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Encapsulation Effects

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Organic Chemistry in Confining Media

Abstract

Consideration of supramolecular systems which provide a confined nanospace for the formation of discrete inclusion complexes with reactive guests is based on new and principally important data. Encapsulation effects are inherent to concave molecules named cavitands. Cavitands are spherical, hollow hosts with inner cavities that are large enough to accommodate one or more guest molecules. The cavity of the cavitand allows it to engage in host–guest chemistry with guest molecules of complementary shape and size. Examples include cyclodextrins, cucurbiturils, calixarenes, resorcinarenes, pillararenes, etc. Cavitands are used as molecular flasks to study the effects of confinement on reactions involving encapsulated guests.

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Todres, Z.V. (2013). Encapsulation Effects. In: Organic Chemistry in Confining Media. Springer, Heidelberg. https://doi.org/10.1007/978-3-319-00158-6_1

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