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Trends in Biodiesel Production: Present Status and Future Directions

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Biofuels in Brazil

Abstract

The use of renewable fuels, an alternative that reduces the generation of greenhouse gases, is one proposal to mitigate the effects that contribute to global warming. Brazil is the fourth largest producer of biodiesel in the world, and growth expectations of the productive capacities have generated huge technological and environmental challenges. In this context, this chapter discusses some of the relevant aspects of biodiesel production in Brazil, including sustainability of raw materials, conventional technology limitations, and further presents technological alternatives as strategies that will guide the future directions which can result in processes with greater environmental and economic returns.

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References

  • Abo El-Enin SA, Attia NK, El-Ibiari NN et al (2013) In-situ transesterification of rapeseed and cost indicators for biodiesel production. Renew Sustain Energy Rev 18:471–477

    Article  CAS  Google Scholar 

  • Ali OM, Mamat R, Faizal CKM (2013) Review of the effects of additives on biodiesel properties, performance, and emission features. J Renew Sustain Energy 5:012701. doi.org/10.1063/1.4792846

  • Andrade GSS, Freitas L, Oliveira PC et al (2012a) Screening, immobilization and utilization of whole cell biocatalysts to mediate the ethanolysis of babassu oil. J Mol Catal B-Enzym 84:183–188

    Article  CAS  Google Scholar 

  • Andrade RDA, Pozzebom E, Faria EA et al (2012b) Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil. Acta Sci Technol 34(2):243–248

    CAS  Google Scholar 

  • ANP—National Agency of Petroleum, Natural Gas and Biofuels (2013) http://www.anp.gov.br/?pg=67205&m=anuario&t1=&t2=anuario&t3=&t4=&ar=0&ps=1&cachebust=1376640163560. Accessed in 16 Aug 2013

  • Basha SA, Gopal KR, Jebaraj S (2009) A review on biodiesel production, combustion, emissions and performance. Renew Sustain Energy Rev 13:1628–1634

    Article  CAS  Google Scholar 

  • Batistella L, Lerin LA, Brugnerotto P et al (2012) Ultrasound-assisted lipase-catalyzed transesterification of soybean oil in organic solvent system. Ultrason Sonochem 19(3):452–458

    Article  PubMed  CAS  Google Scholar 

  • Beck J (2013) Predicting climate change effects on agriculture from ecological niche modeling: who profits, who loses? Clim Chan 116:177–189

    Article  Google Scholar 

  • Bergmann JC, Tupinambá DD, Costa OYA et al (2013) Biodiesel production in Brazil and alternative biomass feedstocks. Renew Sustain Energy Review 21:411–420

    Article  Google Scholar 

  • BiodieselBR (2013) http://www.biodieselbr.com. Accessed in 16 Aug 2013

  • Borges ME, Díaz L (2012) Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review. Renew Sust Renew Energ Rev 16(5):2839–2849

    Article  CAS  Google Scholar 

  • Borges LD, Moura NN, Costa AA et al (2013) Investigation of biodiesel production by HUSY and Ce/HUSY zeolites: Influence of structural and acidity parameters. Appl Catal A 450:114–119

    Article  CAS  Google Scholar 

  • Bournay L, Casanave D, Delfort B et al (2005) New heterogeneous process for biodiesel production: A way to improve the quality and the value of the crude glycerin produced by biodiesel plants. Catal Today 106(1–4):190–192

    Article  CAS  Google Scholar 

  • Brito YC, Ferreira DAC, de Fragoso DMA et al (2012) Simultaneous conversion of triacylglycerides and fatty acids into fatty acid methyl esters using organometallic tin(IV) compounds as catalysts. Appl Catal A Gen 443–444:202–206

    Google Scholar 

  • Brunschwig C, Moussavou W, Blin J (2012) Use of bioethanol for biodiesel production. Prog Energy Combust Sci 38:283–301

    Article  CAS  Google Scholar 

  • Cardona CA, Posada J, Quintero JA (2010) Aprovechamiento de subproductos y residuos agroindustriales: glicerina y lignocelulósicos. Universidad Nacional de Colombia, Sede Manizales. ISBN 978-95-44-7611-1

    Google Scholar 

  • Castro M, Machado F, Rocha A, Perez VH et al (2011) Characterization of biodiesel by unconventional methods: phothermal techniques, biodiesel- quality, emissions and by products—Intech. ISBN 978-953-307-784-0

