Abstract
A possible explanation for the enhanced flow in carbon nanotubes is given using a mathematical model that includes a depletion layer with reduced viscosity near the wall. In the limit of large tubes the model predicts no noticeable enhancement. For smaller tubes the model predicts enhancement that increases as the radius decreases. An analogy between the reduced viscosity and slip-length models shows that the term slip-length is misleading and that on surfaces which are smooth at the nanoscale it may be thought of as a length-scale associated with the size of the depletion region and viscosity ratio. The model therefore provides a physical interpretation of the classical Navier slip condition and explains why “slip-lengths” may be greater than the tube radius.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Denn, M.M.: Extrusion instabilities and wall slip. Annu. Rev. Fluid Mech. 33, 265–287 (2001)
Neto, C., Evans, D.R., Bonaccurso, E., Butt, H.-J., Craig, V.S.J.: Boundary slip in Newtonian liquids: a review of experimental studies. Rep. Prog. Phys. 68, 2859–2897 (2005)
Tretheway, D.C., Meinhart, C.D.: Apparent fluid slip at hydrophobic microchannel walls. Phys. Fluids 14(3), L9–L12 (2002)
Choi, C.-H., Westin, J.A., Breuer, K.S.: Apparent slip flows in hydrophilic and hydrophobic microchannels. Phys. Fluids 15(10), 2897–2902 (2003)
Whitby, M., Cagnon, L., Thanou, M., Quirke, N.: Enhanced fluid flow through nanoscale carbon pipes. Nano Lett. 8(9), 2632–2637 (2008)
Holt, J.K., Park, H.G., Wang, Y., Stadermann, M., Artyukhin, A.B., Grigoropoulos, C.P., Noy, A., Bakajin, O.: Fast mass transport through sub-2-nanometer carbon nanotubes. Science 312, 1034 (2006)
Majumder, M., Chopra, N., Andrews, R., Hinds, B.J.: Enhanced flow in carbon nanotubes. Nature 438, 44 (2005)
Thomas, J.A., McGaughey, A.J.H.: Reassessing fast water transport through carbon nanotubes. Nano Lett. 8(9), 2788–2793 (2008)
Verweij, H., Schillo, M.C., Li, J.: Fast mass transport through carbon nanotube membranes. Small 3(12), 1996–2004 (2007)
Werder, T., et al.: Molecular dynamics simulation of contact angles of water droplets in carbon nanotubes. Nano Lett. 1, 697–702 (2001)
Hummer, G., Rasaiah, J.C., Noworyta, J.P.: Water conduction through the hydrophobic channel of a carbon nanotube. Nature 414(8), 188–190 (2001)
Noya, A., et al.: Nanofluidics in carbon nanotubes. NanoToday 2(6), 22–29 (2007)
Vinogradova, O.I.: Slippage of water over hydrophobic surfaces. Int. J. Miner. Process. 56, 31–60 (1999)
Eijkel, J.C.T., van den Berg, A.: Nanofluidics: what is it and what can we expect from it? Microfluid. Nanofluid. 1, 249–267 (2005)
Myers, T.G.: Why are slip lengths so large in carbon nanotubes? Microfluid. Nanofluid. 10, 1141–1145 (2011)
Joseph, S., Aluru, N.R.: Why are carbon nanotubes fast transporters of water? Nano Lett. 8(2), 452–458 (2008)
Thomas, J.A., McGaughey, A.J.H.: Density, distribution, and orientation of water molecules inside and outside carbon nanotubes. J. Chem. Phys. 128, 084715 (2008)
Verdaguer, A., Sacha, G.M., Bluhm, H., Salmeron, M.: Molecular structure of water at interfaces: wetting at the nanometer scale. Chem. Rev. 106, 1478–1510 (2006)
Travis, K.P., Todd, B.D., Evans, D.J.: Departure from Navier-Stokes hydrodynamics in confined liquids. Phys. Rev. E 55(4), 4288–4295 (1997)
Cottin-Bizonne, C., Cross, B., Steinberger, A., Charlaix, E.: Boundary slip on smooth hydrophobic surfaces: intrinsic effects and possible artifacts. Phys. Rev. Lett. 94, 056102 (2005)
Alexeyev, A.A., Vinogradova, O.I.: Flow of a liquid in a nonuniformly hydrophobized capillary. Colloids Surf. A Physicochem. Eng. Aspects 108, 173–179 (1996)
Zhu, Y., Granick, S.: Rate-dependent slip of Newtonian liquids at smooth surfaces. Phys. Rev. Lett. 87, 96105 (2001)
Thomas, J.A., McGaughey, A.J.H., Kuter-Arnebeck, O.: Pressure-driven water flow through carbon nanotubes: insights from molecular dynamics simulation. Int. J. Therm. Sci. 49, 281–289 (2010)
Acknowledgements
The author gratefully acknowledges the support of this research through the Marie Curie International Reintegration Grant Industrial applications of moving boundary problems Grant no. FP7-256417 and Ministerio de Ciencia e Innovación Grant MTM2011-23789.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this paper
Cite this paper
Myers, T.G. (2014). Enhanced Water Flow in Carbon Nanotubes and the Navier Slip Condition. In: Fontes, M., Günther, M., Marheineke, N. (eds) Progress in Industrial Mathematics at ECMI 2012. Mathematics in Industry(), vol 19. Springer, Cham. https://doi.org/10.1007/978-3-319-05365-3_27
Download citation
DOI: https://doi.org/10.1007/978-3-319-05365-3_27
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-05364-6
Online ISBN: 978-3-319-05365-3
eBook Packages: Mathematics and StatisticsMathematics and Statistics (R0)