Abstract
Direct deposition methods include physical vapor deposition (PVD), chemical vapor deposition (CVD), and electroplating or electroless plating, etc. PVD describes a variety of vacuum deposition methods used to deposit thin films onto a workpiece surface by the condensation of a vaporized material. These methods (e.g., magnetron sputtering and plasma bombardment) involve purely physical processes. In comparison, CVD is based on chemical reactions happening at the surface to be coated. However, the line-of-sight nature of both PVD and CVD prevents a complete replication of original 3D biomorphologies. This shading effect can be avoided by metal plating conducted in liquid environments. Electroplating uses electrical current to reduce dissolved metal cations and can form a coherent metal coating on a conductive substrate. However, since biotemplates are usually nonconductive, it is unsuitable to the replication of biostructures.
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References
Jinshan H, Solanki R, Mcandrew J (2002) Characteristics of copper films produced via atomic layer deposition. J Mater Res 17:2394–2398
Duffy J, Pearson L, Paunovic M (1983) The effect of pH on electroless copper deposition. J Electrochem Soc 130:876–880
Rossnagel SM (1995) Directional and preferential sputtering-based physical vapor deposition. Th Sol Films 263:1–12
Métraux GS, Mirkin CA (2005) Rapid thermal synthesis of silver nanoprisms with chemically tailorable thickness. Adv Mater 17:412–415
Nickel U, Zu Castell A, Pöppl K et al (2000) A silver colloid produced by reduction with hydrazine as support for highly sensitive surface-enhanced Raman spectroscopy. Langmuir 16:9087–9091
Gu X, Nie C, Lai Y et al (2006) Synthesis of silver nanorods and nanowires by tartrate-reduced route in aqueous solutions. Mater Chem Phys 96:217–222
Adhikari B, Banerjee A (2010) Facile synthesis of water-soluble fluorescent silver nanoclusters and Hg-II sensing. Chem Mater 22:4364–4371
Chen JH, Lee YC, Tang MT et al (2007) X-ray tomography and chemical imaging within butterfly wing scales. AIP Conf Proc 879:1940–1943
Tan Y, Gu J, Zang X et al (2011) Versatile fabrication of intact three-dimensional metallic butterfly wing scales with hierarchical sub-micrometer structures. Angew Chem Int Ed Engl 50:8307–8311
Zhang W, Zhang D, Fan TX et al (2009) Novel photoanode structure templated from butterfly wing scales. Chem Mater 21:33–40
Han J, Su HL, Zhang D et al (2009) Butterfly wings as natural photonic crystal scaffolds for controllable assembly of cds nanoparticles. J Mater Chem 19:8741–8746
Anandhavelu S, Thambidurai S (2011) Preparation of chitosan-zinc oxide complex during chitin deacetylation. Carbohydr Polym 83:1565–1569
Limam Z, Selmi S, Sadok S et al (2011) Extraction and characterization of chitin and chitosan from crustacean by-products: biological and physicochemical properties. Afr J Biotechnol 10:640–647
Griffiths PR (2006) Introduction to the theory and instrumentation for vibrational spectroscopy. Wiley, Hoboken
Caldwell JD, Glembocki O, Bezares FJ et al (2011) Plasmonic nanopillar arrays for large-area, high-enhancement surface-enhanced Raman scattering sensors. ACS Nano 5:4046–4055
Chen Z, Zhan P, Wang ZL et al (2004) Two- and three-dimensional ordered structures of hollow silver spheres prepared by colloidal crystal templating. Adv Mater 16:417–422
Omura Y, Renbutsu E, Morimoto M et al (2003) Synthesis of new chitosan derivatives and combination with biodegradable polymer. Polym Adv Technol 14:35–39
Zabetakis D, Dressick WJ (2009) Selective electroless metallization of patterned polymeric films for lithography applications. ACS Appl Mater Interfaces 1:4–25
Renbutsu E, Okabe S, Omura Y et al (2007) Synthesis of UV-curable chitosan derivatives and palladium (II) adsorption behavior on their UV-exposed films. Carbohydr Polym 69:697–706
Smoukov SK, Bishop KJM, Campbell CJ et al (2005) Freestanding three-dimensional copper foils prepared by electroless deposition on micropatterned gels. Adv Mater 17:751–755
Renbutsu E, Okabe S, Omura Y et al (2008) Palladium adsorbing properties of UV-curable chitosan derivatives and surface analysis of chitosan-containing paint. Inter J Biol Macromol 43:62–68
Bao ZH, Weatherspoon MR, Shian S et al (2007) Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas. Nature 446:172–175
Chen Y, Zang XN, Gu JJ et al (2011) ZnO single butterfly wing scales: synthesis and spatial optical anisotropy. J Mater Chem 21:6140–6143
Liu XY, Zhu SM, Zhang D et al (2010) Replication of butterfly wing in TiO2 with ordered mesopores assembled inside for light harvesting. Mater Lett 64:2745–2747
Song F, Su HL, Chen JJ et al (2011) Bioinspired ultraviolet reflective photonic structures derived from butterfly wings (Euploea). Appl Phy Lett 99:163705
Zhu S, Liu X, Chen Z et al (2010) Synthesis of Cu-doped WO3 materials with photonic structures for high performance sensors. J Mater Chem 20:9126–9132
Peng WH, Zhu SM, Wang WL et al (2012) 3D network magnetophotonic crystals fabricated on Morpho butterfly wing templates. Adv Funct Mater 22:2072–2080
Wang J, Chen X, Wang G et al (2002) Melting behavior in ultrathin metallic nanowires. Phys Rev B 66:085408
Lisiecki I, Sack-Kongehl H, Weiss K et al (2000) Annealing process of anisotropic copper nanocrystals. Langmuir 16:8807–8808
Dippel M, Maier A, Gimple V et al (2001) Size-dependent melting of self-assembled indium nanostructures. Phys Rev Lett 87:095505
Link S, Wang ZL, El-Sayed MA (2000) How does a gold nanorod melt? J Phys Chem B 104:7867–7870
Vincendon M (1997) Regenerated chitin from phosphoric acid solutions. Carbohydr Polym 32:233–237
Lakhtakia A, Martin-Palma RJ, Motyka MA et al (2009) Fabrication of free-standing replicas of fragile, laminar, chitinous biotemplates. Bioinspir Biomim 4:034001
Weatherspoon MR, Cai Y, Crne M et al (2008) 3D rutile titania-based structures with Morpho butterfly wing scale morphologies. Angew Chem Int Ed Engl 47:7921–7923
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© 2015 Jiajun Gu, Di Zhang, and Yongwen Tan
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Gu, J., Zhang, D., Tan, Y. (2015). Metal Scale Replicas Prepared via Electroless Deposition. In: Metallic Butterfly Wing Scales. SpringerBriefs in Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-12535-0_3
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DOI: https://doi.org/10.1007/978-3-319-12535-0_3
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