Abstract
Size exclusion chromatography separates polyolefins according to hydrodynamic size in solution and it is assumed that one hydrodynamic size corresponds strictly to one molar mass. This, however, is not always the case as has been shown, e.g. for high molar mass branched polymers. For such materials, co-elution of linear and branched molecules having different molar masses has been observed. On the other hand, samples with very high molar masses cause problems in SEC because the largest molecules are frequently shear degraded by the pores and frits of the columns, resulting in molar masses that are lower compared to those of the injected sample. Most of the above problems can be avoided when channel-based fractionation methods are used. This chapter presents some latest results on polyolefin analysis by field-flow fractionation. The fundamentals of the technique are discussed and a number of experimental approaches are given.
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References
Johann C, Kilz P (1991) J Appl Polym Sci Appl Polym Symp 48:111
Wintermantel M, Antonietti M, Schmidt M (1993) J Appl Polym Sci Appl Polym Symp 5:91
Podzimek S (1994) J Appl Polym Sci 54:91
Percec V, Ahn CH, Cho WD, Jamieson AM, Kim J, Leman T, Schmidt M, Gerle M, Möller M, Prokhorova SA, Sheiko SS, Cheng SD, Zhang A, Ungar G, Yeardley DJ (1998) J Am Chem Soc 120:8619
Gerle M, Fischer K, Roos S, Muller AHE, Schmidt M (1999) Macromolecules 32:2629
Mes EPC, de Jonge H, Klein T, Welz RR, Gillespie DT (2007) J Chromatogr A 1154:319
Otte T, Pasch H, Macko T, Brüll R, Stadler FJ, Kaschta J, Becker F, Buback MJ (2011) Chromatogr A 1218:4257
Makan AC, Otte T, Pasch H (2012) Macromolecules 45:5247
Slagowski EL, Fetters LJ, McIntyre D (1974) Macromolecules 7:394
Zammit MD, Davis TP, Suddaby KG (1998) Polymer 39:5789
Aust N (2003) J Biochem Biophys Methods 56:323
Cave RA, Seabrook SA, Gidley MJ, Gilbert RG (2009) Biomacromolecules 10:2245
Messaud FA, Sanderson RD, Runyon JR, Otte T, Pasch H, Williams SKR (2009) Prog Polym Sci 34:351
Stadler FJ, Kaschta J, Münstedt H, Becker F, Buback M (2009) Rheol Acta 48:479
Schimpf ME, Caldwell K, Giddings JC (2000) Field flow fractionation handbook. John Wiley, Hoboken, NJ
van Bruijnsvoort M, Wahlund KG, Nilsson G, Kok WTJ (2001) Chromatogr A 925:171
Rojas CC, Wahlund KG, Bergenstahl B, Nilsson L (2008) Biomacromolecules 9:1684
Rolland-Sabaté A, Guilois S, Jaillais B, Colonna P (2011) Anal Bioanal Chem 399:1493
Podzimek S (2011) Light scattering, size exclusion chromatography and asymmetric flow field flow fractionation: powerful tools for the characterization of polymers, proteins and nanoparticles. John Wiley, Hoboken, NJ
Bang DY, Shin DY, Lee S, Moon MH (2007) J Chromatogr A 1147:200
Otte T, Brüll R, Macko T, Pasch H, Klein T (2010) J Chromatogr A 1217:722
Otte T, Klein T, Brüll R, Macko T, Pasch H (2011) J Chromatogr A 1218:4240
White RJ (1997) Polym Int 43:373
Liu Y, Radke W, Pasch H (2006) Macromolecules 39:2004
Giddings JC (1993) Science 260:1456
Pasch H, Malik MI, Macko T (2013) Adv Polym Sci 251:77
Gao S, Caldwell D, Myers N, Giddings JC (1985) Macromolecules 18:1272
Miller ME, Giddings JC (1998) J Micro Sep 10:75
Otte T, Pasch H, Brüll R, Macko T (2011) Macromol Chem Phys 212:401
Trinkle S, Friedrich C (2001) Rheol Acta 40:322
Aust N, Parth M, Lederer K (2001) Int J Polym Anal Charact 6:245
Parth M, Aust N, Lederer K (2003) Int J Polym Anal Charact 8:175
Grinshpun V, Rudin A (1985) J Appl Polym Sci 30:2413
Pasti L, Melucci D, Contado C, Dondi F, Mingozzi I (2002) J Sep Sci 25:691
de Groot AW, Hamre WJ (1993) J Chromatogr A 648:33
Barth HG, Carlin FJ Jr (1984) J Liq Chromatogr 7:1717
Zigon M, The NK, Shuyao C, Grubisic-Gallot Z (1997) J Liq Chromatogr 20:2155
Schnabel M (1981) Polymer degradation: principles and practical applications. Hanser International, Munich
Constantin D, Hert M, Machon JP (1981) Eur Polym J 17:115
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Pasch, H., Malik, M.I. (2014). Field-Flow Fractionation. In: Advanced Separation Techniques for Polyolefins. Springer Laboratory. Springer, Cham. https://doi.org/10.1007/978-3-319-08632-3_4
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DOI: https://doi.org/10.1007/978-3-319-08632-3_4
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