Abstract
This study investigated the removal of Cd2+, Cu2+, Ni2+, and Pb2+ from aqueous solutions with novel nanoparticle sorbents (Fe3O4, ZnO, and CuO) using a range of experimental approaches, including, pH, competing ions, sorbent masses, contact time, scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The images showed that Fe3O4, ZnO, and CuO particles had mean diameters of about 50 nm (spheroid), 25 nm (rod shape), and 75 nm (spheroid), respectively. Tests were performed under batch conditions to determine the adsorption rate and uptake at equilibrium from single and multiple component solutions. The maximum uptake values (sum of four metals) in multiple component solutions were 360.6, 114.5, and 73.0 mg g−1, for ZnO, CuO, and Fe3O4, respectively. Based on the average metal removal by the three nanoparticles, the following order was determined for single component solutions: Cd2+ > Pb2+ > Cu2+ > Ni2+, while the following order was determined in multiple component solutions: Pb2+ > Cu2+ > Cd2+ > Ni2+. Sorption equilibrium isotherms could be described using the Freundlich model in some cases, whereas other isotherms did not follow this model. Furthermore, a pseudo-second order kinetic model was found to correctly describe the experimental data for all nanoparticles. Scanning electron microscopy, energy dispersive X-ray before and after metal sorption, and soil solution saturation indices showed that the main mechanism of sorption for Cd2+ and Pb2+ was adsorption, whereas both Cu2+ and Ni2+ sorption were due to adsorption and precipitation. These nanoparticles have potential for use as efficient sorbents for the removal of heavy metals from aqueous solutions and ZnO nanoparticles were identified as the most promising sorbent due to their high metal uptake.
This article is part of the Topical Collection on Nanotechnology for Sustainable Development
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References
Abollino O, Aceto M, Malandrino M, Sarzanini C, Mentasti E (2003) Sorption of heavy metals on Na-montmorillonite effect of pH and organic substances. Water Res 38:1619–1627
Afkhami A, Moosavi R (2010) Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by maghemite nanoparticles. J Hazard Mater 174:398–403
Afkhami A, Norooz-Asl R (2009) Removal, preconcentration and determination of Mo (VI) from water and wastewater samples using maghemite nanoparticles. Colloids Surf A 346:52–57
Afkhami A, Saber-Tehrani M, Bagheri H (2010) Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2,4-dinitrophenylhydrazine. J Hazard Mater 181:836–844
Afkhami A, Bagheri H, Madrakian T (2011) Alumina nanoparticles grafted with functional groups as a new adsorbent in efficient removal of formaldehyde from water samples. Desalination 281:151–158
Ahmadzadeh Tofighy M, Mohammadi T (2011) Adsorption of divalent heavy metals ions from water using carbon nanotube sheets. J Hazard Mater 185:140–147
Allison J, Novo-Gradac K (1991) MINTEQA2/PRODEFA2, A Geochemical assessment model for Environmental system: version 3.11 databases and version 3.0. User Manual. USEPA, Environmental Research Laboratory, Athens, GA
Banerjee SS, Chen DH (2007) Fast removal of copper ions by gum Arabic modified magnetic nano-adsorbent. J Hazard Mater 147:792–799
Bian SW, Mudunkotuwa IA, Rupansinghe T, Grassian VH (2011) Aggregation and dissolution of 4 nm ZnO nanoparticles in aqueous environment: influence of pH, ionic strength, size, and adsorption of humic acid. Langmuir 27:6059–6068
Blanchard G, Maunaye M, Martin G (1984) Removal of heavy metals from waters by means of natural zeolites. Water Res 18:1501–1507
Chen YH, Li FA (2010) Kinetics study on removal of Cu2+ using goethite and hematite nano-photocatalysts. Colloid Inter Sci 347:277–281
Chen JP, Yang L (2006) Study of a previous term heavy metal next term biosorption onto raw and chemically modified Sargassum sp. via spectroscopic and modeling analysis. Langmuir 22:8906–8914
Essington ME (2004) Soil and water chemistry: an integrative approach. CRC Press, Boca Raton
Ezoddina M, Shemirania F, Abdib Kh, Khosravi Saghezchia M, Jamalic MR (2010) Application of modified nano-alumina as a solid phase extraction sorbent for the preconcentration of Cd and Pb in water and herbal samples prior to flame atomic Absorption spectrometry determination. J Hazard Mater 178:900–905
Feng Y, Gong J-L, Zeng J-MNiu Q-Y, Zhang H-Y, Niu Ch-G, Deng J-H, Yan M (2011) Adsorption of Cd (II) and Zn (II) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents. Chem Eng J 162:487–494
Flores V, Cabassud C (1999) A hybrid membrane process for Cu(II) removal from industrial wastewater, comparison with a conventional process system. Desalination 126:101–108
Ghorbel-Abid I, Jrad A, Nahdi K, Trabelsi-Ayadi M (2009) Sorption of chromium (III) from aqueous solution using bentonitic clay. Desalination 246:595–604
Hu J, Chen G, Lo MC (2006) Selective removal of heavy metals from industrial waste water using maghemite nanoparticles: performance and mechanism. J Environ Eng 132:702–715
