Abstract
The basic steps to produce an optical metamaterial from block copolymer self-assembly can be summarized in the following: (a) self-assembly of gyroid block copolymer in thin films; (b) selective degradation and removal of one of the minor phases; (c) back filling of the so created nanoporous template via electrodeposition; (d) removal of the remaining polymer template.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Vignolini S, Yufa NA, Cunha PS, Guldin S, Rushkin I, Stefik M, Hur K, Wiesner U, Baumberg JJ, Steiner U (2012) A 3D optical metamaterial made by self-assembly. Adv Mater (Deerfield Beach, Fla.) 24(10):OP23–OP27
Knoll A, Horvat A, Lyakhova K, Krausch G, Sevink G, Zvelindovsky A, Magerle R (2002) Phase behavior in thin films of cylinder-forming block copolymers. Phys Rev Lett 89(3):035501
Crossland EJW, Ludwigs S, Hillmyer MA, Steiner U (2010) Control of gyroid forming block copolymer templates: effects of an electric field and surface topography. Soft Matter 6(3):670
Wilkes CE (2005) PVC Handbook. Hanser, Munich
Naoki S, Takeji H (1998) Ordering dynamics of a symmetric polystyrene-block-polyisoprene. Real-space analysis on the formation of lamellar microdomain. Macromolecules 3(98):3815–3823
Segalman RA (2005) Patterning with block copolymer thin films. Mater Sci Eng R: Reports 48(6):191–226
Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev 101(9):2921–2990
Kamber NE, Jeong W, Waymouth RM, Pratt RC, Lohmeijer BGG, Hedrick JL (2007) Organocatalytic ring-opening polymerization. Chem Rev 107(12):5813–5840
Zalusky AS, Olayo-Valles R, Wolf JH, Hillmyer MA (2002) Ordered nanoporous polymers from polystyrene-polylactide block copolymers. J Am Chem Soc 124(43):12761–12773
Crossland EJW, Cunha P, Ludwigs S, Hillmyer MA, Steiner U (2011) In situ electrochemical monitoring of selective etching in ordered mesoporous block-copolymer templates. ACS Appl Mater Interface 3(5):1375–1379
Barbero DR, Saifullah MSM, Hoffmann P, Mathieu HJ, Anderson D, Jones GAC, Welland ME, Steiner U (2007) High-resolution nanoimprinting with a robust and reusable polymer mold. Adv Funct Mater 17(14):2419–2425
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Salvatore, S. (2015). Gyroid Metamaterial Fabrication. In: Optical Metamaterials by Block Copolymer Self-Assembly. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-05332-5_3
Download citation
DOI: https://doi.org/10.1007/978-3-319-05332-5_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-05331-8
Online ISBN: 978-3-319-05332-5
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)