Abstract
In this work we present a route to engineer bilayer graphene superlattices via direct nanomanipulation of monolayer graphene sheets by the mean of atomic force microscopy. In order to obtain such structures we manipulate the graphene sheet using an A FM tip in contact mode by scanning it parallel to the edge direction. Since the static surface atomic potential created by the twisted bilayer structure depends on the mismatch angle between the top and bottom layers, we carried out lattice resolution images in order to determine the crystallographic orientation of the graphene and of the folded twisted bilayer.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
B Borca, S Barja, M Garnica et al (2010) Electronic and geometric corrugation of periodically rippled, self-nanostructured graphene epitaxially grown on Ru(0001). New J Phys 12: 093018
M Yankowitz, J Xue, D Cormode et al (2012) Emergence of superlattice Dirac points in graphene on hexagonal boron nitride. Nature Phys 8: 382-386
R Martinazzo, S Casolo, G F Tantardini (2010) Symmetry-induced band-gap opening in graphene superlattices. Phys Rev B 81: 245420
H Şahin, S Ciraci1 (2011) Structural, mechanical, and electronic properties of defect-patterned graphene nanomeshes from first principles. Phys. Rev. B 84: 035452
F Guinea, T Low (2010) Band structure and gaps of triangular graphene superlattices. Phil Trans R Soc A 368: 5391-5402
D Tománek, S G Louie, H J Mamin, D W Abraham, R EThomson, E Ganz, J Clarke (1987) Theory and observation of highly asymmetric atomic structure in scanning-tunneling-microscopy images of graphite. Phys Rev B 35: 7790
M Killi,S Wu, A Paramekanti (2011) Band structures of bilayer graphene superlattices. Phys Rev Lett 107: 086801
E SuárezMorell, J D Correa, P Vargas, M Pacheco, Z Barticevic (2010) Flat bands in slightly twisted bilayer graphene: Tight-binding calculations. Phys Rev B 82:121407
V Carozo, C M Almeida, E H M Ferreira, L G Cancado, C A Achete, A Jorio (2011) Raman signature of graphene superlattices. Nano Lett 11 (11): 4527
R W Havener, H Zhuang, L Brown, R Hennig, J Park (2012) Angle-Resolved Raman Imaging of Interlayer Rotations and Interactions in Twisted Bilayer Graphene. Nano Lett 12 (6): 3162–3167
M J Allen, M Wang, S A Jannuzzi, Y Yang, KL Wang, RB Kaner (2009) Chemically induced folding of single and bilayer graphene. Chem Commun 41:6285
L X Li, R P Liu, Z W Chen, Q Wang et al (2006) Tearing, folding and deformation of a carbon-carbon sp2-bonded network. Carbon 44: 1544
C M Mate, G M McClelland, R Erlandsson, S Chiang (1987) Atomic-scale friction of a tungsten tip on a graphite surface. Phys Rev Lett 59: 1942
D R Baselt, J D Baldeschwieler (1992) Lateral Forces During Atomic Force Microscopy of Graphite in Air. J Vac Sci Technol B 10: 2316
W-C Lai, S-C Chin, Y-C Chang, L-Y Chen, C-S Chang (2010) Lattice-resolved frictional pattern probed by tailored carbon nanotubes. Nanotech 21: 055702
C M Almeida, V Carozo, R Prioli, C A Achete (2011) Identification of graphene crystallographic orientation by atomic force microscopy. J Appl Phys 110: 086101
K S Novoselov, A K Geim, S V Morozov, D Jiang, Y Zhang, S V Dubonos, I V Grigorieva, A A Firsov (2004) Electric Field Effect in Atomically Thin Carbon Films. Science 306: 666-669
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Almeida, C.M., Bede, P.M., Fragneaud, B., Achete, C.A. (2014). Engineering graphene superlattices with crystallographic orien-tation control using atomic force microscope. In: Udomkichdecha, W., Böllinghaus, T., Manonukul, A., Lexow, J. (eds) Materials Challenges and Testing for Manufacturing, Mobility, Biomedical Applications and Climate. Springer, Cham. https://doi.org/10.1007/978-3-319-11340-1_1
Download citation
DOI: https://doi.org/10.1007/978-3-319-11340-1_1
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-11339-5
Online ISBN: 978-3-319-11340-1
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)