Skip to main content
Book cover

MoS2 pp 217–236Cite as

Optical Characterization, Low-Temperature Photoluminescence, and Photocarrier Dynamics in MoS2

  • Chapter
  • First Online:

Part of the book series: Lecture Notes in Nanoscale Science and Technology ((LNNST,volume 21))

Abstract

In recent years, the dichalcogenide MoS2 has gained attention as an interesting material system for basic research and possible optoelectronic applications. Here, we report on optical spectroscopy of few- and single-layer MoS2 flakes. We use Raman spectroscopy to characterize our samples. The energy of the characteristic phonon modes in MoS2 depends on the number of layers, so that the thickness of individual flakes can be mapped in scanning Raman experiments. While bulk MoS2 is an indirect-gap semiconductor, single-layer MoS2 has a direct band gap and emits strong photoluminescence. We investigate the photoluminescence in single-layer MoS2 for different experimental conditions. Additionally, we study the photocarrier dynamics in time-resolved photoluminescence experiments.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   139.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD   179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. Geim, A.K.: Angew. Chem. Int. Ed. 50(31), 6966 (2011)

    Article  CAS  Google Scholar 

  2. Novoselov, K.S., Jiang, D., Schedin, F., Booth, T.J., Khotkevich, V.V., Morozov, S.V., Geim, A.K.: G 102(30), 10451 (2005)

    CAS  Google Scholar 

  3. Mak, K.F., Lee, C., Hone, J., Shan, J., Heinz, T.F.: Phys. Rev. Lett. 105(13), 136805 (2010)

    Article  Google Scholar 

  4. Splendiani, A., Sun, L., Zhang, Y., Li, T., Kim, J., Chim, C.Y., Galli, G., Wang, F.: Nano Lett. 10(4), 1271 (2010)

    Article  CAS  Google Scholar 

  5. Lebègue, S., Eriksson, O.: Phys. Rev. B 79, 115409 (2009)

    Article  Google Scholar 

  6. Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., Kis, A.: Nat. Nanotech. 6, 147 (2011)

    Article  CAS  Google Scholar 

  7. Castellanos-Gomez, A., Barkelid, M., Goossens, A.M., Calado, V.E., van der Zant, H.S.J., Steele, G.A.: Nano Lett. 12, 3187 (2012)

    Article  CAS  Google Scholar 

  8. Huang, Y., Wu, J., Xu, X., Ho, Y., Ni, G., Zou, Q., Koon, G., Zhao, W., Castro Neto, A., Eda, G., Shen, C., Zyilmaz, B.: Nano Res. 6(3), 200 (2013)

    Google Scholar 

  9. Eda, G., Yamaguchi, H., Voiry, D., Fujita, T., Chen, M., Chhowalla, M.: Nano Lett. 11(12), 5111 (2011)

    Article  CAS  Google Scholar 

  10. Hwang, W.S., Remskar, M., Yan, R., Kosel, T., Park, J.K., Cho, B.J., Haensch, W., Xing, H.G., Seabaugh, A., Jena, D.: Appl. Phys. Lett. 102(4), 043116 (2013)

    Article  Google Scholar 

  11. Kim, D., Sun, D., Lu, W., Cheng, Z., Zhu, Y., Le, D., Rahman, T.S., Bartels, L.: Langmuir 27(18), 11650 (2011)

    Google Scholar 

  12. Shi, Y., Zhou, W., Lu, A.Y., Fang, W., Lee, Y.H., Hsu, A.L., Kim, S.M., Kim, K.K., Yang, H.Y., Li, L.J., Idrobo, J.C., Kong, J.: Nano Lett. 12(6), 2784 (2012)

    Article  CAS  Google Scholar 

  13. Zhan, Y., Liu, Z., Najmaei, S., Ajayan, P.M., Lou, J.: Small 8(7), 966 (2012)

    Article  CAS  Google Scholar 

  14. Lee, Y.H., Zhang, X.Q., Zhang, W., Chang, M.T., Lin, C.T., Chang, K.D., Yu, Y.C., Wang, J.T.W., Chang, C.S., Li, L.J., Lin, T.W.: Adv. Mater. 24(17), 2320 (2012)

    Article  CAS  Google Scholar 

  15. Wu, S., Huang, C., Aivazian, G., Ross, J.S., Cobden, D.H., Xu, X.: ACS Nano 7(3), 2768 (2013)

    Article  CAS  Google Scholar 

  16. Liu, H., Ye, P.: IEEE Elect. Device Lett. 33(4), 546 (2012)

    Google Scholar 

  17. Zhang, Y., Ye, J., Matsuhashi, Y., Iwasa, Y.: Nano Lett. 12(3), 1136 (2012)

    Article  CAS  Google Scholar 

  18. Radisavljevic, B., Whitwick, M.B., Kis, A.: Appl. Phys. Lett. 101(4), 043103 (2012)

    Article  Google Scholar 

  19. Wang, H., Yu, L., Lee, Y.H., Shi, Y., Hsu, A., Chin, M.L., Li, L.J., Dubey, M., Kong, J., Palacios, T.: Nano Lett. 12(9), 4674 (2012)

