Skip to main content
SpringerLink
Log in

Raman Spectroscopy in Ionic Liquids Under Variable Thermodynamic and Environmental Conditions

  • Chapter
  • First Online:
The Structure of Ionic Liquids

Part of the book series: Soft and Biological Matter ((SOBIMA))

Abstract

The potentialities of the Raman spectroscopy in providing a deep insight into the microscopic anion-cation interactions in ionic liquids are discussed. We report on and discuss Raman measurements mainly collected on a particular class of ionic liquids called protic ionic liquids (PILs), based on the nitrate anion, NO3 −. Together with the spectroscopic investigation, first principle studies have been carried out for most of the measured samples. The combined experimental-theoretical approach allows us to deeply investigate the effects induced by the length of the alkyl chain on the optical properties of PILs. We also focus and report on systematic temperature (300–450 K) and pressure (0–10 GPa) dependent studies. The extended P–T region explored allows to observe liquid–solid and several solid–solid transitions and to draw general remarks on the phase diagram of PILs. Finally, exploiting the high sensitivity of the Raman spectroscopy to protein secondary and tertiary structures, the efficacy of PILs as protein refolding enhancers is also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 54.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Rogers, R.D., Seddon, K.R.: In: Rogers, R.D., Seddon, K.R. (eds.) Ionic liquids IIIA: Fundamentals, Progress, Challenges, and Opportunities-Properties and Structure; ACS Symposium Series 901, p. 1. American Chemical Society, Washington (2005)

    Chapter  Google Scholar 

  2. Rogers, R.D., Seddon, K.R.: In: Rogers, R.D., Seddon, K.R. (eds.) Ionic Liquids IIIA: Fundamentals, Progress, Challenges, and Opportunities- Transformations and processes; ACS Symposium Series 902, p. 1. American Chemical Society, Washington (2005)

    Chapter  Google Scholar 

  3. Rogers, R.D., Plechkova, N.V., Seddon, K.R.: In: Rogers, R.D., Plechkova, N.V., Seddon, K.R. (eds.) Ionic Liquids: From Knowledge to Application; ACS Symposium Series 1030, p. 1. American Chemical Society, Washington

    Google Scholar 

  4. Gaune-Escard, M., Seddon, K.R.: In: Gaune-Escard, M., Seddon, K.R. (eds.) Molten Salts and Ionic Liquids: Never the Twain?, p. 1. Wiley, New York (2010)

    Chapter  Google Scholar 

  5. Walden, P.: Bull Acad. Imper. Sci. St Petersburg 8, 45 (1914)

    Google Scholar 

  6. Welton, T., Wasserscheid, P.: In: Welton, T., Wasserscheid, P. (eds.) Ionic Liquid Synthesis, 2nd edn, p. 1. Wiley VCH, Weinheim (2008)

    Google Scholar 

  7. Forsyth, S.A., Pringle, J.M., MacFarlane, D.R.: Aust. J. Chem. 57, 113 (2004)

    Article  Google Scholar 

  8. Zeng, Z., Phillips, B.S., Xiao, J.-C., Shreeve, J.M.: Chem. Mater. 20, 2719 (2008)

    Article  Google Scholar 

  9. Hough, W.L., Rogers, R.D.: Bull. Chem. Soc. Jpn. 80, 2262 (2007)

    Article  Google Scholar 

  10. Hough, W.L., Smiglak, M., Rodriguez, H., Swatloski, R.P., Spear, S.K., Daly, D.T., Pernak, J., Grisel, J.E., Carliss, R.D., Soutullo, M.D., Davis Jr, J.H., Rogers, R.D.: New J. Chem. 31, 1429 (2007)

