Abstract
In the past decade, significant theoretical progress has been made in understanding the regime where electrostatic ion correlations dominate in a classical Coulomb fluid, i.e., the strong-coupling limit (SC). The SC models are often based on the picture of a 2-dimensional ionic layer near the charged surface due to Rouzina and Bloomfield [1]. These authors proposed that the character of electrostatic correlations amongst counter-ions near a charged surface is 2-dimensional rather than 3-dimensional.
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Rouzina, I., Bloomfield, V.A.: Macroion attraction due to electrostatic correlation between screening counterions. 1. mobile surface-adsorbed ions and diffuse ion cloud. J. Phys. Chem. 100, 9977 (1996)
Shklovskii, B.: Wigner crystal model of counterion induced bundle formation of rodlike polyelectrolytes. Phys. Rev. Lett. 82(16), 3268–3271 (1999)
Grosberg, A.Y., Nguyen, T.T., Shklovskii, B.I.: The physics of charge inversion in chemical and biological systems. Rev. Mod. Phys. 74, 329 (2002)
Moreira, A.G., Netz, R.R.: Binding of similarly charged plates with counterions only. Phys. Rev. Lett. 87(7), 078301 (2001)
Šamaj, L., Trizac, E.: Counterions at highly charged interfaces: From one plate to like-charge attraction. Phys. Rev. Lett. 106(7), 078301 (2011)
Stevens, M., Robbins, M.: Density functional theory of ionic screening: when do like charges attract? Europhys. Lett. 12, 81–86 (1990)
Penfold, R., Nordholm, S., Jonsson, B., Woodward, C.E.: A simple analysis of ion-ion correlation in polyelectrolyte solutions. J. Chem. Phys. 92(3), 1915 (1990)
Nordholm, S.: Simple analysis of the thermodynamic properties of the one-component plasma. Chem. Phys. Lett. 105, 301 (1984)
Groot, R.D.: Ion condensation on solid particles: theory and simulations. J. Chem. Phys. 95(12), 9191 (1991)
Diehla, A., Tamashiro, M.N., Barbosa, M.C., Levin, Y.: Density-functional theory for attraction between like-charged plates. Phys. A 274, 433–445 (1999)
Barbosa, M.C., Deserno, M., Holm, C.: A stable local density functional apporach to ion-ion correlations. Europhys. Lett. 52, 80 (2000)
Kjellander, R., Marcelja, S.: Inhomogeneous coulomb fluids with image interactions between planar surfaces. i. J. Chem. Phys. 82(4), 2122 (1985)
Kjellander, R.: Inhomogeneous coulomb fluids with image interactions between planar surfaces. ii. on the anisotropic hypernetted chain approximation. J. Chem. Phys. 88(11), 7129 (1988)
Kjellander, R., Marcelja, S.: Inhomogeneous coulomb fluids with image interactions between planar surfaces. iii. distribution functions. J. Chem. Phys. 88(11), 7138 (1988)
Kjellander, R., et al.: Double-layer ion correlation forces restrict calcium-clay swelling. J. Phys. Chem. 92, 6489–6492 (1988)
Wernersson, E., Kjellander, R., Lyklema, J.: Charge inversion and ion ion correlation effects at the mercury/aqueous MgSO\(_{4}\) interface: toward the solution of a long-standing issue. J. Phys. Chem. C 114, 1849–1866 (2010)
Wang, W., Park, R.Y., Travesset, A., Vaknin, D.: Ion-specific induced charges at aqueous soft interfaces. Phys. Rev. Lett. 106(5), 056102 (2011)
Martín-Molina, A., Rodríguez-Beas, C., Faraudo, J.: Charge reversal in anionic liposomes: experimental demonstration and molecular origin. Phys. Rev. Lett. 104(16), 168103 (2010)
Debye, P. Hückel, E.: The theory of electrolytes. i. lowering of freezing point and related phenomena. Phys. Z. 24, 185–206 (1923)
Levin, Y.: Electrostatic correlations: from plasma to biology. Rep. Prog. Phys. 65, 1577 (2002)
Baus, M., Hansen, J.-P.: Statistical mechanics of simple coulomb systems. Phys. Rep. 59(1), 1–94 (1980)
Luo, G., Malkova, S., Yoon, J., Schultz, D.G., Lin, B., Meron, M., Benjamin, I., Vanysek, P., Schlossman, M.L.: Ion distributions at the nitrobenzene-water interface electrified by a common ion. J. Electroanal. Chem. 593, 142–158 (2006)
Luo, G., Malkova, S., Yoon, J., Schultz, D.G., Lin, B., Meron, M., Benjamin, I., Vanysek, P., Schlossman, M.L.: Ion distributions near a liquid-liquid interface. Science 311, 216–218 (2006)
Wick, C.D., Dang, L.X.: Molecular dynamics study of ion transfer and distribution at the interface of water and 1,2-dichloroethane. J. Phys. Chem. C 112(3), 647–649 (2008)
Hou, B.: Ion distributions at electrified liquid-liquid interfaces: an agreement between X-ray reflectivity analysis and macroscopic measurements. Doctoral dissertation, University of Illinois at Chicago (2011)
Tarazona, P.: Free-energy density functional for hard spheres. Phys. Rev. A 31(4), 2672 (1985)
Curtin, W., Ashcroft, N.: Phys. Rev. A 32, 2909 (1985)
Mitrinovic, D.M., Tikhonov, A.M., Li, M., Huang, Z., Schlossman, M.L.: Noncapillary-wave structure at the water-alkane interface. Phys. Rev. Lett. 85, 582 (2000)
Buff, F.P., Lovett, R.A., Stillinger, F.H.: Interfacial density profile for fluids in the critical region. Phys. Rev. Lett. 15, 621 (1965)
Laanait, N., Yoon, J., Hou, B., Vanysek, P., Meron, M., Lin, B., Luo, G., Benjamin, I., Schlossman, M.: Communications: monovalent ion condensations at the electrified liquid/liquid interface. J. Chem. Phys. 132, 171101 (2010)
Torrie, G., Valleau, J.: Double layer structure at the interface between two immiscible electrolyte solutions. J. Electroanal. Chem. 206, 69–79 (1986)
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Laanait, N. (2013). The Role of Electrostatic Ion Correlations in Ion Condensation. In: Ion Correlations at Electrified Soft Matter Interfaces. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-00900-1_7
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DOI: https://doi.org/10.1007/978-3-319-00900-1_7
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