Abstract
This chapter provides an overview of time-resolved photoelectron spectroscopy (TRPES) for unravelling excited state dynamics in polyatomic molecules. It begins with a brief introduction to the basics of nonadiabatic dynamics in polyatomic molecules. This is followed by a description of the principles behind TRPES and a discussion of the roles of the ionisation continuum. We then describe the experimental toolkit, from light and molecule sources to photoelectron spectrometers. Finally, we describe several examples where TRPES has been employed to unravel non-adiabatic dynamics in polyatomic molecules.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
M. Bixon, J. Jortner, J. Chem. Phys. 48, 715 (1968)
J. Jortner, S.A. Rice, R.M. Hochstrasser, Adv. Photochem. 7, 149 (1969)
S.R. Henry, W. Siebrand, in Organic Molecular Photophysics, vol. 1, ed. by J.B. Birks (Wiley, London, 1973), p. 152
K.F. Freed, in Radiationless Processes in Molecules and Condensed Phases, ed. by F.K. Fong (Springer, Berlin, 1976), p. 23
G. Stock, W. Domcke, Adv. Chem. Phys. 100, 1 (1997)
G.A. Worth, L.S. Cederbaum, Annu. Rev. Phys. Chem. 55, 127 (2004)
M. Klessinger, J. Michl, Excited States and Photochemistry of Organic Molecules (VCH, New York, 1994)
H. Köppel, W. Domcke, L.S. Cederbaum, Adv. Chem. Phys. 57, 59 (1984)
S. Matsika, P. Krause, Annu. Rev. Phys. Chem. 62(1), 621 (2011). doi:10.1146/annurev-physchem-032210-103450
I. Fischer, M. Vrakking, D. Villeneuve, A. Stolow, in Femtosecond Chemistry, ed. by M. Chergui (World Scientific, Singapore, 1996)
A. Stolow, Philos. Trans. R. Soc. Lond. A 356, 345 (1998)
C.C. Hayden, A. Stolow, in Advanced Physical Chemistry, vol. 10, ed. by C.Y. Ng (World Scientific, Singapore, 2000)
W. Radloff, in Advanced Physical Chemistry, vol. 10, ed. by C.Y. Ng (World Scientific, Singapore, 2000)
K. Takatsuka, Y. Arasaki, K. Wang, V. McKoy, Faraday Discuss. 1–15 (2000)
D.M. Neumark, Annu. Rev. Phys. Chem. 52, 255 (2001)
T. Suzuki, B.J. Whitaker, Int. Rev. Phys. Chem. 20, 313 (2001)
T. Seideman, Annu. Rev. Phys. Chem. 53, 41 (2002)
K.L. Reid, Annu. Rev. Phys. Chem. 54, 397 (2003)
A. Stolow, Annu. Rev. Phys. Chem. 54, 89 (2003)
A. Stolow, Int. Rev. Phys. Chem. 22, 377 (2003)
T. Suzuki, Y. Seideman, M. Stener, J. Chem. Phys. 120, 1172 (2004)
A. Stolow, A. Bragg, D. Neumark, Chem. Rev. 104, 1719 (2004)
V. Wollenhaupt, M. Engel, T. Baumert, Annu. Rev. Phys. Chem. 56, 25 (2005)
T. Suzuki, Annu. Rev. Phys. Chem. 57, 555 (2006)
I.V. Hertel, W. Radloff, Rep. Prog. Phys. 69, 1897 (2006)
A. Stolow, J.G. Underwood, Adv. Chem. Phys. 139, 497 (2008)
J.H.D. Eland, Photoelectron Spectroscopy, 2nd edn. (Butterworths, London, 1984)
T. Koopmans, Physica 1, 104 (1933)
A.M. Ellis, M. Feher, T.G. Wright, Electronic and Photoelectron Spectroscopy. Fundamentals and Case Studies (Cambridge University Press, Cambridge, 2005)
K.L. Reid, Int. Rev. Phys. Chem. 27(4), 607 (2008)
R.S. Berry, J. Chem. Phys. 45, 1228 (1966)
A.J. Blake, J.L. Bahr, J.H. Carver, V. Kumar, Philos. Trans. R. Soc. Lond. A 268, 159 (1970)
M. Seel, W. Domcke, J. Chem. Phys. 95, 7806 (1991)
