Abstract
The aim of SAS experiments is to extract volume-averaged information on the spatial distribution of scattering length density (neutrons) or the electron density (x-rays) in the sample from the measured differential cross section as a function of scattering vector. Correlation functions can be calculated directly from the SAS data and deliver information on the sample structure. This chapter begins with a brief description of the mathematical form and geometrical meaning of correlation functions, which enter theory of scattering from the two-phase random systems. Asymptotic behavior of scattering in the limit of low and high values of the scattering vector is considered, together with the unified scattering function, which bridges the Guinier and Porod scattering regimes. The rest of the chapter deals with the scattering theory from fractal systems and possible extension of the theory of scattering from the two-phase to multiphase systems.
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Debye, P., Bueche, A.M.: Scattering by an inhomogeneous fluid. J. Appl. Phys. 20, 518 (1949)
Feigin, L.A., Svergun, D.I.: Structure Analysis by Small-Angle X-Ray and Neutron Scattering. Plenum, New York, London (1987)
Bale, H.D., Schmidt, P.W.: Small-angle X-ray scattering investigation of submicroscopic porosity with fractal properties. Phys. Rev. Lett. 53, 596 (1984)
Kjems, J.K., Schofield, P.: Neutron and X-ray studies of interfaces. In: Pynn, R., Skjeltorp, A. (eds.) Scaling Phenomena in Disordered Systems (NATO ASI Series B: Physics). Springer, New Year (1991)
Wong, P.Z., Bray, A.J.: Fractal dimension of rough surfaces in the solid-on-solid model. Phys. Rev. Lett. 59, 1057 (1987)
Kjems, J.K., Freltoft, T.: Neutron and X-ray scattering from aggregates. In: Pynn, R., Skjeltorp, A. (eds.) Scaling Phenomena in Disordered Systems (NATO ASI Series B: Physics). Springer, New York (1991)
Teixeira, J.: Experimental methods for studying fractal aggregates. In: Stanley, H.E., Ostrowski, N. (eds.) On the Growth and Form: Fractal and Non-fractal Patterns in Physics (NATO Science series E: Applied Sciences). Springer, New York (1986)
Teixeira, J.: Small-angle scattering by fractal systems. J. Appl. Crystallogr. 21, 781 (1988)
Porod, G.: General theory. In: Glatter, O., Kratky, O. (eds.) Small Angle X-Ray Scattering. Academic, London (1982)
Debye, P., Anderson, H.R., Brumberger, H.: Scattering by an inhomogeneous solid. 2. The correlation function and its application. J. Appl. Phys. 28, 679 (1957)
Melnichenko, Y.B., Wignall, G.D., Cole, D.R., Frielinghaus, H.: Adsorption of supercritical CO2 in aerogels as studied by small-angle neutron scattering and neutron transmission techniques. J. Chem. Phys. 124, 204711 (2006)
Kirste, V.R., Pord, G.: Rontgenkleinwinkwlstreum an kolloiden systemen—asymptotisches verhalten der streukurven. Colloid Polym. Sci. 184, 1 (1962)
Auvray, L., Auroy, P.: Scattering at interfaces: variations on Porod’s Law. In: Lindner, P., Zemb, T. (eds.) Neutron, X-Ray and Light Scattering: Introduction to an Investigative Tool for Colloidal and Polymeric Systems. North-Holland, Amsterdam (1991)
Glatter, O., Kratky, O. (eds.): Small Angle X-Ray Scattering. Academic, London, New York (1982). A PDF file with this book is available at: http://physchem.kfunigraz.ac.at/sm/Software.htm
Melnichenko, Y.B., Wignall, G.D., Compton, R.N., Bakale, G.: Characterization of fullerenes and fullerene derivatives by small-angle neutron scattering and transmission measurements. J. Chem. Phys. 111, 4724 (1999)
