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Organic Properties and Hydrocarbon Generation Potential of Shales from Few Sedimentary Basins of India

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Book cover Petroleum Geosciences: Indian Contexts

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Abstract

Shales form the principal source rock for most of the conventional and unconventional petroleum systems. In India, both the prolific and prospective sedimentary basins have excellent to fair development of shales that range in age from the Proterozoic to Cenozoic. Deposition, preservation and maturation of organic content in shales define the source rock characteristics and its hydrocarbon generation potential, leading to a prolific/non prolific oil and gas play. Useful insight on development and hydrocarbon generation potential of shales and other organic rich source rocks is obtained through the geochemical study of sedimentary organic matter. In the present work, organic richness, kerogen type and thermal maturity of potential shales from few sedimentary basin of India, namely—Vindhyan, Krishna-Godavari, Kutch, Cambay and Jammu and Kashmir have been studied, to understand their effectiveness as source rocks in the particular basins. The studied shales show high Total organic carbon (TOC) content and contain dominantly Type III kerogen with partial contributions from Type II, in varying stages of hydrocarbon generation from immature to post mature, depending upon the thermal history of respective basins. Quantitative approaches involving the use of kinetic parameters for thermal cracking of organic matter (kerogen) into hydrocarbons, in conjunction with the source rock quality can account for improved understanding of the hydrocarbon resources in these basins.

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References

  • Allan J, Douglas AG (1977) Variations in the content and distribution of n-alkanes in a series of carboniferous vitrinites and sporinites of bituminous rank Geochim. Cosmochim Acta 41:1223–1230

    Article  Google Scholar 

  • Banerjee A, Pahari S, Jha M, Sinha AK, Jain AK, Kumar N, Thomas NJ, Misra KN, Chandra K (2002) The effective source rocks in the Cambay basin. India. AAPG Bull 86(3):433–456

    Google Scholar 

  • Banerjee S, Dutta S, Paikaray S, Mann U (2006) Stratigraphy, sedimentology and bulk organic geochemistry of black shales from the Proterozoic Vindhyan Supergroup, Central India. J Earth Syst Sci 115(1):37–47

    Article  Google Scholar 

  • Behar F, Penteado V, Beaumont HL, De B (2001) Rock-Eval 6 technology: performances and developments. Oil Gas Sci Technol—Rev IFP 56(2):111–134

    Article  Google Scholar 

  • Bhalla SN (1968) Paleoecology of the Raghavapuram Shales (Early Cretaceous), East Coast Gondwanas, India. Palaeogeogr Palaeoclimatol Palaeoecol 5(4):345–357

    Article  Google Scholar 

  • Bhowmick PK, Misra R (2012) Indian oil and gas potential. In: Banerjee DM, Singhvi AR (eds) Proceedings of the INSA glimpses of geoscience research in India, vol 78, pp 218–228

    Google Scholar 

  • Biswas SK (1992) Tertiary stratigraphy of Kutch. J Palaeontol Soc India 37:1–29

    Google Scholar 

  • Brooks JD, Smith JW (1967) The diagenesis of plant lipids during the formation of coal, petroleum and natural gas-I. Changes in the n- paramhydrocarbons. Geochim Cosmochim Acta 31:2389–2397

    Article  Google Scholar 

  • Chandra K, Raju DSN, Bhandari A, Mishra CS (2001) Petroleum systems in the Indian sedimentary basins: stratigraphic and geochemical perspectives. Bull Oil Nat Gas Corp 38(1):1–45

    Google Scholar 

  • Dayal AM, Mani Devleena, Mishra Snigdharani, Patil DJ (2013) Shale Gas prospects of the Cambay Basin, Western India. Geohorizon 18(1):26–31

    Google Scholar 

  • Dayal AM, Mani D, Madhavi T, Kavitha S, Kalpana MS, Patil DJ, Sharma M (2014) Organic geochemistry of Vindhyan sediments: implications for hydrocarbons. J Asian Earth Sci 91:329–338

    Article  Google Scholar 

  • Didyk BM, Simoneit BRT, Brassell SC, Eglinton G (1978) Organic geochemical indicators of palaeoenvironmental conditions of sedimentation. Nature 272:216–222

    Article  Google Scholar 

  • Directorate General of Hydrocarbons (DGH) (2014) Retrieved from www.dghindia.org