M. Seel, W. Domcke, Chem. Phys. 151, 59 (1991)
V. Blanchet, M.Z. Zgierski, A. Stolow, J. Chem. Phys. 114, 1194 (2001)
M. Schmitt, S. Lochbrunner, J.P. Shaffer, J.J. Larsen, M.Z. Zgierski, A. Stolow, J. Chem. Phys. 114, 1206 (2001)
R.S. Minns, D.S.N. Parker, T.J. Penfold, G.A. Worth, H.H. Fielding, Phys. Chem. Chem. Phys. 12, 15607 (2010). doi:10.1039/C001671C
K.L. Reid, Mol. Phys. 110(3), 131 (2012)
H. Park, R.N. Zare, J. Chem. Phys. 104, 4554 (1996)
O. Gessner, A. Lee, J. Shaffer, H. Reisler, S. Levchenko, A. Krylov, J. Underwood, H. Shi, A. East, D. Wardlaw, E. Chrysostom, C. Hayden, A. Stolow, Science 311, 219 (2006)
R.E. Continetti, C.C. Hayden, in Modern Trends in Chemical Reaction Dynamics, ed. by K. Liu, X. Yang. Advanced Series in Physical Chemistry, vol. 14 (World Scientific, Singapore, 2003)
J.A. Davies, J.E. LeClaire, R.E. Continetti, C.C. Hayden, J. Chem. Phys. 111, 1 (1999)
C.Z. Bisgaard, O.J. Clarkin, G. Wu, A.M.D. Lee, O. Geßner, C.C. Hayden, A. Stolow, Science 323(5920), 1464 (2009)
K.L. Reid, J.G. Underwood, J. Chem. Phys. 112, 3643 (2000)
K.L. Reid, T.A. Field, M. Towrie, P. Matousek, J. Chem. Phys. 111, 1438 (1999)
J.G. Underwood, K.L. Reid, J. Chem. Phys. 113, 1067 (2000)
S.C. Althorpe, T. Seideman, J. Chem. Phys. 113, 7901 (2000)
T. Seideman, S.C. Althorpe, J. Electron Spectrosc. Relat. Phenom. 108, 99 (2000)
S.C. Althorpe, T. Seideman, J. Chem. Phys. 110, 147 (1999)
M. Tsubouchi, B.J. Whitaker, L. Wang, H. Kohguchi, T. Suzuki, Phys. Rev. Lett. 86, 4500 (2001)
T. Brabec, F. Krausz, Rev. Mod. Phys. 72, 545 (2000). doi:10.1103/RevModPhys.72.545
U. Keller, Nature 424, 831 (2003). doi:10.1038/nature01938
M. Nisoli, S.D. Silvestri, V. Magni, O. Svelto, R. Danielius, A. Piskarskas, G. Valiulis, A. Varanavicius, Opt. Lett. 19(23), 1973 (1994). doi:10.1364/OL.19.001973
T. Wilhelm, J. Piel, E. Riedle, Opt. Lett. 22(19), 1494 (1997). doi:10.1364/OL.22.001494
F. Krausz, M. Ivanov, Rev. Mod. Phys. 81, 163 (2009). doi:10.1103/RevModPhys.81.163
M. Abd-Elmeguid et al., Tesla technical design report, part 5: The x-ray free electron laser. Tech. rep, DESY (2001)
K. Tiedtke, A. Azima, N. von Bargen, L. Bittner, S. Bonfigt, S. Düsterer, B. Faatz, U. Frühling, M. Gensch, C. Gerth, N. Guerassimova, U. Hahn, T. Hans, M. Hesse, K. Honkavaar, U. Jastrow, P. Juranic, S. Kapitzki, B. Keitel, T. Kracht, M. Kuhlmann, W.B. Li, M. Martins, T. Núñez, E. Plönjes, H. Redlin, E.L. Saldin, E.A. Schneidmiller, J.R. Schneider, S. Schreiber, N. Stojanovic, F. Tavella, S. Toleikis, R. Treusch, H. Weigelt, M. Wellhöfer, H. Wabnitz, M.V. Yurkov, J. Feldhaus, New J. Phys. 11(2), 023029 (2009)
P. Emma, R. Akre, J. Arthur, R. Bionta, C. Bostedt, J. Bozek, A. Brachmann, P. Bucksbaum, R. Coffee, F.J. Decker, Y. Ding, D. Dowell, S. Edstrom, A. Fisher, J. Frisch, S. Gilevich, J. Hastings, G. Hays, P. Hering, Z. Huang, R. Iverson, H. Loos, M. Messerschmidt, A. Miahnahri, S. Moeller, H.D. Nuhn, G. Pile, D. Ratner, J. Rzepiela, D. Schultz, T. Smith, P. Stefan, H. Tompkins, J. Turner, J. Welch, W. White, J. Wu, G. Yocky, J. Galayda, Nat. Photonics 4(9), 641 (2010). doi:10.1038/nphoton.2010.176
