Abstract
The integration of optical elements that increase the photon path length in the light absorbing layer is a promising strategy to increase device efficiency of dye-sensitised solar cells (DSC). Device architectures that incorporate structural order in form of a three-dimensional photonic crystal can lead to the localization of light in specific parts of the spectrum, while retaining the cell’s transparency in others. In this chapter, a first successful route is presented that allowed the experimental realisation of a double layer electrode architecture, including a mesoporous TiO2 underlayer and a macroporous TiO2 inverse opal top layer. This construct enables effective dye sensitisation, electrolyte infiltration, and charge collection from both layers, opening up additional parameter space for effective light management by harvesting photonic crystal-induced resonances.
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References
S. Guldin, S. Hüttner, M. Kolle, M. Welland, P. Müller-Buschbaum, R. Friend, U. Steiner, N. Tetreault, Dye-sensitized solar cell based on a three-dimensional photonic crystal. Nano Lett. 10(7), 2303–2309 (2010)
S. Guldin, P. Docampo, S. Hüttner, P. Kohn, M. Stefik, H.J. Snaith, U. Wiesner, U. Steiner, Self-assembly as a design tool for the integration of photonic structures into excitonic solar cells, in Proceedings of the SPIE, vol. 8111 (2011). doi:10.1117/12.893798
B. O‘Regan, M. Grätzel, A low-cost, high-efficiency solar-cell based on dye-sensitized colloidal TiO\(_2\) films. Nature 353(6346), 737–740 (1991)
J. Kroon, N. Bakker, H. Smit, P. Liska, K. Thampi, P. Wang, S. Zakeeruddin, M. Grätzel, A. Hinsch, S. Hore, U. Würfel, R. Sastrawan, J. Durrant, E. Palomares, H. Pettersson, T. Gruszecki, J. Walter, K. Skupien, G. Tulloch, Nanocrystalline dye-sensitized solar cells having maximum performance. Prog. Photovoltaics 15(1), 1–18 (2007)
Z. Wang, H. Kawauchi, T. Kashima, H. Arakawa, Significant influence of TiO\(_2\) photoelectrode morphology on the energy conversion efficiency of N719 dye-sensitized solar cell. Coord. Chem. Rev. 248(13–14), 1381–1389 (2004)
J.-H. Yum, E. Baranoff, S. Wenger, M. Nazeeruddin, M. Grätzel, Panchromatic engineering for dye-sensitized solar cells. Energ. Environ. Sci. 4(3), 842–857 (2011)
J. Ferber, J. Luther, Computer simulations of light scattering and absorption in dye-sensitized solar cells. Solar Energ. Mater. Solar Cells 54(1–4), 265–275 (1998)
S. Hore, C. Vetter, R. Kern, H. Smit, A. Hinsch, Influence of scattering layers on efficiency of dye-sensitized solar cells. Solar Energ. Mater. Solar Cells 90(9), 1176–1188 (2006)
Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide, L. Han, Dye-sensitized solar cells with conversion efficiency of 11.1%, Jpn. J. Appl. Phys. Part 2 Lett. Express Lett. 45(24–28), L638–L640 (2006)
M. Nazeeruddin, T. Bessho, L. Cevey, S. Ito, C. Klein, F. De Angelis, S. Fantacci, P. Comte, P. Liska, H. Imai, M. Grätzel, A high molar extinction coefficient charge transfer sensitizer and its application in dye-sensitized solar cell. J. Photochem. Photobiol. A Chem. 185(2–3), 331–337 (2007)
