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Column-Based Chromatographic Techniques

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Advanced Separation Techniques for Polyolefins

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Abstract

Crystallization-based fractionation techniques are powerful methods for the chemical composition fractionation of semi-crystalline polyolefins. The non-crystallizing part cannot be fractionated and is obtained as a bulk fraction. As alternative methods, column-based separation techniques can be used. These techniques fractionate polyolefins regardless of crystallinity based on molecular size, chemical composition and/or branching. In this chapter, experimental approaches for the molar mass analysis by size exclusion chromatography and the chemical composition analysis by different means of interaction chromatography will be presented. The dual molar mass/chemical composition fractionation by two-dimensional liquid chromatography will be highlighted and examples for comprehensive analysis will be given.

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Authors and Affiliations

  1. Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland, South Africa

    Harald Pasch

  2. International Center for Chemical and Biological Sciences (ICCBS) H.E.J. Research Institute of Chemistry, University of Karachi, Karachi, Pakistan

    Muhammad Imran Malik

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  1. Harald Pasch
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  2. Muhammad Imran Malik
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Pasch, H., Malik, M.I. (2014). Column-Based Chromatographic Techniques. In: Advanced Separation Techniques for Polyolefins. Springer Laboratory. Springer, Cham. https://doi.org/10.1007/978-3-319-08632-3_3

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