Abstract
In order to investigate the orthogonal self-assembled character of gelled bicontinuous microemulsions the first and fundamental step was to identify under which conditions a mixture of water, n-decane, C10E4 and 12-HOA forms the desired system. Thus it was crucial to carry out phase studies. On the one hand, a microemulsion is known to be bicontinuous at its \(\widetilde{T}\) temperature.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Notes
- 1.
Note that the main results of this Chapter have already been published in a peer-reviewed paper entitled “Studying orthogonal self-assembled systems: phase behaviour and rheology of gelled microemulsions” in the journal Soft Matter [2]. The figures are herein reproduced, in modified form, by permission of The Royal Society of Chemistry.
- 2.
Measurements carried out by Kristina Jovic during her bachelor thesis and her ‘Hiwi’ employment under my supervision. Note that such measurements will in the following be indicated by “KJ”
- 3.
The density measurements were carried out with a DMA 5000 M density meter from Anton Paar.
- 4.
References
C. Stubenrauch, C. Frank, R. Strey, D. Burgemeister, C. Schmidt, Langmuir 18, 5027–5030 (2002)
M. Laupheimer, K. Jovic, F.E. Antunes, M.M.M. da Graça, C. Stubenrauch, Soft Matter 9, 3661–3670 (2013)
S. Burauer, T. Sachert, T. Sottmann, R. Strey, Phys. Chem. Chem. Phys. 1, 4299–4306 (1999)
C. Stubenrauch, R. Tessendorf, R. Strey, I. Lynch, K.A. Dawson, Langmuir 23, 7730–7737 (2007)
M.H.G.M. Penders, R. Strey, J. Phys. Chem. 99, 10313–10318 (1995)
M. Laupheimer, C. Stubenrauch, Tenside Surf. Det. 51, 17–25 (2014)
P. Terech, S. Friol, Tetrahedron 63, 7366–7374 (2007)
P. Terech, V. Rodriguez, J.D. Barnes, G.B. McKenna, Langmuir 10, 3406–3418 (1994)
S.R. Raghavan, B.H. Cipriano, in Molecular Gels. Materials with Self-Assembled Fibrillar Networks, ed. by R.G. Weiss, P. Terech (Springer, Dordrecht, 2006), pp. 241–252
M. Núñez-Santiago, A. Tecante, Carbohydr. Polym. 69, 763–773 (2007)
M. Tomšič, F. Prossnigg, O. Glatter, J. Colloid Interface Sci. 322, 41–50 (2008)
M. George, R.G. Weiss, in: Molecular Gels. Materials with Self-Assembled Fibrillar Networks, ed. by R.G. Weiss, P. Terech (Springer, Dordrecht, 2006), pp. 449–551
R. Tessendorf, unpublished work
R. Tessendorf, Microemulsions as Templates for High Surface Area Polymers (WiKu-Wissenschaftsverlag Dr. Stein, Köln, 2009)
M.A. Rogers, T. Pedersen, L. Quaroni, Cryst. Growth Des. 9, 3621–3625 (2009)
J.E. Eldridge, J.D. Ferry, J. Phys. Chem. 58, 992–995 (1954)
K. Murata, M. Aoki, T. Suzuki, T. Harada, H. Kawabata, T. Komori, F. Ohseto, K. Ueda, S. Shinkai, J. Am. Chem. Soc. 116, 6664–6676 (1994)
N. Amanokura, K. Yoza, H. Shinmori, S. Shinkai, D.N. Reinhoudt, J. Chem. Soc. Perkin Trans. 2, 2585–2591 (1998)
P. Terech, C. Rossat, F. Volino, J. Colloid Interface Sci. 227, 363–370 (2000)
S. Bhattacharya, A. Pal, J. Phys. Chem. B 112, 4918–4927 (2008)
K. Nishinari, Progr. Colloid Polym. Sci. 136, 87–94 (2009)
P. Terech, R.G. Weiss, Chem. Rev. 97, 3133–3159 (1997)
M. Magno, R. Tessendorf, B. Medronho, M.M.M. da Graça, C. Stubenrauch, Soft Matter 5, 4763–4772 (2009)
A.M. Brizard, M.C.A. Stuart, J.H. van Esch, Faraday Discuss. 143, 345–357 (2009)
M. Burkhardt, S. Kinzel, M. Gradzielski, J. Colloid Interface Sci. 331, 514–521 (2009)
J.L. Jones, C.M. Marques, J. Phys. France 51, 1113–1127 (1990)
P. Terech, D. Pasquier, V. Bordas, C. Rossat, Langmuir 16, 4485–4494 (2000)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Laupheimer, M. (2014). Phase Behaviour and Rheology of Gelled Microemulsions. In: Gelled Bicontinuous Microemulsions. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-07719-2_3
Download citation
DOI: https://doi.org/10.1007/978-3-319-07719-2_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-07718-5
Online ISBN: 978-3-319-07719-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)