  • Dutta S, Steiner M, Banerjee S, Erdtmann B, JeevanKumar S, Mann U (2006) Chuaria circularis from the early Mesoproterozoic Suket Shale, Vindhyan Supergroup, India: insights from light and electron microscopy and pyrolysis–gas chromatography. J Earth Syst Sci 115(1):99–112

    Article  Google Scholar 

  • Dutta S, Mathews RP, Singh BH, Tripathi SM, Singh A, Saraswati PK, Banerjee S, Mann U (2011) Petrology, palynology and organic geochemistry of Eocene lignite of Matanomadh, Kutch Basin, Western India: Implications to depositional environment and hydrocarbon source potential. Int J Coal Geol 85:91–102

    Article  Google Scholar 

  • Eden H, Mungo D (2013) Geochemistry-the dark horse upstream. GeoExpro 10(1):22–25

    Google Scholar 

  • Espitalie J, Marquis F, Sage L (1987) Organic geochemistry of the Paris Basin. In: Brooks J, Glennie K (eds) Petroleum geology of north west Europe. Graham and Totman, London, pp 71–86

    Google Scholar 

  • Fuex AN (1977) The use of stable carbon isotope in hydrocarbon exploration. J Geochem Explor 7:155–188

    Article  Google Scholar 

  • Grob RL (2004) Theory of chromatography. In: Grob RL, Barry EF (eds) Modern practice of gas chroamtography, 4th edn. Willy, New York, 743p

    Google Scholar 

  • Gupta SK (2006) Basin architecture and petroleum system of Krishna-Godavari basin, east coast of India. Lead Edge 25(7):830–837

    Article  Google Scholar 

  • Horvitz L (1985) Geochemical exploration for petroleum. Science 229(4716):821–827

    Article  Google Scholar 

  • Hunt JM (1996) Petroleum geochemistry and geology, 2nd edn. W.H. Freeman and company, USA, 715p

    Google Scholar 

  • Jiang C, Alexander R, Kagi RI, Murray AP (1998) Polycyclic aromatic hydrocarbons in ancient sediments and their relationships to palaeoclimate. Org Geochem 29(5–7):1721–1735

    Article  Google Scholar 

  • Jokhan Ram J (2005) Hydrocarbon exploration in onland frontier basins of India: perspective and challenges. J Palaeontol Soc India 50(1):1–16

    Google Scholar 

  • Jones RW, Demaison GJ (1982) Organic facies-stratigraphic concept and exploration tool. In: Salvidar-Sali A (ed) Proceedings of the second ASCOPE conference and exhibition, Manila, Oct 1981, pp 51–68

    Google Scholar 

  • Jones RW (1983) Organic matter characteristics near the shelf-slope boundary. Soc Econ Paleontol Mineral (SEPM) 33:391–405 (special publication)

    Google Scholar 

  • Karunakaran C, Ranga Rao A (1979) Status of exploration for hydrocarbon in the Himalayan region—contributions to stratigraphy and structure. In: Proceeding of Himalayan geology seminar, 13–17 Sept 1979. Miscellaneous publications no 41, Part V, vol 1–6(6). Geological Survey of India, New Delhi

    Google Scholar 

  • Killops SD, Massoud MS (1992) Polycyclic aromatic hydrocarbons of pyrolytic origin in ancient sediments: evidence for Jurassic vegetation fires. Org Geochem 18(1):1–7

    Article  Google Scholar 

  • Kumar B, Raju SV, Patil DJ, Kalpana G, Vishnu Vardhan C (2006) Integrating surface geochemical expressions with geological, geophysical and remote sensing data: case histories from selected Proterozoic Basins of India. http://www.searchanddiscovery.com/documents/2006/06088houston_abs/abstracts/kumar.htm, downloaded on 16 Dec 2012

  • Lafargue E, Marquis F, Pillot D (1988) Rock-Eval 6 applications in hydrocarbon exploration, production and soil contamination studies, vol 53(4). In: Juillet-Août (1998). IFP, Pondicherry

    Google Scholar 

  • Lakshminarayana G (2002) Evolution in Basin Fill Style during the Mesozoic Gondwana Continental break-up in the Godavari Triple Junction, SE India. Gondwana Res 5(1):227–244

