Abstract
We have studied the pH and the temperature effects on copper ions adsorption on natural and treated clays from ENOF Chemical Ltd., Research Company, Algeria. Treated clay was studied to improve the adsorption capacity. X-Ray diffraction identified montmorillonite and kaolinite as major clay minerals. The langmuir adsorption model was used for the mathematical description of the adsorption equilibrium and the equilibrium data adhered very well to this model. The treated and natural clay had the monolayer adsorption capacity equal to 15.40 and 12.22 mg.g−1 respectively at pH value of 6.5 and 20 °C and the adsorption isotherms could be fitted with Langmuir isotherms, and the coefficients indicated favorable adsorption of Cu(II) on the clays. Determination of the thermodynamic parameters, H, S and G showed that the adsorption process was spontaneous and exothermic accompanied by decrease in entropy and Gibbs energy. Results of this study will be useful for future scale up for using this material as a low-cost adsorbent for the removal of Cu(II) from wastewater.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Unlu, N., Ersoz, M.: Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sobent from aqueous solutions. J. Hazard. Mater. B 136, 272–280 (2006)
Srivastava, V.C., Mall, I.D., Misha, I.M.: Characterisation of mesoporous rice husk ash (RHA) and adsorption kinetics of metal ions from aqueous solution onto RHA. J. Hazard. Mater. B 134, 257–267 (2006)
Das, N., Kumar, J.R.: Adsorption of some bivalent heavy metal ions from aqueous solutions by manganese nodule leached residues. J. Colloid Interface Sci. 293, 253–262 (2006)
Pusino, A., Micera, G., Gessa, C., Petretto, S.: Interaction of diclofop and diclofop–methyl with Al 3+, Fe 3+, and Cu 2+ saturated montmorillonite. Clays Clay Miner. 37, 558–562 (1989)
Robert, M., Tessier, D.: Méthode de préparation des argiles des sols pour des études minéralogiques. Ann. Agron 25, 859–882 (1974)
Foletto, E.L., Volzone, C., Porto, L.: Performance of an Argentinian acid-activated bentonite in the bleaching of soybean oil. Braz. J. Chem. Eng. 20, 139–145 (2003)
Hajjaji, M., Kacim, S., Alami, A., El-Bouadili, A., El Mountassir, M.: Chemical and mineralogical Characterization of a clay taken from the Moroccan Meseta and a study of the interaction between its fine fraction and methyleneblue. Appl. Clay Sci. 20, 1–12 (2001)
Madejova, J.: FTIR techniques in clay mineral studies. Vib. Spectrosc. 31, 1–10 (2003)
Heller-Kallai, L., Bergaya, F., Theng, B.K.G., Lagaly, G.: Handbook of Clay Science. Developments in Clay Science, pp. 289–308, Elsevier, Amsterdam (2006)
Ghosh, D., Bhattacharyya, K.G.: Adsorption of methylene blue on kaolinite Appl. Clay Sci. 20, 295–300 (2002)
Yavuz, O., Altunkaynk, Y., Güzel, F.: Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Res. 37, 948–952 (2003)
Stumm, W.: Chemistry of the Solid–Water interface, pp. 21–34, 229–232. Wiley, New York (1992)
Farrah, H., Pickeringf, W.F.: The effect of pH on the retention of Cu, Pb, Zn and Cd by clay-humic acid mixtures. Water Air Soil Pollut. 8, 189–179 (1977)
Bellir, K., Bencheikh, L., et al.: Study of the retention of heavy metals by natural material used as liners in landfills. Desalination 185, 111–119 (2005)
Boddu, V.M., Abburi, K., et al.: Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent. Environ. Sci. Technol. 37, 4449–4456 (2003)
Benzina, M.: Contribution à l’étude cinétique et thermodynamique de l’adsorption des vapeurs organiques sur des argiles locales, Modélisation d’un adsorbeur à lit fixe. Thèse de Doctorat es-science physique, Faculté des sciences de Tunis 25 (1990)
Seki, Y., Yurdakoc, K.: Adsorption of promethazine hydrochloride with KSF montmorillonite. Adsorption 12(1), 89–100 (2006)
Suhas, C.P.J.M., Ribeiro, C.M.M.L.: Lignin from natural adsorbent to activated carbon. a review. Bioresour. Technol. 98, 2301–2312 (2007)
Acknowledgements
The authors would like to thank the University of Technology Faculty of Chemistry, Oran, Algeria and Mascara’s Laboratory University. The authors thank also Prof. F. Djafri for her assistance in XRD and IR measurements and educational experience, without forgetting Prof. A. Djafri for her helpful discussions. Finally, the authors offer a special thanks to Prof. M. Bouchekara for his guidance and support throughout of this research.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Djebbar, M., Djafri, F., Bouchekara, M. (2014). Equilibrium, Langmuir Isotherms and Thermodynamic Studies for Adsorption of Cu(II) on Natural Clay. In: Öchsner, A., Altenbach, H. (eds) Design and Computation of Modern Engineering Materials. Advanced Structured Materials, vol 54. Springer, Cham. https://doi.org/10.1007/978-3-319-07383-5_24
Download citation
DOI: https://doi.org/10.1007/978-3-319-07383-5_24
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-07382-8
Online ISBN: 978-3-319-07383-5
eBook Packages: EngineeringEngineering (R0)