    Article  CAS  Google Scholar 

  20. Bertolazzi, S., Krasnozhon, D., Kis, A.: ACS Nano 7(4), 3246 (2013)

    Article  CAS  Google Scholar 

  21. Xiao, D., Liu, G.B., Feng, W., Xu, X., Yao, W.: Phys. Rev. Lett. 108, 196802 (2012)

    Article  Google Scholar 

  22. Castellanos-Gomez, A., Agraït, N., Rubio-Bollinger, G.: Appl. Phys. Lett. 96(21), 213116 (2010)

    Article  Google Scholar 

  23. Benameur, M.M., Radisavljevic, B., HTron, J.S., Sahoo, S., Berger, H., Kis, A.: Nanotechnology 22(12), 125706 (2011)

    Google Scholar 

  24. Ferrari, A.C., Meyer, J.C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K.S., Roth, S., Geim, A.K.: Phys. Rev. Lett. 97(18), 187401 (2006)

    Google Scholar 

  25. Yan, J., Zhang, Y., Kim, P., Pinczuk, A.: Phys. Rev. Lett. 98, 166802 (2007)

    Article  Google Scholar 

  26. Casiraghi, C., Pisana, S., Novoselov, K.S., Geim, A.K., Ferrari, A.C.: Appl. Phys. Lett. 91(23), 233108 (2007)

    Article  Google Scholar 

  27. Heydrich, S., Hirmer, M., Preis, C., Korn, T., Eroms, J., Weiss, D., Schüller, C.: Appl. Phys. Lett. 97(4), 043113 (2010)

    Article  Google Scholar 

  28. Ferrari, A.C.: Solid State Commun. 143, 47 (2007)

    Article  CAS  Google Scholar 

  29. Lee, C., Yan, H., Brus, L.E., Heinz, T.F., Hone, J., Ryu, S.: ACS Nano 4(5), 2695 (2010)

    Article  CAS  Google Scholar 

  30. Najmaei, S., Liu, Z., Ajayan, P.M., Lou, J.: Appl. Phys. Lett. 100(1), 013106 (2012)

    Article  Google Scholar 

  31. Scheuschner, N., Ochedowski, O., Schleberger, M., Maultzsch, J.: Phy. Status solidi B 249(12), 2644 (2012)

    Google Scholar 

  32. Rice, C., Young, R.J., Zan, R., Bangert, U., Wolverson, D., Georgiou, T., Jalil, R., Novoselov, K.S.: Phys. Rev. B 87, 081307 (2013)

    Article  Google Scholar 

  33. Tonndorf, P., Schmidt, R., Böttger, P., Zhang, X., Börner, J., Liebig, A., Albrecht, M., Kloc, C., Gordan, O., Zahn, D.R.T., de Vasconcellos, S.M., Bratschitsch, R.: Opt. Express 21(4), 4908 (2013)

    Article  CAS  Google Scholar 

  34. Molina-Sánchez, A., Wirtz, L.: Phys. Rev. B 84, 155413 (2011)

    Article  Google Scholar 

  35. Li, S.L., Miyazaki, H., Song, H., Kuramochi, H., Nakaharai, S., Tsukagoshi, K.: ACS Nano 6(8), 7381 (2012)

    Article  CAS  Google Scholar 

  36. Zeng, H., Liu, G.B., Dai, J., Yan, Y., Zhu, B., He, R., Xie, L., Xu, S., Chen, X., Yao, W., Cui, X.: Sci. Rep. 3, 1608 (2013)

    Google Scholar 

  37. Nemanich, G.L.R.J., Solin, S.A.: In: Proceedings of the International Conference on Lattice Dynamics. In: M. Balkanski (ed.), Flammarion (1975)

    Google Scholar 

  38. Verble, J., Wietling, T., Reed, P.: Solid State Commun. 11(8), 941 (1972)

    Article  CAS  Google Scholar 

  39. Kuzuba, T., Era, K., Ishii, T., Sato, T.: Solid State Commun. 25(11), 863 (1978)

    Article  CAS  Google Scholar 

  40. Tan, P.H., Han, W.P., Zhao, W.J., Wu, Z.H., Chang, K., Wang, H., Wang, Y.F., Bonini, N., Marzari, N., Pugno, N., Savini, G., Lombardo, A., Ferrari, A.C.: Nat. Mater. 11, 294 (2012)