    Google Scholar 

  • Mani D, Patil DJ, Dayal AM (2011a) Stable carbon isotope geochemistry of near surface adsorbed alkane gases in Saurashtra basin. Chemical Geology 280(1–2):144–153

    Article  Google Scholar 

  • Mani D, Dayal AM, Rasheed MA, Satish Kumar T, Rao TG, Balaram V (2011b) Soil Iodine determination in Deccan Syneclise Basin of India: implications for near surface geochemical hydrocarbon prospecting. Nat Resour Res 20(1):75–88

    Article  Google Scholar 

  • Mani D, Ratnam B, Patil DJ, Kalpana MS, Dayal AM (2012a) Geochemical proxies for the interpretation of sedimentary paleoenvironment: preliminary results from Krishna Godavari basin, India. In: IGCP-3rd annual symposium response of asian rivers to climate change—past, present and future scenario, 14–16 Nov 2012. CSIR-National Geophysical Research Institute, Hyderabad

    Google Scholar 

  • Mani D, Patil DJ, Kalpana MS, Dayal AM (2012b) Evaluation of hydrocarbon prospects using surface geochemical data with constraints from geological and geophysical observations in Jamnagar area, Saurashtra Basin, India. J Pet Geol 35(1):67–84

    Article  Google Scholar 

  • Mani D, Patil DJ, Dayal AM (2013) Evolution of sedimentary organic matter and formation of oil and gas: a geochemical approach. In: International seminar on earth science for society, 7–8 Dec 2012. CSIR-National Geophysical Research Institute, Hyderabad

    Google Scholar 

  • Mani D, Dayal AM, Patil DJ, Hafiz M, Hakoo N, Bhat GM (2014) Gas potential of Proterozoic and Phanerozoic shales from NW Himalaya, India: inferences from new pyrolysis data. Int J Coal Geol 128–129:81–95

    Article  Google Scholar 

  • Mani D, Ratnam B, Patil DJ, Kalpana MS, Dayal AM (2015) Elemental and organic matter characteristics of the Gondwana sediments from the Krishna–Godavari Basin, India. Chemie der Erde-Geochemistry (accepted)

    Google Scholar 

  • Misra SR, Mani D, Kavita S, Kalpana MS, Patil DJ, Vyas DU, Dayal AM (2013a) Organic matter characteristics and gas generation potential of the Tertiary shales from the NW Kutch basin, India. J Pet Sci Eng (under review)

    Google Scholar 

  • Misra SR, Mani D, Kavita S, Patil DJ, Kalpana MS, Dayal AM (2013b) Pyrolysis results of shales from the South Cambay basin, India: implications for gas generation potential. J Geol Soc India (accepted article)

    Google Scholar 

  • Mittal AK, Pandey HC, Singh RR (2006) Geochemistry of gas seeps from surface shows and wells of the Himalayan foreland Basin. In: Proceedings of 6th international conference and exposition on petroleum geophysics, Kolkata, pp 235–291

    Google Scholar 

  • Nagori ML, Khosla SC, Jakhar SR (2013) Middle Eocene Ostracoda from the Tadkeshwar Lignite Mine, Cambay Basin, Gujarat. JGeol Soc India 81:514–520

    Article  Google Scholar 

  • Ojha PS (2012) Precambrian sedimentary basins of India: an appraisal of their petroleum potential. In: Bhat G, Craig J, Thurow JW, Thusu B, Cozzi A (eds) Geology and hydrocarbon potential of Neoproterozoic–Cambrian Basins in Asia, vol 366. Geological Society, London. doi: 10.1144/sp366.11 (special publications)

  • Patil DJ, Mani D, Madhavi T, Sudarshan V, Srikarni C, Kalpana MS, Sreenivas B, Dayal AM (2013) Near surface hydrocarbon prospecting in Mesozoic Kutch sedimentary basin, Gujarat, Western India–A reconnaissance study using geochemical and isotopic approach. J Pet Sci Eng 108:393–403

    Article  Google Scholar 

  • Peters K (1986) Guidelines for evaluating petroleum source rocks using programmed pyrolysis. Am Assoc Pet Geol 70:318–329

    Google Scholar 

  • Peters KE, Cassa MR (1994) Applied source rock geochemistry. In: Magoon LB, Dow WG (eds) The petroleum system—from source to trap: Tulsa, Okla. Am Assoc Pet Geol Memoir 60:93–117

