Abstract
In order to generate more structurally relevant biomimetics for dinuclear metallohydrolases much effort has been devoted to the synthesis of asymmetric ligands. These ligands are considered to be more suitable models for the asymmetric coordination environment found in enzymatic systems.
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Notes
- 1.
Parts of this chapter have appeared in L.J. Daumann et al., “Asymmetric Zinc(II) Complexes as Functional and Structural Models for Phosphoesterases” Dalton Trans. 2013; 42, 9574–9584—Reproduced by permission of The Royal Society of Chemistry.
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Daumann, L.J. (2014). Asymmetric Zn(II) Complexes as Structural and Functional Models for GpdQ. In: Spectroscopic and Mechanistic Studies of Dinuclear Metallohydrolases and Their Biomimetic Complexes. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-06629-5_7
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