A. Azima, S. Dusterer, P. Radcliffe, H. Redlin, N. Stojanovic, W. Li, H. Schlarb, J. Feldhaus, D. Cubaynes, M. Meyer, J. Dardis, P. Hayden, P. Hough, V. Richardson, E.T. Kennedy, J.T. Costello, Appl. Phys. Lett. 94(14), 144102 (2009). doi:10.1063/1.3111789
R. Campargue, J. Phys. Chem. 88(20), 4466 (1984). doi:10.1021/j150664a004
J.B. Anderson, J.B. Fenn, Phys. Fluids 8(5), 780 (1965). doi:10.1063/1.1761320
A. Amirav, U. Even, J. Jortner, Chem. Phys. 51(1–2), 31 (1980). doi:10.1016/0301-0104(80)80077-2
P.M. Mayer, T. Baer, Int. J. Mass Spectrom. Ion Process. 156(3), 133 (1996). doi:10.1016/S0168-1176(96)04422-9
U. Even, J. Jortner, D. Noy, N. Lavie, C. Cossart-Magos, J. Chem. Phys. 112(18), 8068 (2000). doi:10.1063/1.481405
M. Faubel, T. Kisters, Nature 339(6225), 527 (1989). doi:110.1038/339527a0
A. Charvat, E. Lugovoj, M. Faubel, B. Abel, Rev. Sci. Instrum. 75(5), 1209 (2004). doi:10.1063/1.1710704
M. Faubel, K.R. Siefermann, Y. Liu, B. Abel, Acc. Chem. Res. 45(1), 120 (2012). doi:10.1021/ar200154w
Y. Tang, H. Shen, K. Sekiguchi, N. Kurahashi, T. Mizuno, Y.I. Suzuki, T. Suzuki, Phys. Chem. Chem. Phys. 12, 3653 (2010). doi:10.1039/B925741A
P. Kruit, F.H. Read, J. Phys. E, Sci. Instrum. 16(4), 313 (1983)
A.T.J.B. Eppink, S. Min Wu, B.J. Whitaker, in Imaging in Molecular Dynamics, ed. by B.J. Whitaker (Cambridge University Press, Cambridge, 2003)
S.J. Cavanagh, S.T. Gibson, M.N. Gale, C.J. Dedman, E.H. Roberts, B.R. Lewis, Phys. Rev. A 76, 052708 (2007). doi:10.1103/PhysRevA.76.052708
V. Blanchet, M.Z. Zgierski, T. Seideman, A. Stolow, Nature 401, 52 (1999). doi:10.1038/43410
J.A. Davies, A.M. Green, K.L. Reid, Phys. Chem. Chem. Phys. 12, 9872 (2010). doi:10.1039/C0CP00102C
C.J. Hammond, K.L. Reid, K.L. Ronayne, J. Chem. Phys. 124(20), 201102 (2006). doi:10.1063/1.2204596
M. Tsubouchi, B.J. Whitaker, L. Wang, H. Kohguchi, T. Suzuki, Phys. Rev. Lett. 86, 4500 (2001). doi:10.1103/PhysRevLett.86.4500
O. Geßner, A.M.D. Lee, J.P. Shaffer, H. Reisler, S.V. Levchenko, A.I. Krylov, J.G. Underwood, H. Shi, A.L.L. East, D.M. Wardlaw, E.t.H. Chrysostom, C.C. Hayden, A. Stolow, Science 311(5758), 219 (2006). doi:10.1126/science.1120779
A.E. Bragg, J.R.R. Verlet, A. Kammrath, O. Cheshnovsky, D.M. Neumark, Science 306(5696), 669 (2004). doi:10.1126/science.1103527
P. Wernet, J. Gaudin, K. Godehusen, O. Schwarzkopf, W. Eberhardt, Rev. Sci. Instrum. 82(6), 063114 (2011). doi:10.1063/1.3600901
P. Wernet, M. Odelius, K. Godehusen, J. Gaudin, O. Schwarzkopf, W. Eberhardt, Phys. Rev. Lett. 103, 013001 (2009)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Spesyvtsev, R., Underwood, J.G., Fielding, H.H. (2014). Time-Resolved Photoelectron Spectroscopy for Excited State Dynamics. In: de Nalda, R., Bañares, L. (eds) Ultrafast Phenomena in Molecular Sciences. Springer Series in Chemical Physics, vol 107. Springer, Cham. https://doi.org/10.1007/978-3-319-02051-8_5
Download citation
DOI: https://doi.org/10.1007/978-3-319-02051-8_5
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-02050-1
Online ISBN: 978-3-319-02051-8
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)