ohno K, Morinaga T, Takeno S, Tsujii Y, Fukuda T (2007) Suspensions of silica particles grafted with concentrated polymer brush: effects of graft chain length on brush layer thickness and colloidal crystallization. Macromolecules 40(25):9143–9150. doi:10.1021/ma071770z
Ojha S, Dang A, Hui CM, Mahoney C, Matyjaszewski K, Bockstaller MR (2013) Strategies for the synthesis of thermoplastic polymer nanocomposite materials with high inorganic filling fraction. Langmuir 29(28):8989–8996. doi:10.1021/la401522v
Park SY, Lytton-Jean AKR, Lee B, Weigand S, Schatz GC, Mirkin CA (2008) DNA-programmable nanoparticle crystallization. Nature 451(7178):553–556. doi:10.1038/nature06508
Phillips CL, Iacovella CR, Glotzer SC (2010) Stability of the double gyroid phase to nanoparticle polydispersity in polymer-tethered nanosphere systems. Soft Matter 6(8):1693–1703. doi:10.1039/b911140a
Pietrasik J, Hui CM, Chaladaj W, Dong HC, Choi J, Jurczak J, Bockstaller MR, Matyjaszewski K (2011) Silica-Polymethacrylate hybrid particles synthesized using high-pressure atom transfer radical polymerization. Macromol Rapid Commun 32(3):295–301. doi:10.1002/marc.201000531
Pyun J, Jia SJ, Kowalewski T, Patterson GD, Matyjaszewski K (2003) Synthesis and characterization of organic/inorganic hybrid nanoparticles: Kinetics of surface-initiated atom transfer radical polymerization and morphology of hybrid nanoparticle ultrathin films. Macromolecules 36(14):5094–5104. doi:10.1021/ma034188t
Rodriguez R, Herrera R, Archer LA, Giannelis EP (2008) Nanoscale ionic materials. Adv Mater 20(22):4353–4358. doi:10.1002/adma.200801975
Savin DA, Pyun J, Patterson GD, Kowalewski T, Matyjaszewski K (2002) Synthesis and characterization of silica-graft-polystyrene hybrid nanoparticles: effect of constraint on the glass-transition temperature of spherical polymer brushes. J Polym Sci Part B-Polym Phys 40(23):2667–2676. doi:10.1002/polb.10329
Scheutjens J, Fleer GJ (1979) Statistical-theory of the adsorption of interacting chain molecules.1. Partition-function, segment density distribution and adsorption isotherms. J Phys Chem 83(12):1619–1635. doi:10.1021/j100475a012
Scheutjens J, Fleer GJ (1980) Statistical-theory of the adsorption of interacting chain molecules.2. Train, loop and tail size distribution. J Phys Chem 84(2):178–190. doi:10.1021/j100439a011
Shah AA, Schultz B, Kohlstedt KL, Glotzer SC, Solomon MJ (2013) Synthesis, assembly, and image analysis of spheroidal patchy particles. Langmuir 29(15):4688–4696. doi:10.1021/la460317t
Srivastava S, Schaefer JL, Yang Z, Tu Z, Archer LA (2014) Polymer-particle composites: phase stability and applications in electrochemical energy storage. Adv Mater 26(2):201–233. doi:10.1002/adma.201303070
Tchoul MN, Fillery SP, Koerner H, Drummy LF, Oyerokun FT, Mirau PA, Durstock MF, Vaia RA (2010) Assemblies of titanium dioxide-polystyrene hybrid nanoparticles for dielectric applications. Chem Mater 22(5):1749–1759. doi:10.1021/cm903182n
Tsarevsky NV, Matyjaszewski K (2007) “Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials. Chem Rev 107(6):2270–2299. doi:10.1021/cr050947p
Tsujii Y, Ohno K, Yamamoto S, Goto A, Fukuda T (2006) Structure and properties of high density polymer brushes prepared by surface-initaited living radical polymerization. In: Jordan R (ed) Advances in polymer science: surface initiated polymerization, vol 197. Springer, Berlin, pp 1–47
Virtanen S, Krentz TM, Nelson JK, Schadler LS, Bell M, Benicewicz B, Hillborg H, Zhao S (2014) Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocomposites. IEEE Trans Dielectr Electr Insulation 21(2):563–570. doi:10.1109/tdei.2014.004415
Voudouris P, Choi J, Dong H, Bockstaller MR, Matyjaszewski K, Fytas G (2009) Effect of shell architecture on the static and dynamic properties of polymer-coated particles in solution. Macromolecules 42(7):2721–2728. doi:10.1021/ma802878r
Wang JS, Matyjaszewski K (1995) Controlled living radical polymerization—atom-transfer radical polymerization in the presence of transition-metal complexes. J Am Chem Soc 117(20):5614–5615. doi:10.1021/ja00125a035
Wijmans CM, Zhulina EB (1993) Polymer brushes at curved surfaces. Macromolecules 26(26):7214–7224. doi:10.1021/ma00078a016
Xu C, Wu T, Mei Y, Drain CM, Batteas JD, Beers KL (2005) Synthesis and characterization of tapered copolymer brushes via surface-initiated atom transfer radical copolymerization. Langmuir 21(24):11136–11140. doi:10.1021/la051853d
Yu H-Y, Koch DL (2010) Structure of solvent-free nanoparticle-organic hybrid materials. Langmuir 26(22):16801–16811. doi:10.1021/la102815r
Yu HY, Koch DL (2014) Self-diffusion and linear viscoelasticity of solvent-free nanoparticle-organic hybrid materials. J Rheol 58(2):369–395. doi:10.1122/1.4862316
Zhong M, Matyjaszewski K (2011a) How fast can a CRP be conducted with preserved chain end functionality? Macromolecules 44(8):2668–2677
Zhong MJ, Matyjaszewski K (2011b) How fast can a CRP be conducted with preserved chain end functionality? Macromolecules 44(8):2668–2677. doi:10.1021/ma102834s
Acknowledgments
S. Ramakrishnan and G. L. Chakkalakal were supported by AMSRD-ARL-RO-SI proposal number: 62885-MS-REP, agreement number: W911NF-13-1-0132 from the Department of Defense (Army Research Office).
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Chakkalakal, G., Ramakrishnan, S., Bockstaller, M. (2015). Polymer-Tethered Nanoparticle Materials—An Emerging Platform for Multifunctional Hybrid Materials. In: Kim, CS., Randow, C., Sano, T. (eds) Hybrid and Hierarchical Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-12868-9_3
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