S. Nishimura, N. Abrams, B. Lewis, L. Halaoui, T. Mallouk, K. Benkstein, J. van de Lagemaat, A. Frank, Standing wave enhancement of red absorbance and photocurrent in dye-sensitized titanium dioxide photoelectrodes coupled to photonic crystals. J. Am. Chem. Soc. 125(3), 6306–6310 (2003)
L. Halaoui, N. Abrams, T. Mallouk, Increasing the conversion efficiency of dye-sensitized TiO\(_2\) photoelectrochemical cells by coupling to photonic crystals. J. Phys. Chem. B 109(13), 6334–6342 (2005)
S. Colodrero, A. Mihi, L. Haggman, M. Ocaña, G. Boschloo, A. Hagfeldt, H. Míguez, Porous one-dimensional photonic crystals improve the power-conversion efficiency of dye-sensitized solar cells. Adv. Mater. 21(7), 764–770 (2009)
D. Colonna, S. Colodrero, H. Lindstrom, A. Di Carlo, H. Míguez, Introducing structural colour in dscs by using photonic crystals: interplay between conversion efficiency and optical properties. Energ. Environ. Sci. (2012). doi:10.1039/C2EE02658A
K. Sakoda, Enhanced light amplification due to group-velocity anomaly peculiar to two- and three-dimensional photonic crystals. Opt. Express 4(5), 167–176 (1999)
D. Mittleman, J. Bertone, P. Jiang, K. Hwang, V. Colvin, Optical properties of planar colloidal crystals: dynamical diffraction and the scalar wave approximation. J. Chem. Phys. 111(1), 345–354 (1999)
R. Rengarajan, D. Mittleman, C. Rich, V. Colvin, Effect of disorder on the optical properties of colloidal crystals. Phys. Rev. E 71(1), Part 2, 15968–15976 (2005)
A. Mihi, H. Míguez, Origin of light-harvesting enhancement in colloidal-photonic-crystal-based dye-sensitized solar cells. J. Phys. Chem. B 109(33), 15968–15976 (2005)
S. Ito, S. Zakeeruddin, P. Comte, P. Liska, D. Kuang, M. Grätzel, Bifacial dye-sensitized solar cells based on an ionic liquid electrolyte. Nat. Photonics 2(11), 693–698 (2008)
A. Mihi, F. Lopez-Alcaraz, H. Míguez, Full spectrum enhancement of the light harvesting efficiency of dye sensitized solar cells by including colloidal photonic crystal multilayers. Appl. Phys. Lett. 88(19), 193110 (2006)
R. Pozas, A. Mihi, M. Ocana, H. Míguez, Building nanocrystalline planar defects within self-assembled photonic crystals by spin-coating. Adv. Mat. 18(9), 1183–1187 (2006)
A. Mihi, M.E. Calvo, J. Anta, H. Míguez, Spectral response of opal-based dye-sensitized solar cells. J. Phys. Chem. C 112(1), 13–17 (2008)
S.-H.A. Lee, N. Abrams, P. Hoertz, G. Barber, L. Halaoui, T. Mallouk, Coupling of titania inverse opals to nanocrystalline titania layers in dye-sensitized solar cells. J. Phys. Chem. B 112(46), 14415–14421 (2008)
M. Nedelcu, S. Guldin, M. Orilall, J. Lee, S. Hüttner, E. Crossland, S. Warren, C. Ducati, P. Laity, D. Eder, U. Wiesner, U. Steiner, H. Snaith, Monolithic route to efficient dye-sensitized solar cells employing diblock copolymers for mesoporous TiO\(_2\). J. Mater. Chem. 20(7), 1261–1268 (2010)
P. Jiang, J. Bertone, K. Hwang, V. Colvin, Single-crystal colloidal multilayers of controlled thickness. Chem. Mater. 11(8), 2132–2140 (1999)
H. Míguez, G. Ozin, S. Yang, N. Tetreault, Mechanical stability enhancement by pore size connectivity control in colloidal crystals by layer-by-growth of oxide, U.S. Patent App. 11/878,023, 2007
