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Column-Based Chromatographic Techniques

  • Harald Pasch
  • Muhammad Imran Malik
Chapter
Part of the Springer Laboratory book series (SPLABORATORY)

Abstract

Crystallization-based fractionation techniques are powerful methods for the chemical composition fractionation of semi-crystalline polyolefins. The non-crystallizing part cannot be fractionated and is obtained as a bulk fraction. As alternative methods, column-based separation techniques can be used. These techniques fractionate polyolefins regardless of crystallinity based on molecular size, chemical composition and/or branching. In this chapter, experimental approaches for the molar mass analysis by size exclusion chromatography and the chemical composition analysis by different means of interaction chromatography will be presented. The dual molar mass/chemical composition fractionation by two-dimensional liquid chromatography will be highlighted and examples for comprehensive analysis will be given.

Keywords

High Performance Liquid Chromatography Molar Mass Size Exclusion Chromatography Evaporative Light Scatter Detector High Molar Mass 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer International Publishing Switzerland 2014

Authors and Affiliations

  • Harald Pasch
    • 1
  • Muhammad Imran Malik
    • 2
  1. 1.Department of Chemistry and Polymer ScienceUniversity of StellenboschMatielandSouth Africa
  2. 2.International Center for Chemical and Biological Sciences (ICCBS) H.E.J. Research Institute of ChemistryUniversity of KarachiKarachiPakistan

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