    Article  Google Scholar 

  11. Mizuuchi, H., Jaitely, V., Murdan, S., Florence, A.: Eur. J. Pharmac. Sci. 33, 326 (2008)

    Article  Google Scholar 

  12. Boon, J.A., Levisky, J.A., Pflug, J.L., Wilkes, J.S.: J. Org. Chem. 51, 480 (1986)

    Article  Google Scholar 

  13. Fischer, T., Sethi, A., Welton, T., Woolf, J.: Tetrahedron Lett. 40, 793 (1999)

    Article  Google Scholar 

  14. Wasserscheid, P., Keim, W.: Angew. Chem. Int. Ed. 39, 3772 (2000)

    Article  Google Scholar 

  15. Welton, T.: Chem. Rev. 99, 2071 (1999)

    Article  Google Scholar 

  16. Koel, M.C.: Rev. Ann. Chem. 35, 177 (2005)

    Google Scholar 

  17. Tan, S.S.Y., MacFarlane, D.R., Upfal, J., Edye, L.A., Doherty, W.O.S., Patti, A.F., Pringle, J.M., Scott, J.L.: Green Chem. 11, 339 (2009)

    Article  Google Scholar 

  18. Sun, H., Zhang, D., Liu, C., Zhang, C.: THEOCHEM 900, 37 (2009)

    Article  Google Scholar 

  19. Buzzeo, M.C., Evans, R.G., Compton, R.G.: Chem. Phys. Chem. 2004(5), 1106 (2004)

    Article  Google Scholar 

  20. Endres, F., Abedin, S.Z.E.: Phys. Chem. Chem. Phys. 8, 2101 (2006)

    Article  Google Scholar 

  21. Hapiot, P., Lagrost, C.: Chem. Rev. 108, 2238 (2008)

    Article  Google Scholar 

  22. MacFarlane, D.R., Forsyth, M., Howlett, P.C., Pringle, J.M., Sun, J., Annat, G., Neil, W., Izgorodina, E.I.: Acc. Chem. Res. 40, 1165 (2007)

    Article  Google Scholar 

  23. Angell, C.A., Byrne, N., Belieres, J.-P.: Acc. Chem. Res. 40, 1228 (2007)

    Article  Google Scholar 

  24. Greaves, T.L., Drummond, C.J.: Chem. Rev. 108, 206 (2008)

    Article  Google Scholar 

  25. Xu, W., Angell, C.A.: Science 302, 422 (2003)

    Article  ADS  Google Scholar 

  26. Yoshizawa, M., Xu, W., Angell, C.A.: J. Am. Chem. Soc. 125, 15411 (2003)

    Article  Google Scholar 

  27. Fumino, K., Wulf, A., Ludwig, R.: Angew. Chem. Int. Ed. 48, 3184 (2009)

    Google Scholar 

  28. Fumino, K., Peppel, T., Geppert-Rybczynśk, A.M., Zaitsau, D.H., Lehmann, J.K., Verevkin, S.P., Kockerling, M., Ludwig, R.: Phys. Chem. Chem. Phys. 11, 14064 (2011)

    Google Scholar 

  29. Atkin, R., Warr, G.G.: J. Phys. Chem. B 112, 4164 (2008)

    Article  Google Scholar 

  30. Greaves, T.L., Weerawardena, A., Krodkiewska, I., Drummond, C.: J. J. Phys. Chem. B 112, 896 (2008)

    Article  Google Scholar 

  31. Mamontov, E., Luo, H., Dai, S.J.: Phys. Chem. B 113, 159 (2009)

    Article  Google Scholar 

  32. Hayes, R., Imberti, S., Warr, G.G., Atkin, R.: Phys. Chem. Chem. Phys. 13, 3237 (2011)

    Article  Google Scholar 

  33. Song, X., Hamano, H., Minofar, B., Kanzaki, R., Fujii, K., Kameda, Y., Kohara, S., Watanabe, M., Ishiguro, S.-I., Umebayashi, Y.J.: Phys. Chem. B 116, 2801 (2012)

