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Transparent Hybrid Films for Stone Conservation and Protection

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Built Heritage: Monitoring Conservation Management

Part of the book series: Research for Development ((REDE))

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Abstract

In this study a silane polymer and an inorganic nanoparticles (TiO2)/polymer composite coating have been tested as protective agents on three different substrates, Carrara/Botticino marbles and Angera stone to improve their hydrophobicity features. The coatings obtained turned out to be hydrophobic as concerns the sylane polymer and superhydrophobic in the case of the hybrid coating. Aging tests have demonstrated the stability of the surface colours.

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References

  • Alessandrini, G., Aglietto, M., Castelvetro, V., Ciardelli, F., Peruzzi, R., & Toniolo, L. (2000). Comparative evaluation of fluorinated and unfluorinated acrylic copolymers as water repellent coating materials for stone. Journal of Applied Polymer Scence, 76, 962–977.

    Article  Google Scholar 

  • Castelvetro, V., Aglietto, M., Ciardelli, F., Chiantore, O., Lazzari, M., & Toniolo, L. (2002). Structure control, coating properties, and durability of fluorinated acrylic-based polymers. Journal of Coatings Technology, 4, 57–66.

    Article  Google Scholar 

  • Chen, J. H., Hu, J., Wang, M., Min, C., & Zhao, Y. (2013). Biomimetic superhydrophobic surfaces. Journal of Dispersion Science and Technology, 34, 1–21.

    Google Scholar 

  • Fermo, P., Cappelletti, G., Cozzi, N., Padeletti, G., Kaciulis, S., Brucale, M. C, & Merlini, M. (2013). Hydrophobizing coatings for cultural heritage. A detailed study of resin/stone surface interaction. Applied Physics A, 116, 341–348.

    Google Scholar 

  • Hsieh, C. T., Chen, J. M., Kuo, R. R., Lin, T. S., & Wu, C. F. (2005). Influence of surface roughness on water- and oil-repellent surfaces coated with nanoparticles. Applied Surface Science, 240, 318–326.

    Article  Google Scholar 

  • Khallaf, M. K., El-Midany, A. A., & El-Mofty, S. E. (2011). Influence of acrylic coatings on the interfacial, physical, and mechanical properties of stone-based monuments. Progress in Organic Coating, 72, 592–598.

    Article  Google Scholar 

  • Licciulli, A., Calia, A., Lettieri, M., Diso, D., Masieri, M., Franza, S., et al. (2011). Photocatalytic TiO2 coatings on limestone. Journal of Sol-Gel Science Technology, 60, 437–444.

    Article  Google Scholar 

  • Ono, K., Andaroodi, E., Einifar, A., Abe, N., Matini, M. R., Bouet, O., et al. (2008). 3DCG reconstitution and virtual reality of UNESCO world heritage in danger: The Citadel of Bam. Progress in Informatics, 5, 99–136.

    Article  Google Scholar 

  • Price, C. A. (1996). Stone conservation, an overview of current research (Vol. 73). Santa Monica, CA: J. Paul Getty Trust.

    Google Scholar 

  • Quagliarini, E., Bondioli, F., Goffredo, G. B., Licciulli, A., & Munafo, P. (2012). Smart surfaces for architectural heritage: Preliminary results about the application of TiO2-based coatings on travertine. Journal of Cultural Heritage, 13, 204–209.

    Article  Google Scholar 

  • Quagliarini, E., Bondioli, F., Goffredo, G. B., Licciulli, A., & Munafo, P. (2013). Self-cleaning materials on Architectural Heritage: Compatibility of photo-induced hydrophilicity of TiO2 coatings on stone surfaces. Journal of Cultural Heritage, 14, 1–7.

    Article  Google Scholar 

  • Wu, L. Y. L., Soutar, A. M., & Zeng, X. T. (2005). Increasing hydrophobicity of sol-gel hard coatings by chemical and morphological modifications. Surface Coating Technology, 198, 420.

    Article  Google Scholar 

  • Zielecka, M., & Bujnowska, E. (2006). Silicone-containing polymer matrices as protective coatings—Properties and applications. Progress in Organic Coating, 55, 160–167.

    Article  Google Scholar 

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Correspondence to P. Fermo .

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© 2015 Springer International Publishing Switzerland

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Cappelletti, G., Fermo, P., Piazzalunga, A., Padeletti, G. (2015). Transparent Hybrid Films for Stone Conservation and Protection. In: Toniolo, L., Boriani, M., Guidi, G. (eds) Built Heritage: Monitoring Conservation Management. Research for Development. Springer, Cham. https://doi.org/10.1007/978-3-319-08533-3_36

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  • DOI: https://doi.org/10.1007/978-3-319-08533-3_36

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-08532-6

  • Online ISBN: 978-3-319-08533-3

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