S. Guldin, Nanostructuring inorganic material by copolymer-assisted self-assembly and its multifunctional use for dye-sensitised solar cells, Master’s thesis, Technische Universität München, 2008
A. Usami, Theoretical study of application of multiple scattering of light to a dye-sensitized nanocrystalline photoelectrochemical cell. Chem. Phys. Lett. 277(1–3), 105–108 (1997)
M. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Muller, P. Liska, N. Vlachopoulos, M. Grätzel, Conversion of light to electricity by cis-x2bis(2,2’-bipyridyl-4,4’-dicarboxylate)ruthenium(ii) charge-transfer sensitizers (X = Cl-, Br-, I-, Cn-, and Scn-) on nanocrystalline TiO\(_2\) electrodes. J. Am. Chem. Soc. 115(14), 6382–6390 (1993)
Y. Seo, K. Woo, J. Kim, H. Lee, W. Lee, Rapid fabrication of an inverse opal TiO\(_2\) photoelectrode for DSSC using a binary mixture of TiO\(_2\) nanoparticles and polymer microspheres. Adv. Funct. Mater. 21(16), 3094–3103 (2011)
A. Mihi, C. Zhang, P. Braun, Transfer of preformed three-dimensional photonic crystals onto dye-sensitized solar cells. Angewandte Chemie-Int. Ed. 50(25), 5711–5714 (2011)
J.-H. Shin, J. Moon, Bilayer inverse opal TiO\(_2\) electrodes for dye-sensitized solar cells via post-treatment. Langmuir 27(10), 6311–6315 (2011)
B. Hatton, L. Mishchenko, S. Davis, K. Sandhage, J. Aizenberg, Assembly of large-area, highly ordered, crack-free inverse opal films. Proc. Natl. Acad. Sci. U.S.A. 107(23), 10354–10359 (2010)
L. Liu, S. Karuturi, L. Su, A.I.Y. Tok, TiO\(_2\) inverse-opal electrode fabricated by atomic layer deposition for dye-sensitized solar cell applications. Energ. Environ. Sci. 4(1), 209–215 (2011)
S. Guldin, P. Docampo, M. Stefik, G. Kamita, U. Wiesner, H. Snaith, U. Steiner, Layer-by-layer formation of block copolymer derived TiO\(_2\) for solid state dye-sensitized solar cells. Small 8(3), 432–440 (2012)
S. Colodrero, A. Forneli, C. Lopez-Lopez, L. Pelleja, H. Míguez, E. Palomares, Efficient transparent thin dye solar cells based on highly porous 1D photonic crystals. Adv. Funct. Mater. 22(6), 1303–1310 (2012)
D.-K. Hwang, B. Lee, D.-H. Kim, R. Chang, Efficiency enhancement in dye-sensitized solar cells by three-dimensional photonic crystals, Applied Physics Express, vol 5 issue 12, 122–103, 2012
U. Bach, D. Lupo, P. Comte, J.E. Moser, F. Weissörtel, J. Salbeck, H. Spreitzer, M. Grätzel, Solid-state dye-sensitized mesoporous TiO\(_{2}\) solar cells with high photon-to-electron conversion efficiencies. Nature 395, 583–585 (1998)
J. Melas-Kyriazi, I.-K. Ding, A. Marchioro, A. Punzi, B. Hardin, G. Burkhard, N. Tetreault, M. Grätzel, J.-E. Moser, M. McGehee, The effect of hole transport material pore filling on photovoltaic performance in solid-state dye-sensitized solar cells. Adv. Energ. Mater. 1(3), 407–414 (2011)
J. Halls, C. Walsh, N. Greenham, E. Marseglia, R. Friend, S. Moratti, A. Holmes, Efficient photodiodes from interpenetrating polymer networks. Nature 376(6540), 498–500 (1995)
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Guldin, S. (2013). Dye-Sensitised Solar Cell Based on a Three-Dimensional Photonic Crystal. In: Inorganic Nanoarchitectures by Organic Self-Assembly. Springer Theses. Springer, Heidelberg. https://doi.org/10.1007/978-3-319-00312-2_9
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