    Article  Google Scholar 

  34. Kobayashi, A., Osawa, K., Terazima, M., Kimura, Y.: Phys. Chem. Chem. Phys. 14, 13676 (2012)

    Article  Google Scholar 

  35. Ribeiro, M.C.C.: J. Phys. Chem. B 116, 7281 (2012)

    Article  Google Scholar 

  36. Sacchetti, A., Baldini, M., Postorino, P., Martin, C., Maignan, A.: J. Raman Spettrosc. 37, 591 (2006)

    Article  ADS  Google Scholar 

  37. Postorino, P., Congeduti, A., Degiorgi, E., Itie, J.P., Munsch, P.: Phys. Rev. B 65, 224102 (2002)

    Article  ADS  Google Scholar 

  38. Mangialardo, S., Gontrani, L., Leonelli, F., Caminiti, R., Postorino, P.: RSC Advances 2, 12329 (2012)

    Article  Google Scholar 

  39. Baciocchi, R., Costa, G., Lategano, E., Marini, C., Polettini, A., Pomi, R., Postorino, P., Rocca, S.: Waste Manage. 30, 1310 (2010)

    Article  Google Scholar 

  40. Fattibene, P., Carosi, A., De Coste, V., Sacchetti, A., Nucara, A., Postorino, P., Dore, P.: Phys. Med. Biol. 50, 1095 (2005)

    Article  Google Scholar 

  41. Mangialardo, S., Piccirilli, F., Perucchi, A., Dore, P., Postorino, P.: J. Raman Spectrosc. 43, 692 (2012)

    Article  Google Scholar 

  42. Zahn, S., Thar, J., Kirchner, B.J.: Chem. Phys. 132, 124506 (2010)

    Article  ADS  Google Scholar 

  43. Maginn, E.J.: J. Phys. Condens. Matter 21, 373101 (2009)

    Article  Google Scholar 

  44. Canongia Lopes, J.N.A., Deschamps, J., Padua, A.A.H.: In: Rogers, R.D., Seddon, K.R. (eds.) Ionic Liquids IIIA: Fundamentals, Progress, Challenges, and Opportunities-Properties and Structure; ACS Symposium Series 901, p. 134. American Chemical Society, Washington (2005)

    Chapter  Google Scholar 

  45. Canongia Lopes, J.N.A., Padua, A.A.H.: J. Phys. Chem. B 110, 7485 (2006)

    Article  Google Scholar 

  46. Borodin, O.: J. Phys. Chem. B 113, 11463 (2009)

    Article  Google Scholar 

  47. Sambasivarao, S.V., Acevedo, O.: J. Chem. Theory Comput. 5, 1038 (2009)

    Article  Google Scholar 

  48. Bodo, E., Gontrani, L., Triolo, A., Caminiti, R.: J. Phys. Chem. Lett. 1, 1095 (2010)

    Article  Google Scholar 

  49. Bodo, E., Gontrani, L., Caminiti, R., Plechkova, N.V., Seddon, K.R., Triolo, A.: J. Phys. Chem. B 114, 16398 (2010)

    Article  Google Scholar 

  50. Bodo, E., Postorino, P., Mangialardo, S., Piacente, G., Ramondo, F., Bosi, F., Ballirano, P., Caminiti, R.: J. Phys. Chem. B 115, 13149 (2011)