Inglezakis VJ, Loizidou MD, Grigoropoulou HP (2003) Ion exchange of Pb2+, Cu2+, Fe3.+, and Cr3+ on natural clinoptilolite: selectivity determination and influence of acidity. J Colloid Inter Sci 261:49–54
Jalali M, Arfania H (2010) Leaching of heavy metals and nutrients from calcareous sandy-loam soil receiving municipal sewage sludge. J Plant Nutr Soil Sci 173:407–416
Jalali M, Moharrami, S (2007) Competitive adsorption of trace metals in calcareous soils of western Iran. Geoderma 140:156–163
Keyhanian F, Shariati Sh, Faraji M, Hesabi M (2011) Magnetite nanoparticles with surface modification for removal of methyl violet from aqueous solutions. Arab J Chem (in press)
Lazaridis NK, Charalambous C (2005) Sorptive removal of trivalent and hexavalent chromium from binary aqueous solutions by composite alginate–goethite beads. Water Res 39:4385–4396
Martinson CA, Reddy KJ (2009) Adsorption of arsenic(III) and arsenic(V) by cupric oxide nanoparticles. J Colloid Inter Sci 336:406–411
McBridge MB (1994) Environmental chemistry of soils. Oxford University Press, New York
Mobasherpour I, Salahi E, Pazouki M (2011a) Removal of nickel (II) from aqueous solutions by using nano-crystalline calcium hydroxyapatite. J Saudi Chem Soc 15:105–112
Mobasherpour I, Salahi E, Pazouki M (2011b) Removal of divalent cadmium cations by means of synthetic nanocrystallite hydroxyapatite. Desalination 266:142–148
Nagappa B, Chandrappa GT (2007) Mesoporous nanocrystalline magnesium oxide for environmental remediation. Microporous Mesoporous Mater 106:212–218
Navrotsky A (2000) Nanomaterials in the environment, agriculture, and technology (NEAT). J Nanoparticles Res 2:321–323
Ok YS, Yang JE, Zhang Y-S, Kim SJ, Chung DY (2007) Heavy metal adsorption by a formulated zeolite-portland cements mixture. J Hazard Mater 147:91–96
Panayotova M, Velikov B (2002) Kinetics of heavy metal ions removal by use of natural zeolite. J Environ Sci Health Part A 37:139–147
Panneerselvam P, Morad N, Tan KA (2011) Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel (II) from aqueous solution. J Hazard Mater 186:160–168
Pederson AJ (2002) Evaluation of assisting agents for electrodialytic removal of Cd, Pb, Zn, Cu and Cr from MSWI fly ash. J Hazard Mater B95:185–198
Rahmani A, Zavvar Mosavi H, Fazli M (2010) Effect of nanostructure alumina on adsorption of heavy metals. Desalination 253:94–100
Recillas S, García A, González E, Casals E, Puntes V, Sánchez A, Font X (2011) Use of CeO2, TiO2 and Fe3O4 nanoparticles for the removal of lead from water: toxicity of nanoparticles and derived compounds. Desalination 277:213–220
Rezaei M, Khajenoori M, Nematollahi B (2011) Preparation of nanocrystalline MgO by surfactant assisted precipitation method. Mater Res Bull 46:1632–1637
Savage N, Diallo MS (2005) Nanomaterials and water purification : opportunities and challenges. J Nanoparticles Res 7:331–342
Sharma YC, Srivastava V (2010) Separation of Ni (II) ions from aqueous solutions by magnetic nanoparticles. J Chem Eng Data 55:1441–1442
Sheng P, Ting YP, Chen JP, Hong L (2004) Sorption of lead, copper, cadmium, zinc, and nickel by marine algal biomass: characterization of biosorptive capacity and investigation of mechanisms. J Colloid Inter Sci 275:131–141
Singh J, Im J, Whitten JE, Soares JW, Steeves DM (2010) Chemisorption of a thiol-functionalized ruthenium dye on zinc oxide nanoparticles: implications for dye-sensitized solar cells. Chem Phys Lett 497:196–199
Song J, Kong H, Jang J (2011) Adsorption of heavy metal ions from aqueous solution by polyrhodanine-encapsulated magnetic nanoparticles. J Colloid Inter Sci 359:505–511
Vidal M, Santos MJ, Abrao T, Rodriguez J, Rigol A (2009) Modeling competitive metal sorption in a mineral soil. Geoderma 149:189–198
Wingenfelder U, Hansen C, Furrer G, Schulin R (2005) Removal of heavy metals from mine waters by natural zeolites. Environ Sci Technol 39:4606–4613
Yantasee W, Warner CL, Sangvanich T, Addleman RS, Carter TG, Wiacek RG, Fryxell GE, Timchalk C, Warner MG (2007) Removal of heavy metals from aqueous systems with thiol functionalized superparamagnetic nanoparticles. Environ Sci Technol 41:5114–5119
Zhang Y, Chen Y, Westerhoff P, Hristovski K, Crittenden JC (2008) Stability of commercial metal oxide nanoparticles in water. Water Res 42:2204–2212
Zhou YT, White CB, Nie HL, Zhu LM (2009) Adsorption mechanism of Cu 2+ from solution by chitosan-coated magnetic nanoparticles modified with α-ketoglutaric acid. Colloids Sur B 74:244–252
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Special Issue Editors: Mamadou Diallo, Neil Fromer, Myung S. Jhon
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Mahdavi, S., Jalali, M., Afkhami, A. (2012). Removal of heavy metals from aqueous solutions using Fe3O4, ZnO, and CuO nanoparticles. In: Diallo, M.S., Fromer, N.A., Jhon, M.S. (eds) Nanotechnology for Sustainable Development. Springer, Cham. https://doi.org/10.1007/978-3-319-05041-6_14
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DOI: https://doi.org/10.1007/978-3-319-05041-6_14
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