    Google Scholar 

  • Peters KE, Moldowan JM (1993) The biomarker guide—interpreting molecular fossils in petroleum and ancient sediments. Prentice Hall, New Jersey

    Google Scholar 

  • Peters KE, Walters CC, Moldowan JM (2005) The biomarker guide: biomarkers and isotopes in the environment and human history, vol 1. Cambridge Press, Cambridge

    Google Scholar 

  • Philp RP (1985a) Fossil fuel biomarkers applications and spectra. Elsevier, The Netherlands

    Google Scholar 

  • Philp RP (1985b) Biological markers in fossil fuel production. Mass Spectrom Rev 4:1–54

    Article  Google Scholar 

  • Platzner IT (1997) Modern isotope ratio mass spectrometry. Wiley, Chichester

    Google Scholar 

  • Sastri MVA, Moitra AK (1984) Vindhyan stratigraphy—a review, memoir. Geol Surv India 116(II):109–148

    Google Scholar 

  • Sastri VV, Venkatachala BS, Narayanan V (1981) The evolution of the east coast of India. Palaeogeogr Palaeoclimatol Palaeoecol 36:23–54

    Article  Google Scholar 

  • Sharma M (2006) Late Proterozoic (Statherian) carbonaceous film from the olive (Koldaha shale), Semri Group, Vindhyan Supergroup, India. J Paleontol Soc India 51(2):27–35

    Google Scholar 

  • Simoneit BRT, Fetzer JC (1996) High molecular weight polycyclic aromatic hydrocarbons in hydrothermal petroleums from the Gulf of California and Northeast Pacific Ocean. Org Geochem 24:1065–1077

    Article  Google Scholar 

  • Simoneit BRT (1992) Natural hydrous pyrolysis-petroleum generation in submarine hydrothermal systems. In: Whelan JK, Farrington JW (eds) Productivity, accumulation and preservation of organic matter in recent and ancient sediments. Columbia University Press, New York, pp 368–402

    Google Scholar 

  • Sneddon J, Masuram S, Richert JC (2007) Gas chromatography-mass spectrometry-basic principles, instrumentation and selected applications for detection of organic compounds. Anal Lett 40(6):1003–1012. doi:10.1080/00032710701300648

    Article  Google Scholar 

  • Tissot B (1969) Premières données sur les mécanismes et la cinetique de la formation du pétroledans les sédiments. Simulation d’un schéma réactionnel sur ordinateur (First data on the mechanisms and kinetics of the formation of petroleum in sediments. Simulation of a reaction scheme on a computer) Revue de Institut Français du Pétrole, vol 24, pp 470–501

    Google Scholar 

  • Tissot BP, Welte DH (1984) Petroleum formation and occurrence. A new approach to oil and gas exploration. Springer, Berlin, p 538pp

    Book  Google Scholar 

  • Tissot B, Espitalie J (1975) L’evolution thermique de la matiere organique des sediments; applica-tions d’une simulation mathematique; Potentiel petrolier des basins sedimentaires et reconstitu-tion de l’histoire thermique des sediments: Revue de l’Institut Francais du Petrole et Annales des Combustibles Liquides, vol 30, pp 743–777

    Google Scholar 

  • Van Krevelen DW (1961) Coal: typology-chemistry-physics-constitution. Elsevier Science, Amsterdam

    Google Scholar 

  • Veevers JJ (2004) Gondwanaland from 650–500 Ma assembly through 320 Ma merger in Pangea to 185–100 Ma breakup: supercontinental tectonics via stratigraphy and radiometric dating. Earth Sci Rev 68:1–132

    Article  Google Scholar 

Download references

Acknowledgments

The authors acknowledge Oil Industry Development Board, New Delhi for providing financial aid in setting up of the laboratory. The Director, NGRI is acknowledged for permitting the publication of this work. DM acknowledges CSIR for the Senior Research Associate ship.

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Correspondence to Devleena Mani .

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Mani, D., Patil, D.J., Dayal, A.M. (2015). Organic Properties and Hydrocarbon Generation Potential of Shales from Few Sedimentary Basins of India. In: Mukherjee, S. (eds) Petroleum Geosciences: Indian Contexts. Springer Geology. Springer, Cham. https://doi.org/10.1007/978-3-319-03119-4_4

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