Abstract
Eu-doped Zinc Oxide nanoparticles, with wurtzite hexagonal phase have been successfully synthesized via simple sol-gel method. Crystallinity, morphologies and optical properties of the as-prepared nanoparticles were investigated by X-ray diffraction (XRD), Atomic Force microscopy (AFM) and photoluminescence spectroscopy (PL). XRD results indicated that trivalent europium ions were successfully doped into the crystal lattice of ZnO matrix with ~13 nm average crystallite size. X-ray peak broadening analysis was used to evaluate the average crystallite size and lattice strain by the Williamson-Hall (W-H) method. Photoluminescence spectroscopic results indicated that the emission peak located at ~610 nm was attributed to the 4f–4f intra-shell transition of 5D0 → 7F2 incorporated into wurtzite ZnO host by substitution on the Zn sub lattice.
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Acknowledgments
The authors would like to thank UGC-DAE-IUC Indore, and HSADL, Bhopal for some characterizations.
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Pandey, P., Parra, M.R., Kurchania, R., Haque, F.Z. (2014). Synthesis and Optical Properties of Pure and Eu+3 Ion Doped ZnO Nanoparticles Prepared Via Sol-Gel Method. In: Jain, V., Verma, A. (eds) Physics of Semiconductor Devices. Environmental Science and Engineering(). Springer, Cham. https://doi.org/10.1007/978-3-319-03002-9_151
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DOI: https://doi.org/10.1007/978-3-319-03002-9_151
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-03001-2
Online ISBN: 978-3-319-03002-9
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