    Google Scholar 

  • CENBIO (2013) Brazilian center of biomass reference. http://www.cenbio.iee.usp.br. Accessed in 16 Aug 2013

  • Chisti Y (2007) Biodiesel from microalgae. Biotechnol Adv 25(3):294–306

    Article  PubMed  CAS  Google Scholar 

  • Crespo AMR (2013) Detecção de Gases Poluentes e Avaliação das Propriedades Térmicas e Reológicas das Misturas Binárias (Diesel e Biodiesel) Tese-Universidade Estadual do Norte Fluminense Darcy Ribeiro

    Google Scholar 

  • Da Rós PCM, Silva CSP, Silva-Stenico ME et al (2012a) Microcystis aeruginosa lipids as feedstock for biodiesel synthesis by enzymatic route. J Mol Catal B Enzym 84:177–182

    Article  Google Scholar 

  • Da Rós PC, de Castro HF, Carvalho AKF et al (2012b) Microwave-assisted enzymatic synthesis of beef tallow biodiesel. J Ind Microbiol Biotechnol 39(4):529–536

    Article  PubMed  Google Scholar 

  • Da Rós PCM, Freitas L, Perez VH et al (2013) Enzymatic synthesis of biodiesel from palm oil assisted by microwave irradiation. Bioprocess Biosyst Eng 36:443–451

    Article  PubMed  Google Scholar 

  • Da Silva de NL, Garnica JAG, Batistella CB et al (2011) Use of experimental design to investigate biodiesel production by multiple-stage Ultra-Shear reactor. Bioresour Technol 102 (3):2672–2677

    Google Scholar 

  • da Silva G, Mack M, Contiero J (2009) Glycerol: A promising and abundant carbon source for industrial microbiology. Biotechn Adv 27(1):30–39

    Article  Google Scholar 

  • Da Silva NL, Martinez EL, Rios LF et al (2012) Comparative study of simulations and experimental results of biodiesel production using two types of reactive distillation columns. In: Bogle IDL, Fairweather M (eds) Computer Aided Chemical Engineering, vol 30. Elsevier, Amsterdam, pp 107–111

    Google Scholar 

  • Dantas J, Santos JRD, Cunha RB et al (2013) Use of Ni–Zn ferrites doped with Cu as catalyst in the transesterification of soybean oil to methyl esters. Mater Res 16(3):625–627

    Article  CAS  Google Scholar 

  • de Carvalho LMG, de Abreu WC, e Silva MGO et al (2013) Heterogeneous catalysis afford biodiesel of babassu, castor oil and blends. J Braz Chem Soc 24(4):550–557

    Google Scholar 

  • de Galvão LPFC, Barbosa MN, Araujo AS et al (2012) Iodeto de potássio suportado em peneiras moleculares mesoporosas (sba-15 e mcm-41) como catalisador básico para síntese de biodiesel. Quim Nova 35(1):41–44

    Google Scholar 

  • de Mattos FCG, de Souza JA da S, do Cotrim ABA et al (2012) Lewis acid/surfactant rare earth trisdodecylsulfate catalysts for biodiesel production from waste cooking oil. Appl Catal A Gen 423–424:1–6

    Google Scholar 

  • Demirbas A, Demirbas MF (2011) Importance of algae oil as a source of biodiesel. Energ Convers Manag 52(1):163–170

    Article  Google Scholar 

  • do Amaral FB, Broetto F, Batistella CB et al (2011) Extração e Caracterização Qualitativa do Óleo de Polpa e Amêndoas. Rev Energ Agric 26 (1):12–20

    Google Scholar 

  • do Nascimento LAS, Angélica RS, da Costa CEF et al (2011) Conversion of waste produced by the deodorization of palm oil as feedstock for the production of biodiesel using a catalyst prepared from waste material. Bioresour Technol 102(17):8314–8317

    Google Scholar 

  • Doná G, Cardozo-Filho L, Silva C et al (2013) Biodiesel production using supercritical methyl acetate in a tubular packed bed reactor. Fuel Process Technol 106:605–610

    Article  Google Scholar 

  • Dussan KJ, Cardona CA, Giraldo OH et al (2010) Analysis of a reactive extraction process for biodiesel production using a lipase immobilized on magnetic nanostructures. Bioresour Technol 101(24):9542–9549