    Article  Google Scholar 

  51. Robert, C., Casella, G.: Monte Carlo Statistical Methods. Springer, Berlin, p. 1

    Google Scholar 

  52. Hartke, B.J.: Phys. Chem. 97, 9973 (1993)

    Article  Google Scholar 

  53. http://dasher.wustl.edu/tinker/

  54. Bodo, E., Mangialardo, S., Ramondo, F., Ceccacci, F., Postorino, P.: J. Phys. Chem. B 116, 13878 (2012)

    Article  Google Scholar 

  55. Varnek, A., Kireeva, N., Tetko, I.V., Baskin, I.I., Solovev, V.P.: J. Chem. Inf. Model. 47, 1111 (2007)

    Article  Google Scholar 

  56. Greaves, T.L., Weerawardena, A., Fong, C., Krodkiewska, I., Drummond, C.J.: J. Phys. Chem. B 110, 22479 (2006)

    Article  Google Scholar 

  57. López-Martin, I., Burello, E., Davey, P.N., Seddon, K.R., Rothenberg, G.: Chem. Phys. Chem. 8, 690 (2007)

    Article  Google Scholar 

  58. Wakai, C., Oleinikova, A., Ott, M., Weingartner, H.: J. Phys. Chem. B 109, 17028 (2005)

    Article  Google Scholar 

  59. Lee, J.-M., Prausnitz, J.M.: Chem. Phys. Lett. 492, 55 (2010)

    Article  ADS  Google Scholar 

  60. Smith, R., Tanford, C.: Proc. Nat. Acad. Sci. USA 70(289–293), 1973 (1973)

    Google Scholar 

  61. Mylrajan, M., Srinivasan, T.: J. Raman Spectrosc. 16, 412 (1985)

    Article  ADS  Google Scholar 

  62. Mylrajan, M., Srinivasan, T.: J. Raman Spectrosc. 18, 365 (1987)

    Article  ADS  Google Scholar 

  63. Jorgensen, W.L., Maxwell, D.S., Tirado-Rives, J.: J. Am. Chem. Soc. 117, 11225 (1996)

    Article  Google Scholar 

  64. Lebrero, M.C.G., Bikiel, D.E., Elola, M.D., Estrin, D.A., Roitberg, A.E.: J. Chem. Phys. 117, 2718 (2002)

    Article  ADS  Google Scholar 

  65. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Mennucci, B., Petersson, G.A., Nakatsuji, H., Caricato, M., Li, X., Hratchian, H.P., Izmaylov, A.F., Bloino, J., Zheng, G., Sonnenberg, J.L., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Montgomery, Jr. J.A., Peralta, J.E., Ogliaro, F., Bearpark, M., Heyd, J.J., Brothers, E., Kudin, K.N., Staroverov, V.N., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J.C., Iyengar, S.S., Tomasi, J., Cossi, M., Rega, N., Millam, J.M, Klene, M., Knox, J.E., Cross, J.B., Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R.E., Yazyev, O., Austin, A.J., Cammi, R., Pomelli, C., Ochterski, J.W., Martin, R.L., Morokuma, K., Zakrzewski, V.G., Voth, G.A., Salvador, P., Dannenberg, J.J., Dapprich, S., Daniels, A.D., Farkas, Ö., Foresman, J.B., Ortiz, J.V., Cioslowski, J., Fox, D.J.: Gaussian 09, Revision A.1. Gaussian Inc., Wallingford

    Google Scholar 

  66. Mao, H.K., Bell, P.M., Shaner, J., Steinberg, D.: J. Appl. Phys. 49, 3276 (1978)

    Article  ADS  Google Scholar 

  67. Mahler, H.C., Friess, W., Grauschopf, U., Kiese, S.: J. Pharm. Sci. 98, 2909 (2009)

    Article  Google Scholar 

  68. Nelson, R., Sawaya, M.R., Balbirnie, M., Madsen, A.Ø., Riekeland, C., Grothe, R., Eisenberg, D.: Nature 435, 773 (2005)

    Article  ADS  Google Scholar 

  69. Summers, C.A., Flowers II, R.A.: Protein Sci. 9, 2001 (2000)

    Article  Google Scholar 

  70. Byrne, N., Wang, L.-M., Belieres, J.-P., Angell, C.A.: Chem. Commun. 2007, 2714 (2007)

    Article  Google Scholar 

  71. Lange, C., Patil, G., Rudolph, R.: Protein Sci. 14, 2693 (2005)

    Article  Google Scholar 

  72. Byrne, N.N., Angell, C.A.: Chem. Commun. 2009, 1046 (2009)

    Google Scholar 

  73. Zhang, S., Sun, N., He, X., Lu, X., Zhang, X.: J. Phys. Chem. Ref. Data 35, 1475 (2006)

    Article  ADS  Google Scholar 

  74. Van Wart, H.E., Lewis, A., Scheraga, H.A., Saevat, F.D.: Proc. Natl. Acad. Sci. 70, 2619 (1973)

    Article  ADS  Google Scholar 

  75. Sugeta, H.: Spectrochim. Acta 31A, 1729 (1975)

    Article  ADS  Google Scholar 

  76. Qian, W., Zhao, W., Krimm, S.: J. Mol. Struct. 1991(250), 89–102 (1991)

    Article  ADS  Google Scholar 

  77. Tu, A.T.: Spectroscopy of Biological System. Wiley and Sons, New York (1986). 47

    Google Scholar 

  78. Siamwiza, M.N., Lord, R.C., Chen, M.C., Takamatsu, T., Harada, I., Matsuura, H., Shimanouchi, T.: Biochemistry 14, 4870 (1975)