Roe, R.J.: Methods of X-Ray and Neutron Scattering in Polymer Science. Oxford University Press, New York, Oxford (2000)
Hoinkis, E.: Small-angle scattering of neutrons and X-rays from carbons and graphites. In: Thrower, P.A. (ed.) Chemistry and Physics of Carbon. Marcel Dekker, New York (1997)
Beaucage, G., Schaefer, D.W.: Structural studies of complex systems using small-angle scattering—a unified Guinier power—law approach. J. Non-Cryst. Solids 172–174, 797 (1994)
Beaucage, G.: Approximations leading to a unified exponential power-law approach to small-angle scattering. J. Appl. Crystallogr. 28, 717 (1995)
Beaucage, G.: Small-angle scattering from polymeric mass fractals of arbitrary mass-fractal dimension. J. Appl. Crystallogr. 29(134) (1996)
Chathoth, S.M., He, L., Mamontov, E., Melnichenko, Y.B.: Effect of carbon dioxide and nitrogen on the diffusivity of methane confined in nano-porous carbon aerogel. Micropor. Mesopor. Mat. 148, 101 (2012)
Mandelbrot, B.B.: The Fractal Geometry of Nature. Freeman, San Francisco (1983)
Avnir, D., Biham, O., Lidar, D., Malcai, O.: Is the geometry of nature fractal? Science 279, 39 (1997)
Radlinski, A.P., Radlinska, E.Z., Agamalian, M., Wignall, G.D., Lindner, P., Randl, O.G.: Fractal geometry of rocks. Phys. Rev. Lett. 82, 3078 (1999)
Ruppert, L.F., Sakurovs, R., Blach, T.P., He, L., Melnichenko, Y.B., Mildner, D.F.R., Alcantar-Lopez, L.: A USANS/SANS study of the accessibility of pores in the Barnett shale to methane and water. Energy Fuel 27, 772 (2013)
Schaefer, D.W., Keefer, K.D.: Fractal geometry of silica condensation polymers. Phys. Rev. Lett. 53, 1383 (1984)
Pfeifer, P.: Mapping a Pore Fractal. Physics News Update No. 578 (American Institute of Physics, 27 Feb 2002). Reproduced with permission. The original image may be viewed at http://www.fractal.org/Life-Science-Technology/Publications/Pore-fractal.htm
Pfeifer, P., Ehrburger-Dolle, F., Rieker, T.P., Gonzalez, M.T., Hoffman, W.P., Molina-Sabio, M., Rodriguez-Reinoso, F., Schmidt, P.W., Voss, D.J.: Nearly space-filling fractal networks of carbon nanopores. Phys. Rev. Lett. 88, 115502 (2002)
Freltoft, T., Kjems, J.K., Sinha, S.K.: Power-law correlations and finite size effects in silica particle aggregates studied by small-angle neutron scattering. Phys. Rev. B 33, 269 (1986)
Vonk, C.G.: Investigation of non-ideal 2-phase polymer structures by small-angle X-ray scattering. J. Appl. Crystallogr. 6, 81 (1973)
Ruland, W.: Small-angle scattering of 2-phase systems—determination and significance of systematic deviations from Porod law. J. Appl. Crystallogr. 4, 70 (1971)
Koberstein, J.T., Morra, B., Stein, R.S.: Determination of diffuse-boundary thicknesses of polymers by small-angle X-ray scattering. J. Appl. Crystallogr. 13, 34 (1980)
Schmidt, P.W., Avnir, D., Levy, D., Hohr, A., Steiner, M., Roll, A.: Small-angle X-ray scattering from the surfaces of reversed-phase silicas—power-law scattering exponents of magnitudes greater than 4. J. Chem. Phys. 94(1474) (1991)
Li, Z.H., Gong, Y.J., Wu, D., Sun, Y.H., Wang, J., Liu, Y., Dong, B.Z.: A negative deviation from Porod’s law in SAXS of organo-MSU-X. Micropor. Mesopor. Mat. 46, 75 (2001)
Radlinski, A.P.: Small-angle neutron scattering and the microstructure of rocks. Rev. Miner. Geochem. 63, 363 (2006)
Schmidt, P.W.: Interpretation of small-angle scattering curves proportional to a negative power of the scattering vector. J. Appl. Crystallogr. 15, 567 (1982)
