Abstract
The synthesized novel Siamese-twin porphyrin LH4 was designed as a chelating macrocyclic ligand to bind two metals in close proximity. The twin N4 pockets are negatively charged twice after deprotonation. Most first row transition metals exhibit a stable oxidation state of 2 + [1]. With these M2+ metals, neutral complexes of the Siamese-twin porphyrin can be formed and the oxidation of neutral complexes usually is easier compared to positively charged complexes. This may facilitate the formation of high-valent species, including metal-oxo species.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
N.N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd edn. (Butterworth–Heinemann, Amsterdam, 1997)
H. Irving, R.J.P. Williams, Nature 162, 746–747 (1948)
H. Irving, R.J.P. Williams, J. Am. Chem. Soc. 1953, 3192–3210
A.F. Holleman, N. Wiberg, Lehrbuch der Anorganischen Chemie, 102nd edn. (Walter de Gruyter, Berlin, 2007)
N. Wheatley, P. Kalck, Chem. Rev. 99, 3379–3420 (1999)
E.K. van den Beuken, B.L. Feringa, Tetrahedron 54, 12985–13011 (1998)
P.A. Shapley, N. Zhang, J.L. Allen, D.H. Pool, H.-C. Liang, J. Am. Chem. Soc. 122, 1079–1091 (2000)
K. Severin, Chem. Eur. J. 8, 1514–1518 (2002)
D.W. Stephan, Coord. Chem. Rev. 95, 41–107 (1989)
Y. Yang, K.A. Abboud, L. McElwee-White, Dalton Trans. 22, 4288–4296 (2003)
E. Riedel, Moderne Anorganische Chemie, 3rd edn. (de Gruyter, Berlin, 2009)
J. Klingele, S. Dechert, F. Meyer, Coord. Chem. Rev. 253, 2698–2741 (2009)
A.L. Gavrilova, B. Bosnich, Chem. Rev. 104, 349–384 (2004)
N.M. Atherton, Principles of Electron Spin Resonance (Ellis Horwood PTR Prentice Hall, New York, 1993)
K. A. Sandberg, Ph.D. thesis, Theoretical Investigations of Spin–Spin Interactions:Semiempirical Estimations of the Exchange Parameter for Diradical Metalloporphyrin Cations and Zero Field Splitting Parameter for Conjugated Diradicals (NC State University, 1998)
P.W. Atkins, Physikalische Chemie, 3rd edn. (WILEY-VCH, Weinheim, 2001)
O. Kahn, Molecular Magnetism (Wiley-VCH, Weinheim, 1993)
L.K. Frensch, K. Pröpper, M. John, S. Demeshko, C. Brückner, F. Meyer, Angew. Chem. Int. Ed. 50, 1420–1424 (2011)
D. Ajo, A. Bencini, F. Mani, Inorg. Chem. 27, 2437–2444 (1988)
V.P. Hanot, T.D. Robert, J. Kolnaar, J.P. Haasnoot, J. Reedijk, H. Kooijman, A.L. Spek, J. Chem. Soc. Dalton Trans. 22, 4275–4281 (1996)
H. Matsushima, H. Hamada, K. Watanabe, M. Koikawa, T. Tokii, J. Chem. Soc., Dalton Trans. 971–977 (1999)
W. Plass, Chem. Unserer Zeit 32, 323–333 (1998)
T.-L. Hu, J.-R. Li, C.-S. Liu, X.-S. Shi, J.-N. Zhou, X.-H. Bu, J. Ribas, Inorg. Chem. 45, 162–173 (2005)
J. Teichgräber, G. Leibeling, S. Dechert, F. Meyer, Z. Anorg, Allg. Chem. 631, 2613–2618 (2005)
R.S. Drago, Physical Methods for Chemists, 2nd edn. (Saunders College Publishing, New York, 1992)
T. Ohnishi, Biochimica et Biophysica Acta (BBA) - Bioenergetics 1364, 186–206 (1998)
X. Liu, J.A. McAllister, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner, M.A. Halcrow, Chem. Eur. J. 10, 1827–1837 (2004)
M. Heichel, P. Höfer, A. Kamlowski, M. Griffin, A. Muys, C. Noble, D. Wang, G.R. Hanson, C. Eldershaw, K.E. Gates, K. Burrage, Bruker Report 148, 6–9 (2000)
D. Meschede, Gerthsen Physik, 23rd edn. (Springer, Berlin, 2006)
M.K. Johnsons, in Physical Methods in Bioinorganic Chemistry, ed. by J. Lawrence Que (University Science Books, Sausalito, 2000)
M.G.I. Galinato, T. Spolitak, D.P. Ballou, N. Lehnert, Biochemistry 50, 1053–1069 (2010)
J. Mack, M.J. Stillman, N. Kobayashi, Coord. Chem. Rev. 251, 429–453 (2007)
J.-J. Girerd, Y. Journaux, ed. by J. Lawrence Que (University Science Books, Sausalito, 2000)
R. Krishnan, J.S. Binkley, R. Seeger, J.A. Pople, J. Chem. Phys. 72, 650–654 (1980)
K. Raghavachari, G.W. Trucks, J. Chem. Phys. 91, 2457–2460 (1989)
B. Dittrich, T. Koritsánszky, P. Luger, Angew. Chem. Int. Ed. 43, 2718–2721 (2004)
C.J. O’Connor, Prog. Inorg. Chem. 29, 203–283 (1982)
G.A. Bain, J.F. Berry, J. Chem. Educ. 85, 532 (2008)
L.K. Blusch, Y. Hemberger, K. Pröpper, B. Dittrich, F. Witterauf, M. John, G. Bringmann, C. Brückner, F. Meyer, Chem. Eur. J. 19, 5868–5880 (2013)
B. Dittrich, C.B. Hübschle, M. Messerschmidt, R. Kalinowski, D. Girnt, P. Luger, Acta Crystallogr. Sect. A Found. Crystallogr. A61, 314–320 (2005)
B. Dittrich, C.B. Hübschle, P. Luger, M.A. Spackman, Acta Crystallogr. Sect. D Biol. Crystallogr. D62, 1325–1335 (2006)
L.K. Blusch, K.E. Craigo, V. Martin-Diaconescu, E. Bill, A. B. McQuarters, S. Dechert, S. DeBeer, N. Lehnert, F. Meyer, J. Am. Chem. Soc. DOI:10.1021/ja406176e
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2013 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Blusch, L.K. (2013). Nickel and Copper Complexes. In: The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-01674-0_5
Download citation
DOI: https://doi.org/10.1007/978-3-319-01674-0_5
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-01673-3
Online ISBN: 978-3-319-01674-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)