    Article  Google Scholar 

  79. Harada, I., Miura, T., Takeuchi, H.: Spectrochim. Acta, Part A 42, 307 (1986)

    Google Scholar 

  80. Wen, Z.Q., Cao, X., Vance, A.: J. Pharm. Sci. 976, 2228 (2008)

    Article  Google Scholar 

  81. Zhao, W., Yang, R.: J. Phys. Chem. B 114, 503 (2010)

    Article  Google Scholar 

  82. Torreggiani, A., Foggia, M.D., Manco, I., Maio, A.D., Markarian, S.A., Bonora, S.: J. Mol. Struct. 891, 115 (2008)

    Article  ADS  Google Scholar 

  83. Cho, T.Y., Byrne, N., Moore, D.J., Pethica, B.A., Angell, C.A., Debenedetti, P.G.: Chem. Commun. 2009, 4441 (2009)

    Article  Google Scholar 

  84. Williams, R.W.: Methods Enzymol. 130, 311 (1986)

    Article  Google Scholar 

  85. RCSB Protein Data Bank http://www.rcsb.org/pdb/explore/explore.do?structureId=2lyz

  86. Xu, M., Shashilov, V.A., Ermolenkov, V.V., Fredriksen, L., Zagorevski, D., Lednev, I.K.: Protein Sci. 16, 815 (2007)

    Article  Google Scholar 

  87. Gosal, W.S., Clark, A.H., Ross-Murphy, S.B.: Biomacromolecules 5, 2408 (2004)

    Article  Google Scholar 

  88. Popova, L.A., Kodali, R., Wetzel, R., Lednev, I.K.: J. Am. Chem. Soc. 2010(132), 6324–6328 (2010)

    Article  Google Scholar 

  89. Ionov, R., Hedoux, A., Guinet, Y., Bordat, P., Lerbret, A., Affouard, F., Prevost, Descamps, M.: J. Non-Cryst. Solids 352:4430 (2006)

    Google Scholar 

  90. Takeuchi, H., Harada, I.: Spectrochim. Acta 42A, 1069 (1986)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physics, La Sapienza University of Rome, P. Aldo Moro 5, 00185, Rome, Italy

    Sara Mangialardo & Paolo Postorino

  2. Department of Chemistry, La Sapienza University of Rome, P. Aldo Moro 5, 00185, Rome, Italy

    Enrico Bodo

  3. CNLS@Sapienza, Istituto Italiano di Tecnologia, V.le Regina Elena 291, 00161, Rome, Italy

    Leonetta Baldassarre

Authors
  1. Sara Mangialardo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Leonetta Baldassarre
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Enrico Bodo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Paolo Postorino
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Paolo Postorino .

Editor information

Editors and Affiliations

  1. Chimica, Università di Roma "la Sapienza", Rome, Italy

    Ruggero Caminiti

  2. Consiglio Nazionale delle Ricerche, Istituto di Struttura della Materia, Rome, Italy

    Lorenzo Gontrani

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Mangialardo, S., Baldassarre, L., Bodo, E., Postorino, P. (2014). Raman Spectroscopy in Ionic Liquids Under Variable Thermodynamic and Environmental Conditions. In: Caminiti, R., Gontrani, L. (eds) The Structure of Ionic Liquids. Soft and Biological Matter. Springer, Cham. https://doi.org/10.1007/978-3-319-01698-6_3

Download citation

Publish with us

Policies and ethics

Search

Navigation