Hinde, A.L.: PRINSAS—a windows-based computer program for the processing and interpretation of small-angle scattering data tailored to the analysis of sedimentary rocks. J. Appl. Crystallogr. 37, 1020 (2004)
Radlinski, A.P., Ioannidis, M.A., Hinde, A.L., Hainbuchner, M., Baron, M., Rauch, H., Kline, S.R.: Angstrom-to-millimeter characterization of sedimentary rock microstructure. J. Colloid Interface Sci. 274, 607 (2004)
Radlinski, A.P., Boreham, C.J., Lindner, P., Randl, O., Wignall, G.D., Hinde, A., Hope, J.M.: Small angle neutron scattering signature of oil generation in artificially and naturally matured hydrocarbon source rocks. Org. Geochem. 31, 1 (2000)
Israelachvili, J.N.: Forces between surfaces in liquids. Adv. Colloid Interface Sci. 16, 31 (1982)
Higgins, J.S., Benoit, H.C.: Polymers and Neutron Scattering. Clarendon, Oxford (1994)
Bacon, G.E.: Neutron Diffraction. Clarendon, Oxford (1975)
Endo, H., Schwahn, D., Colfen, H.: On the role of block copolymer additives for calcium carbonate crystallization: small angle neutron scattering investigation by applying contrast variation. J. Chem. Phys. 120, 9410 (2004)
Hoinkis, E., Allen, A.J.: A small-angle neutron scattering study of porous graphitic materials before and after adsorption and condensation of C6D6 within the accessible pores. J. Colloid Interface Sci. 145, 540 (1991)
Wu, W.L.: Small-angle X-ray study of particulate reinforced composites. Polymer 23, 1907 (1982)
Peterlin, A.: Small-angle scattering by a 3 component system. Macromol. Chem. Phys. 87, 152 (1965)
Melnichenko, Y.B., Wignall, G.D.: Small-angle neutron scattering in materials science: recent practical applications. J. Appl. Phys. 102, 021101 (2007)
Rother, G., Melnichenko, Y.B., Wignall, G.D., Cole, D.R., Frielinghaus, H.: Microstructural characterization of adsorption and depletion regimes of supercritical fluids in nanopores. J. Phys. Chem. C 111, 15736 (2007)
Melnichenko, Y.B., Wignall, G.D.: Density and volume fraction of supercritical CO2 in pores of native and oxidized aerogels. Int. J. Thermophys. 30, 1578 (2009)
Ciccariello, S.: The best two-phase idealization of a sample in small-angle scattering. Acta Crystallogr. A 58, 460 (2002)
Pikus, S., Kobylas, E., Ciccariello, S.: Small-angle scattering characterization of n-aliphatic alcohol films adsorbed on hydroxyled porous silicas. J. Appl. Crystallogr. 36, 744 (2003)
Ciccariello, S., Melnichenko, Y.B., He, L.: Supercritical carbon dioxide behavior in porous silica aerogel. J. Appl. Crystallogr. 44, 43 (2011)
Ciccariello, S., Melnichenko, Y.B., He, L.: Phase behavior of carbon dioxide confined in silica aerogel in the vicinity of the bulk critical point. J. Phys. Chem. C 115, 22336 (2011)
Melnichenko, Y.B., Ciccariello, S.: Small-angle neutron scattering study of deuterated propane adsorption in silica aerogel. J. Phys. Chem. C 116, 24661 (2012)
Bahadur, J., Radlinski, A., Melnichenko, Y.B., Mastalerz, M., Schimmelmann, A.: SANS/USANS study of the New Albany Shale: a treatise on microporisity. Energy Fuel 29, 576 (2015)
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Melnichenko, Y.B. (2016). Fundamentals of Data Analysis. In: Small-Angle Scattering from Confined and Interfacial Fluids. Springer, Cham. https://doi.org/10.1007/978-3-319-01104-2_6
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DOI: https://doi.org/10.1007/978-3-319-01104-2_6
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