    Article  CAS  Google Scholar 

  41. Hayek, M., Brafman, O., Lieth, R.M.A.: Phys. Rev. B 8, 2772 (1973)

    Article  CAS  Google Scholar 

  42. Plechinger, G., Heydrich, S., Eroms, J., Weiss, D., Schüller, C., Korn, T.: Appl. Phys. Lett. 101(10), 101906 (2012)

    Article  Google Scholar 

  43. Chandrasekhar, M., Rössler, U., Cardona, M.: Phys. Rev. B 22, 761 (1980)

    Article  CAS  Google Scholar 

  44. Zeng, H., Zhu, B., Liu, K., Fan, J., Cui, X., Zhang, Q.M.: Phys. Rev. B 86, 241301 (2012)

    Article  Google Scholar 

  45. Zhao, Y., Luo, X., Li, H., Zhang, J., Araujo, P.T., Gan, C.K., Wu, J., Zhang, H., Quek, S.Y., Dresselhaus, M.S., Xiong, Q.: Nano Lett. 13(3), 1007 (2013)

    Article  CAS  Google Scholar 

  46. Zhang, X., Han, W.P., Wu, J.B., Milana, S., Lu, Y., Li, Q.Q., Ferrari, A.C., Tan, P.H.: Phys. Rev. B 87, 115413 (2013)

    Article  Google Scholar 

  47. Varshni, Y.: Physica 34, 149 (1967)

    Article  CAS  Google Scholar 

  48. Korn, T., Heydrich, S., Hirmer, M., Schmutzler, J., Schüller, C.: Appl. Phys. Lett. 99(10), 102109 (2011)

    Article  Google Scholar 

  49. Plechinger, G., Schrettenbrunner, F.X., Eroms, J., Weiss, D., Schnller, C., Korn, T.: Phy. Stat. Solidi (RRL) û Rap. Res. Lett. 6(3), 126 (2012)

    Google Scholar 

  50. Scalise, E., Houssa, M., Pourtois, G., Afanas’ev, V., Stesmans, A.: Nano Research 5, 43 (2012)

    Google Scholar 

  51. Yun, W.S., Han, S.W., Hong, S.C., Kim, I.G., Lee, J.D.: Phys. Rev. B 85, 033305 (2012)

    Article  Google Scholar 

  52. Johari, P., Shenoy, V.B.: ACS Nano 6(6), 5449 (2012)

    Article  CAS  Google Scholar 

  53. Scalise, E., Houssa, M., Pourtois, G., Afanas’ev, V., Stesmans, A.: Physica E (2012). (In Press)

    Google Scholar 

  54. Rice, C., Young, R.J., Zan, R., Bangert, U., Wolverson, D., Georgiou, T., Jalil, R., Novoselov, K.S.: Phys. Rev. B 87, 081307 (2013)

    Article  Google Scholar 

  55. Cao, T., Wang, G., Han, W., Ye, H., Zhu, C., Shi, J., Niu, Q., Tan, P., Wang, E., Liu, B., Feng, J.: Nat. Comm. 3, 887 (2012)

    Article  Google Scholar 

  56. Zeng, H., Dai, J., Yao, W., Xiao, D., Cui, X.: Nat. Nanotech. 7, 490 (2012)

    Article  CAS  Google Scholar 

  57. [57] K. Kin Fai Mak, K. He, J. Shan, T. Heinz, Nature Nanotech. 7, 494 (2012)

    Google Scholar 

  58. Sallen, G., Bouet, L., Marie, X., Wang, G., Zhu, C.R., Han, W.P., Lu, Y., Tan, P.H., Amand, T., Liu, B.L., Urbaszek, B.: Phys. Rev. B 86, 081301 (2012)

    Article  Google Scholar 

  59. Kioseoglou, G., Hanbicki, A.T., Currie, M., Friedman, A.L., Gunlycke, D., Jonker, B.T.: Appl. Phys. Lett. 101(22), 221907 (2012)

    Article  Google Scholar 

  60. Sanvitto, D., Hogg, R.A., Shields, A.J., Whittaker, D.M., Simmons, M.Y., Ritchie, D.A., Pepper, M.: Phys. Rev. B 62(20), R13294 (2000)

    Article  CAS  Google Scholar 

  61. Wang, R., Ruzicka, B.A., Kumar, N., Bellus, M.Z., Chiu, H.Y., Zhao, H.: Phys. Rev. B 86, 045406 (2012)

    Article  Google Scholar 

  62. Shi, H., Yan, R., Bertolazzi, S., Brivio, J., Gao, B., Kis, A., Jena, D., Xing, H.G., Huang, L.: ACS Nano 7(2), 1072 (2013)

    Article  CAS  Google Scholar 

  63. Mak, K.F., He, K., Lee, C., Lee, G.H., Hone, J., Heinz, T.F., Shan, J.: Nat. Mater. 12, 207 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge financial support by the DFG via SFB689, SPP 1285, GRK 1570, and KO3612/1-1 as well as fruitful discussion with L. Wirtz, A. Molina-Sánchez, J. Maultsch, and N. Scheuschner.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. Korn .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Korn, T. et al. (2014). Optical Characterization, Low-Temperature Photoluminescence, and Photocarrier Dynamics in MoS2 . In: Wang, Z. (eds) MoS2. Lecture Notes in Nanoscale Science and Technology, vol 21. Springer, Cham. https://doi.org/10.1007/978-3-319-02850-7_8

Download citation

Publish with us

Policies and ethics