    Article  PubMed  CAS  Google Scholar 

  • Elbehri A; Segerstedt A, Liu P (2013) Biofuels and the sustainability challenges: A global assessment of sustainability issues, trends and policies for biofuels and related feedstocks. Food and Agriculture Organization of The United Nations (FAO), ROME

    Google Scholar 

  • Endalew AK, Kiros Y, Zani R (2011) Inorganic heterogeneous catalysts for biodiesel production from vegetable oils. Biomass Bioenerg 35(9):3787–3809

    Article  CAS  Google Scholar 

  • Evangelista JPC, Chellappa T, Coriolano ACF et al (2012) Synthesis of alumina impregnated with potassium iodide catalyst for biodiesel production from rice bran oil. Fuel Process Technol 104:90–95

    Article  CAS  Google Scholar 

  • Farooq M, Ramli A, Subbarao D (2013) Biodiesel production from waste cooking oil using bifunctional heterogeneous solid catalysts. J Clean Prod 59:131–140. doi:10.1016/j.jclepro.2013.06.015

    Google Scholar 

  • Ferrari RA, de Azevedo Filho JA (2012) Macauba as Promising substrate for crude oil and biodiesel production. J Agri Sci Technol B 2:1119–1126

    CAS  Google Scholar 

  • Focke WW, van der Westhuizen ISBE, Grobler ABL et al (2012) The effect of synthetic antioxidants on the oxidative stability of biodiesel. Fuel 94:227–233

    Article  CAS  Google Scholar 

  • Freitas L, Da Rós PCM, Santos JC et al (2009) An integrated approach to produce biodiesel and monoglycerides by enzymatic interestification of babassu oil (Orbinya sp). Process Biochem 44(10):1068–1074

    Article  CAS  Google Scholar 

  • Gallagher BJ (2011) The economics of producing biodiesel from algae. Renew Energy 36(1):158–162

    Article  CAS  Google Scholar 

  • Gog A, Roman M, Tosa M et al (2012) Biodiesel production using enzymatic transesterification—current state and perspectives. Renew Energ 39(1):10–16

    Article  CAS  Google Scholar 

  • Guimarães AO, Machado FAL, Zanelato EB et al (2009) Photopyroelectric methodology applied to thermal characterization of biodiesel. Inter Rev Chem Eng 1(6):623–663

    Google Scholar 

  • Guzatto G, de Martini TL, Samios D (2011) The use of a modified TDSP for biodiesel production from soybean, linseed and waste cooking oil. Fuel Process Technol 92(10):2083–2088

    Article  CAS  Google Scholar 

  • Hassan MHJ, Kalam MDA (2013) An overview of biofuel as a renewable energy source: development and challenges. Procedia Eng 56:39–53

    Article  Google Scholar 

  • Hossain AK, Davies PA (2013) Pyrolysis liquids and gases as alternative fuels in internal combustion engines—a review. Renew Sustain Energy Rev 21:165–189

    Article  CAS  Google Scholar 

  • IPCC—Intergovernmental Panel on Climate Change (2007) Report of working group III, climate change: mitigation of climate change, Bangkok

    Google Scholar 

  • Islam A, Taufiq-Yap HY, Chu CH et al (2013) Studies on design of heterogeneous catalysts for biodiesel production. Process Saf Environ Prot 91(1–2):131–144

    Article  CAS  Google Scholar 

  • Jang MG, Kim DK, Park SC et al (2012) Biodiesel production from crude canola oil by two-step enzymatic processes. Renew Energy 42:99–104

    Article  CAS  Google Scholar 

  • Kamat S, Khot M, Zinjarde S et al (2013) Coupled production of single cell oil as biodiesel feedstock, xylitol and xylanase from sugarcane bagasse in a biorefinery concept using fungi from the tropical mangrove wetlands. Bioresour Technol 135:246–253

    Article  PubMed  CAS  Google Scholar 

  • Kerr RA (2013) Soot is warming the world even more than thought. Science 339(6118):282

    Article  Google Scholar 

  • Knothe G (2006) Analyzing Biodiesel: Standards and Other Methods. J Am Oil Chem Soc 83(10):823–833

    Article  CAS  Google Scholar 

  • Knothe G, Krahl J, Van Gerpen J et al (2005) The biodiesel handbook, 2nd edn. AOCS Press, Urbana

