Abstract
The first electrochemical experiments were performed with solid materials, esp. metals. However, these experiments, conducted in the eighteenth and nineteenth centuries, were directed toward the elucidation of the basic features of the electrical action of chemical substances and the chemical action of electricity. Initially, metals played the major role; only later it became obvious that many chemical compounds possess metallic or semiconducting properties that can be utilized in electrochemical cells. Parallel to the studies of new electrode materials, solid electrolytes were discovered and entire solid galvanic cells could be constructed. In this book, we will entirely neglect pure solid electrolytes because this is a field in its own and the subject of many thorough treatises.
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Scholz, F., Schröder, U., Gulaboski, R., Doménech-Carbó, A. (2015). Earlier Developed Techniques. In: Electrochemistry of Immobilized Particles and Droplets. Springer, Cham. https://doi.org/10.1007/978-3-319-10843-8_1
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