Skip to main content
SpringerLink
Log in

Herbicide Analysis Using a New OPIE. A Case Study: Sunflower Oil

  • Conference paper
  • First Online:
Sensors and Microsystems

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 268))

  • 2375 Accesses

Abstract

Traces of several herbicides belonging to different classes of pesticide were tested in sunflower oil, and good results were obtained using a new organic phase immuno-electrode (OPIE). Both the competition step and the final enzymatic measure were carried out in optimised organic solvents. Using the new OPIE the pesticides 2,4-D and 2,4,5-T (i.e. agent orange herbicides), atrazine and simazine (triazinic pesticides) and parathion (organophosphate pesticide) were tested without problems in sunflower oil.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. J. Wang, Y. Lin, Q. Chen, “Organic-phase biosensors for monitoring phenol and hydrogen peroxide in pharmaceutical antibacterial products”, Analyst, 118 (1993), 277-283.

    Article  Google Scholar 

  2. J. Wang, E. Demsey, A. Eremenko, and M. R. Smyth, “Organic-Phase Biosensing of Enzyme Inhibitors” Anal. Chim. Acta. 279 (1993), 203-208.

    Article  Google Scholar 

  3. E.I. Iwuoha, D. Saenz de Villaverde, N.P. Garcia, M.R. Smyth, J.M. Pingarron, “Reactivities of organic phase biosensors. 2. The amperometric behaviour of horseradish peroxidase immobilised on a platinum electrode modified with an electrosynthetic polyaniline film”, Biosens. Bioelectron. 12 (1997), 749-755.

    Article  Google Scholar 

  4. L. Campanella, A. Bonanni, E. Martini, N. Todini, M. Tomassetti, Determination of triazine pesticides using a new enzyme inhibition tyrosinase OPEE operating in chloroform, Sens. Act. B, Chem. 111-112 (2005) 505-511.

    Article  Google Scholar 

  5. L. Campanella, R. Dragone, D. Lelo, E. Martini, M. Tomassetti, “Inhibition tyrosinase organic phase biosensor for triazinic and benzotriazinic pesticides analysis”, Anal. Bioanal. Chem., 384 (2006) 915-921.

    Article  Google Scholar 

  6. L. Campanella, D. Lelo, E. Martini, M. Tomassetti, “Organophosphorus and carbamate pesticide analysis using an inhibition tyrosinase organic phase enzyme sensor; comparison by butyrylcholinesterase + choline oxidase OPEE and application to natural waters”, Anal. Chim. Acta, 587 (2007), 22-32.

    Article  Google Scholar 

  7. L. Campanella, E. Martini, M. Tomassetti, “Immunochemical potentiometric method for HIgG And Anti-HIgG determination, using a NH3 probe and the immunoprecipitation as preconcentration procedure”, Anal. Lett. 40 (2007), 113-125.

    Article  Google Scholar 

  8. L. Campanella, D. Lelo, E. Martini, M. Tomassetti, “Immunoglobulin G determination in human serum and human milk using an immunosensor of new conception fitted with an enzyme probe as transducer”, Sensors 8 (2008), 6727-676.

    Article  Google Scholar 

  9. L. Campanella, E. Martini, M. Pintore, M. Tomassetti, “Lactoferrin And Immunoglobulin G Determination In Animal Milk By New Immunosensors”, Sensors 9 (2009), 2202-2221.

    Article  Google Scholar 

  10. L. Campanella, E. Martini, M. Tomassetti, Further development of lactoferrin immunosensor (part III). J. Pharm. Biomed. Anal. 53 (2010), 186-195

    Article  Google Scholar 

  11. L. Campanella, S. Eremin, D. Lelo. E. Martini, M. Tomassetti, Reliable new immunosensor for atrazine pesticide analysis, Sens. Act. B, Chem. 156 (2011) 501-515.

    Article  Google Scholar 

  12. M. Tomassetti, E. Martini, L. Campanella, New immunosensors operating in organic phase (OPIEs) for analysis of triazinic pesticides in olive oil, Electroanalysis 24 (4) (2012) 842-856.

    Article  Google Scholar 

  13. L. Rastrelli, K. Totaro, F. De Simone, “Determination of organophosphorus pesticide residues in Cilento (Campania, Italy) virgin olive oil by capillary gas chromatography”, Food Chem. 79(3) (2002), 303–305.

    Article  Google Scholar 

  14. N. M. Randolph, H. W. Dorough, G. L. Teetes, “Malathion, methyl parathion, diazinon, and endosulfan residues in sunflower seeds” J. Econ. Entomol. 62(2) (1969), 462-464.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Rome “Sapienza”, p.le A. Moro, 5, 00183, Rome, Italy

    E. Martini, M. Tomassetti & L. Campanella

Authors
  1. E. Martini
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Tomassetti
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Campanella
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Tomassetti .

Editor information

Editors and Affiliations

  1. Dept. of Electronic Engineering, University of Rome Tor Vergata, Rome, Italy

    Corrado Di Natale

  2. Department of Information Engineering, University of Brescia, Brescia, Italy

    Vittorio Ferrari

  3. SENSOR Laboratory, IDASC, National Research Council (CNR), Brescia, Italy

    Andrea Ponzoni

  4. Department of Information Engineering, University of Brescia, Brescia, Italy

    Giorgio Sberveglieri

  5. Department of Information Engineering, University of Brescia, Brescia, Italy

    Marco Ferrari

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer International Publishing Switzerland

About this paper

Cite this paper

Martini, E., Tomassetti, M., Campanella, L. (2014). Herbicide Analysis Using a New OPIE. A Case Study: Sunflower Oil. In: Di Natale, C., Ferrari, V., Ponzoni, A., Sberveglieri, G., Ferrari, M. (eds) Sensors and Microsystems. Lecture Notes in Electrical Engineering, vol 268. Springer, Cham. https://doi.org/10.1007/978-3-319-00684-0_30

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-00684-0_30

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-00683-3

  • Online ISBN: 978-3-319-00684-0

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics

Search

Navigation