    Book  Google Scholar 

  • Leoneti AB, Aragão-Leoneti V, de Oliveira SVWB (2012) Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol. Renew Energy 45:138–145

    Article  CAS  Google Scholar 

  • Levenspiel O (1999) Chemical reaction engineering, 3rd edn. Wiley, New York

    Google Scholar 

  • Lian J, Garcia-Perez M, Coates R et al (2012) Yeast fermentation of carboxylic acids obtained from pyrolytic aqueous phases for lipid production. Bioresour Technol 118:177–186

    Article  PubMed  CAS  Google Scholar 

  • Lian J, Garcia-Perez M, Chen S (2013) Fermentation of levoglucosan with oleaginous yeasts for lipid production. Bioresour Technol 133:183–189

    Article  PubMed  CAS  Google Scholar 

  • Lima SM, Figueiredo MS, Andrade LHC et al (2009) Effects of residue and antioxidant on thermo-optical properties of biodiesel. Appl Opt 48(30):5728–5732

    Article  PubMed  CAS  Google Scholar 

  • Liu CH, Huang CC, Wang YW et al (2012) Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles. Appl Energ 100:41–46

    Article  CAS  Google Scholar 

  • Macedo FL, Candeia RA, Sales LLM et al (2011a) Thermal characterization of oil and biodiesel from oiticica (Licania rigidaBenth). J Therm Anal Calorim 106:531–534

    Article  CAS  Google Scholar 

  • Macedo AL, Santos RS, Pantoja L et al (2011b) Pequi cake composition, hydrolysis and fermentation to bioethanol. Braz J Chem Eng 28(1):9–15

    Article  CAS  Google Scholar 

  • Meher LC, Sager DV, Naik SN (2006) Technical aspects of biodiesel production by transesterification - a review. Renew Sustain Energy Rev 10(3):248–268

    Article  CAS  Google Scholar 

  • Monteiro MR, Ambrozin ARP, Liao LM et al (2008) Critical review on analytical methods for biodiesel characterization review. Talanta 77(2):593–605

    Article  CAS  Google Scholar 

  • Nagarajan S, Chou SK, Cao S et al (2012) An updated comprehensive techno-economic analysis of algae biodiesel. Bioresour Technol 145:150–156

    Article  PubMed  Google Scholar 

  • Nascimento UM, Vasconcelos ACS, Azevedo EB (2009) Otimização da produção de biodiesel a partir de óleo de coco babaçu com aquecimento por micro-ondas. Eclet Quim 34(4):37–48

    Google Scholar 

  • Ngo TPN, Li A, Tiew KW et al (2013) Efficient transformation of grease to biodiesel using highly active and easily recyclable magnetic nanobiocatalyst aggregates. Bioresour Technol 145:233–239

    Article  PubMed  CAS  Google Scholar 

  • Nogueira BM, Carretoni C, Cruz R et al (2010) Microwave activation of enzymatic catalysts for biodiesel production. J Mol Catal B Enzym 67(1–2):117–121

    Article  CAS  Google Scholar 

  • Pahl G (2008) Biodiesel: growing a new energy economy, 2nd edn. Chelsea Green Publishing Company, White River Junction

    Google Scholar 

  • Queiroz AG, França L, Ponte MX (2012) The life cycle assessment of biodiesel from palm oil (“dendê”) in the Amazon. Biomass Bioenerg 36:50–59

    Article  CAS  Google Scholar 

  • Quintella SA, Saboya RMA, Salmin DC et al (2012) Transesterificarion of soybean oil using ethanol and mesoporous silica catalyst. Renew Energy 38(1):136–140

    Article  CAS  Google Scholar 

  • Quispe CAG, Coronado CJR, Carvalho Jr JA (2013) Glycerol: Production, consumption, prices, characterization and new trends in combustion. Renew Sust Energy Rev 27:475–493

    Google Scholar 

  • REN21 (2013) Renewables 2013 global status report (Paris: REN21 Secretariat). http://www.ren21.net/portals/0/documents/resources/gsr/2013/gsr2013_lowres.pdf. Accessed 16 Aug 2013

  • Rodrigues S, Mazzone LCA, Santos FFP et al (2009) Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol. Braz J Chem Eng 26(2):361–366

    Article  CAS  Google Scholar 

  • Sallet CL, Alvim AM (2011) Biocombustíveis: uma análise da evolução do biodiesel no Brasil. Econ Tec 25:1–13

