New Nanosized Systems Based Lanthanide Diketonate Complexes for OLEDs

  • I. A. SavchenkoEmail author
  • A. S. Berezhnytska
  • N. B. Ivakha
  • E. K. Trunova
Conference paper
Part of the Springer Proceedings in Physics book series (SPPHY, volume 156)


The complexes of erbium with 2-methyl-5-phenylpenten-1-3,5-dion (mphpd), Er(mphpd)3 · 2H2O and allyl-3-oxo-butanoate (allyl) Er(OH)(allyl)2 · H2O were synthesized. On their basis, the metallopolymers [Er(mphpd)3]n and [Er(OH)(allyl)2]nwere obtained by free-radical polymerization, and the kinetics of polymerization was studied by dilatometric method at the first time. The method of dynamic light scattering and the results of electronic microscopy showed that the obtained polymer systems are nanoscale. The luminescent spectra of obtained metallocomplexes in solid state are investigated and analyzed.


Electronic Absorption Spectrum Lanthanide Complex Monomeric Complex Triplet Exciton Dope Polymer 
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Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  • I. A. Savchenko
    • 1
    Email author
  • A. S. Berezhnytska
    • 2
  • N. B. Ivakha
    • 2
  • E. K. Trunova
    • 2
  1. 1.National Taras Shevchenko University of KyivKyivUkraine
  2. 2.V. I. Vernadsky Institute of General and Inorganic Chemistry NASUKievUkraine

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