    Google Scholar 

  • Salum TFC, Villeneuve P, Barea B et al (2010) Synthesis of biodiesel in column fixed-bed bioreactor using the fermented solid produced by Burkholderia cepacia LTEB11. Process Biochem 45(8):1348–1354

    Article  CAS  Google Scholar 

  • Sauer IL, de Queiroz MS, Miragaya JCG et al (2006) Energias renováveis: ações e perspectivas na Petrobras. Bahia Análise & Dados 16(1):9–22

    Google Scholar 

  • Semwal S, Arora AK, Badoni RP et al (2011) Biodiesel production using heterogeneous catalysts. Bioresour Technol 102(3):2151–2161

    Article  PubMed  CAS  Google Scholar 

  • Sepulveda JH, Vera CR, Yori JC et al (2011) H3PW12O40 (HPA), an efficient and reusable catalyst for biodiesel production related reactions: esterification of oleic acid and etherification of glycerol. Quim Nova 34(4):601–606

    Article  CAS  Google Scholar 

  • Stelmachowski M (2011) Utilization of glycerol, a by-product of the transesterification process of vegetable oils: a review. Ecol Eng 18:9–30

    CAS  Google Scholar 

  • Sthel MS, Tavares JR, Lima GR et al (2009) Atmospheric pollution: global warming and a possible use of bio-fuels in a wide scale. Int Rev Chem Eng 1(6):564–570

    Google Scholar 

  • Suarez PAZ, da Silva FM (2012) Development of a Lewis-based catalytic system for biodiesel production: from a batch laboratory scale to a continuous pilot plant. J Braz Chem Soc 23(7):1201–1208

    Article  CAS  Google Scholar 

  • Tan T, Lu J, Nie K et al (2011) Biodiesel production with immobilized lipase: a review. Biotechnol Adv 28(5):628–634

    Article  Google Scholar 

  • Tan HW, Aziz ARA, Aroua MK (2013) Glycerol production and its applications as a raw material: A review. Renew Sust Energy Rev 27:118–127

    Article  CAS  Google Scholar 

  • Teixeira LSG, Assis JCR, Mendonça DR et al (2009) Comparison between conventional and ultrasonic preparation of beef tallow biodiese. Fuel Process Technol 90(8):1164–1166

    Article  CAS  Google Scholar 

  • Torres CM, Ríos SD, Torras C et al (2013) Microalgae-based biodiesel: a multicriteria analysis of the production process using realistic scenarios. Bioresour Technol 147:7–16

    Article  PubMed  CAS  Google Scholar 

  • Trentin CM, Lima AP, Alkimim IP et al (2011) Continuous production of soybean biodiesel with compressed ethanol in a microtube reactor using carbon dioxide as co-solvent. Fuel Process Technol 92(5):952–958

    Article  CAS  Google Scholar 

  • Vargas-Lopez JM, Wiesenborn D, Tostenson K et al (1999) Processing of Crambe for Oil and Isolation of Erucic Acid. JAOCS 76(7):801–809

    CAS  Google Scholar 

  • Ventura M, Simionatto E, Andrade LH et al (2012) Thermal lens spectroscopy for the differentiation of biodiesel-diesel blends. Rev Sci Instrum 83(4):043902–043902-5

    Google Scholar 

  • Wang X, Xueying L, Chuanming Z et al (2011) Biodiesel production in packed-bed reactors using lipase–nanoparticle biocomposite. Bioresour Technol 102(10):6352–6355

    Article  PubMed  CAS  Google Scholar 

  • Xu J, Zhao X, Wang W et al (2012) Microbial conversion of biodiesel byproduct glycerol to triacylglycerols by oleaginous yeast Rhodosporidium toruloides and the individual effect of some impurities on lipid production. Biochem Eng J 65:30–36

    Article  CAS  Google Scholar 

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Acknowledgments

We are grateful to the Rio de Janeiro Research Foundation (FAPERJ) and The National Council for Scientific and Technological Development (CNPq) for the financial support.

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Perez, V.H. et al. (2014). Trends in Biodiesel Production: Present Status and Future Directions. In: da Silva, S., Chandel, A. (eds) Biofuels in Brazil. Springer, Cham. https://doi.org/10.1007/978-3-319-05020-1_13

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